Marsh-water column interactions in two Louisiana estuaries. I. Sediment dynamics

Throughflow marsh flumes were used to measure total sediment exchanges (TSS) between the marshes and water column of two Louisiana estuaries. One, the Barataria Basin estuary, is isolated from significant riverine sediment input. There were significant (p<0.05) imports of 33.9 to 443 mg TSS m^?2 h^?1 at the Barataria Basin brackish marsh (BM) site. The Barataria Basin saltmarsh (SM) site exported TSS in two summer samplings, but significant uptake was measured in April (166 mg m^?2 h^?1) and November (45 mg m^?2 h^?1) during a winter frontal passage event. The other estuary, Fourleague Bay, receives large sediment inputs from the Atchafalaya River, and TSS imports of 22.5 to 118.5 mg m^?2 h^?1 were measured at the BM site here. We calculated sediment accumulation from fluxes quantified in marsh flumes using site-specific sedimentological data and flooding regimes at each site. Water level records from May 1987 to April 1989 showed an extended period of unusually low flooding frequencies. As a result, calculated accretion rates were low, with monthly rates of 0.02 to 0.11 mm and ?0.06 to 0.06 mm at the Barataria BM and SM sites, respectively, and ?0.18 to 0.08 mm at the Fourleague Bay marsh flume site. Actual net sediment deposition, determined by feldspar marker horizon analysis, was 0.7–1.6 mm mo^?1 at the Barataria SM and 0.2–1.3 mm mo^?1 at the Fourleague Bay BM. Even the highest calculated accretion rates, based on flume measurements, were half to one order of magnitude lower than actual measured sediment deposition. This discrepancy was probably because: 1) most sedimentation occurs during episodic events, such as Hurricane Gilbert in September 1988, which deposited 3.5–15.5 mm of sediment on the Barataria Basin saltmarsh, or 2) most vertical accretion in Louisiana marshes occurs via deposition of in situ organic matter rather than by influx of allochthonous sediment. Our results affirm the variability of short-term sediment transport and depositional processes, the close coupling of meteorologic forcing and flooding regime to sediment dynamics, and the importance of understanding these interrelated mechanisms in the context of longer term measurements.     

Marsh-water column interactions in two Louisiana estuaries. II. Nutrient dynamics

The exchange of dissolved nutrients between marshes and the inundating water column was measured using throughflow marsh flumes built, in two microtidal Louisiana estuaries: the Barataria Basin estuary and Fourleague Bay. The flumes were sampled between September 1986 and April 1988, coincident with an extended period of low sea level on the Louisiana coast. The Barataria Basin estuary is in the later, deteriorating stage of the deltaic cycle, characterized by low freshwater inputs and subsiding marshes. Both brackish and saline marshes supplied dissolved organic nitrogen (DON), inorganic nitrogen (ammonium + nitrate + nitrite = DIN), dissolved organic carbon (DOC), and total nitrogen (as total Kjeldahl nitrogen = TKN) to the water column. The export of DIN is probably related to the N accumulated in earlier stages of deltaic development and released as these marshes deteriorate. Coastal brackish marshes of Fourleague, Bay, part of an accreting marsh system in an early, developmental stage of the deltaic cycle, exported TKN to the open water estuary in all samplings. This marsh apparently acted as a short-term buffer of DIN by taking up NH₄ ⁺ in spring, when baywide concentrations were high, and supplying DIN to the estuary in summer and fall, when concentrations, in the bay were lower. Differences in phosphorus (P), DOC, and DON fluxes between these two estuaries were also observed. The Fourleague Bay site exported soluble reactive phosphorus (SRP) and total phosphorus (TP) and imported DOC. This P export may be related to remobilization of sediment-bound riverine P by the reducing, soils of the marshes. Fluxes of SRP at the Barataria Basin sites were variable and low while DOC was imported. Most imports of dissolved nutrients were correlated with higher upstream [source] concentrations, and flux rates were fairly consistent throughout the tide. Dissolved nutrient exports, did not correlate with upstream concentrations, though, and in many cases the flux was dominated by early, flood tide nutrient release. This pulsed behavior may be caused by rapid diffusion from the sediments early in the tidal cycle, when the sediment-water concentration gradient is largest. Interestuary differences were also seen in particulate organic matter fluxes, as the Fourleague Bay marsh exported POC and PON during all samplings while Barataria Basin imported these nutrients. In general, the magnitude and direction of nutrient exchanges in Louisiana marshes, seem to reflect the deltaic successional stage of the estuary.     

