Origin and variability of resource-grade marine ferromanganese nodules and crusts in the Pacific Ocean: A review of biogeochemical and physical controls

Marine ferromanganese nodules and crusts containing Mn, Cu, Ni and Co in the most promising resource-grade concentrations and quantities, together with Fe and Zn (all elements of biogeochemical importance) are found far from land on the deep seafloor of the Pacific Ocean. The biogeochemical, chemical and physical mechanisms contributing to their formation, distribution, abundance and – for these six elements – variability in their concentrations in these deposits, are the main focus of the present review. The mechanisms addressed include biological productivity, sedimentation types and rates, bottom water characteristics, the Calcium Carbonate Compensation Depth, the depth and intensity of the oxygen minimum zone, and biogeochemical characteristics of the six focal elements. Particular attention is given to comparisons between the deposits found in the north and the south Pacific, in order to present an overarching view of our current understanding of the mechanisms that apply to both nodules and crusts in both oceanic hemispheres, including examination of the possible existence of a marine ferromanganese oxide continuum. The renewed interest in the commercial exploitation of these deposits has stimulated a welcome increase in scientific research that is essential to informing the public discourse on seabed mining. We briefly reflect on the work addressed in this review in that context.     

http://www.sciencedirect.com/science/article/pii/S167498711400108X

We present three 3D numerical models of deep subduction where buoyant material from an oceanic plateau and a plume interact with the overriding plate to assess the influence on subduction dynamics,trench geometry,and mechanisms for plateau accretion and continental growth.Transient instabilities of the convergent margin are produced,resulting in:contorted trench geometry;trench migration parallel with the plate margin;folding of the subducting slab and orocline development at the convergent margin;and transfer of the plateau to the overriding plate.The presence of plume material beneath the oceanic plateau causes flat subduction above the plume,resulting in a "bowed" shaped subducting slab.In plateau-only models,plateau accretion at the edge of the overriding plate results in trench migration around the edge of the plateau before subduction is re-established directly behind the trailing edge of the plateau.The plateau shortens and some plateau material subducts.The presence of buoyant plume material beneath the oceanic plateau has a profound influence on the behaviour of the convergent margin.In the plateau + plume model,plateau accretion causes rapid trench advance.Plate convergence is accommodated by shearing at the base of the plateau and shortening in the overriding plate.The trench migrates around the edge of the plateau and subduction is re-established well behind the trailing edge of the plateau,effectively embedding the plateau into the overriding plate.A slab window forms beneath the accreted plateau and plume material is transferred from the subducting plate to the overriding plate through the window.In all of the models,the subduction zone maintains a relatively stable configuration away from the buoyancy anomalies within the downgoing plate.The models provide a dynamic context for plateau and plume accretion in Phanerozoic accretionary orogenic systems such as the East China Orogen and the Central Asian Orogen(Altiads),which are characterised by accreted ophiolite complexes with diverse geochemical affinities,and a protracted evolution of accretion of exotic terranes including oceanic plateau and terranes with plume origins.     

Colloidal Stability and Toxicity of Gold Nanoparticles and Gold Chloride on <Emphasis Type="Italic">Chlamydomonas reinhardtii</Emphasis>

Here we have examined interactions of gold nanoparticles differing in primary particle size and coating with the green algae Chlamydomonas reinhardtii as function of the colloidal stability of the particles in the experimental media used for toxicity studies. Interactions of dissolved Au³⁺ ions with algae were also examined. Included endpoints were photosynthetic yield and algal growth. Morphological and structural effects were examined microscopically and by flow cytometry. The results indicate no significant toxicity of gold nanoparticles to C. reinhardtii. Analysis of