Ion exchange reactions of KNiAsO4

The mica-like layer compound KNiAsO₄ easily exchanges its interlayer potassium ions for alkyl ammonium ions, RNH ₃ ⁺ (R=CH₃ - C₁₈H₃₇). Short chain ions (<>₄) will react in aqueous solution and longer chains in ethanolic solution. The reaction of KNiAsO₄ with aqueous solutions of methyl, ethyl and butyl ammonium chlorides of different concentrations has been investigated using a potassium ionselective electrode. Room temperature kinetic curves of percent exchange vs time were obtained. These indicate an apparent cooperative mechanism with some rearrangement of the alkyl ammonium ions between the layers during the reaction. KNiAsO₄ also reacts with water. This reaction may facilitate the exchange reaction with aqueous alkyl ammonium ions. The alkyl ammonium ions form ordered arrangements between the [NiAsO₄]^– layers. Small chains (<>₄) adopt a variety of configurations within the same product.Paper from the NATO Advanced Study Institute on Physical Properties and Thermodynamic Behaviour of Minerals, Cambridge 1987     

Phytoplankton production and seasonal biomass variation of seagrass,Ruppia maritima L., in a tropical Mexican lagoon with an ephemeral inlet

Plankton metabolism andRuppia maritima biomass were measured seasonally during 1982–83 in El Verde Lagoon, a small coastal lagoon with an ephemeral inlet on the Pacific Coast of Mexico. Total net aquatic primary production was 521 g C m^?2 y^?1. The water column was slightly heterotrophic, with an annual P/R ratio of 0.89. Our analysis indicates that tropical and subtropical coastal lagoons with restricted or seasonal inlets have generally higher net aquatic primary productivity levels than lagoons with permanently open inlets. We hypothesize that this is due to retention of nutrients and plankton stocks during the dry season. The seasonal pattern of water column metabolism was related to rainfall and riverflow, with higher values generally occurring during the wet season. Net production and respiration were about three times lower during the 1982 dry season as compared to the 1983 dry season which received considerable rains due to abnormal climatic conditions. The biomass ofR. maritima ranged from zero to 620 g dry wt m^?2. Growth occurred only during the dry season and there were two distinct biomass peaks representing two separate crops. The second crop was heavily epiphytized with nitrogen-fixing algae. There was an apparent succession in dominance of water column productivity over the year, withRuppia dominating during the dry season and phytoplankton more important during the wet season.     

High precision measurements of sediment elevation in shallow coastal areas using a sedimentation-erosion table

The use of a sedimentation-erosion table (SET) for the measurement of small changes in sediment surface elevation in intertidal and shallow subtidal areas is described. The SET provides a constant reference plane in space from which the distance to the sediment surface can be measured by lowering pins to the surface. The precision of the method was determined by repeated measurements in coastal marshes, mudflats, and subtidal areas in Louisiana and Georgia. The confidence interval of the SET is about ±1.5 mm. The SET is more accurate if pins are lowered manually and the sediment surface is determined visually than if pins are lowered by gravity and the sediment surface is determined by soil resistance.     

Seasonality of materials transport through a coastal freshwater marsh: Riverine versus tidal forcing

Transports of nitrate and suspended solids were measured six times from January 1984 until January 1985 in a small freshwater tidal bayou in south-central Louisiana. The bayou and adjacent marshes are influenced by Atchafalaya River discharges, tides, and coastal weather patterns. Large net ebb-directed water transports occurred in winter, spring, and summer, coincident with high river discharges, indicating riverine dominance. A very small net flood-directed water transport occurred in fall, indicating tidally dominated hydrology. Nitrate and suspended solids transports were net ebb-directed in all seasons, but were two orders of magnitude higher during high river flow. Exports changed as hydrology switched from river dominated to tidally dominated, and as concentrations of materials changed. Comparison of suspended solids and nitrate concentrations in the river and bayou shows that these materials were usually lower in the bayou, indicating retention by the marsh/aquatic system.     

AnnGIS: Integration of GIS and a Continuous Simulation Model for Non-Point Source Pollution Assessment

Non-Point Source (NPS) models and monitoring data are often used to evaluate management practices and develop NPS pollution control plans. Application of a dynamic NPS model requires efficient input data acquisition, storage, organization, reduction, and analysis accompanied by manipulation, interpretation, reporting, and display of model outputs. A Geographic Information System (GIS) helps extract, store, and organize input data as well as manipulate and display model outputs. This paper illustrates the development of an integrated GIS system for a continuous simulation, pollutant-loading model, AnnAGNPS ( Ann ualized AG ricultural N on- P oint S ource Pollution). The integrated system, called AnnGIS, was developed using the ArcView GIS and related program extensions. Using AnnGIS, modeling studies and management plans can be efficiently and easily developed. AnnGIS helps store, organize, and manipulate spatial and tabular data, extract spatial input parameters, develop analysis scenarios, and visualize input and output data in spatial, tabular, and graphical forms. AnnGIS is generic in nature (not limited to a particular geographic location) and can be successfully used in regions for which AnnAGNPS is designed. AnnGIS's powerful graphical user interface and reference data sets facilitate efficient and informed decision-making concerning agricultural non-point pollution control and management.     

Policy and practice in karst landscape protection: Bohol, the Philippines

The karst landscape in the interior of the Philippines' Bohol Province represents one of the world's premier kegelkarst (cone karst) environments. Government efforts to protect some of this karst, exemplified by the establishment of the Rajah Sikatuna National Park and the Chocolate Hills Natural Monument, have proven to be significant catalysts of social conflict. In Bohol there is a long history of traditional land tenure, which has recently been supplanted by a Westernized model. Protected area establishment is a response to deforestation, agricultural exploitation and uncontrolled quarrying. However, the imposition of protective legislation to prevent further degradation has disenfranchized and marginalized many local farmers and residents. The conflict between the obligation of the State to ensure environmental protection and the perceived property rights of landowners and farmers has provoked an escalation in civil unrest and armed conflict.     

Short-term sedimentation dynamics in the Rhône River Delta. France: The importance of riverine pulsing

Short-term sedimentation patterns were evaluated from August 1992 to May 1993 in different wetland habitats characteristic of the Rhône Delta, including impounded and seasonally-dry saline Arthrocnemum marshes, brackish Juncus, Phragmites, and Scirpus riverine wetlands directly connected to the Rhône River, and Arthrocnemum-dominated marine marshes influenced by the Mediterranean. Short-term sedimentation was measured as sediment accumulation on paper filters which had been placed on the soil surface for several weeks. Total sedimentation and material lost on ignition was significantly related to individual sampling periods, reflecting the importance of short-term processes. High sedimentation at riverine sites (up to 22 g m^?2 d^?1) was related to a combination of river stage and wind events. Marine and impounded wetlands of the Rhône Delta experienced low sedimentation throughout the period of study. Sedimentation rates averaged over the study period were 0.8 g m^?2 d^?1, 1.8 g m^?2 d^?1, and 5.4 g m^?2 d^?1 for marine, impounded, and riverine sites, respectively. Percent material lost on ignition was low in all habitats (average 15%) and followed a seasonal trend with a minimum in late fall and winter (1%). Soil percent organic matter was also low in the top several centimeters (13%), suggesting that inorganic sedimentation is very important for accretion on these wetland surfaces. Coastal flooding was not a significant mechanism for sedimentation in the marine sites during the period of study. Sedimentation is an important factor in elevation change, and this study shows that impounded habitats, the most common “natural environment“ left in the delta, may become vulnerable to sea-level rise in the future if management practices continue to isolate these wetlands from riverine sources of sediment.     

Drainage density changes during rainfall

Observations of stream behaviour during rainfall indicate that previous notions of a simple expanding and contracting network need review and refinement. In a small rural catchment near Armidale, N.S.W. changes in flowing stream length during rainfall have been depicted on flow length graphs which indicate a varied network response to similar rainfall amounts. Channel flow phenomena include discontinuous flow, the generation of flow points within the channel and movement of water downslope from saturated depression sources. Localized physical controls have a significant effect on stream growth which is a sensitive indicator of the catchment response to rainfall. During rapid changes in stream length total flowing length and discharge are highly correlated. A model of the pattern of network expansion and contraction involves several phases of flow contraction.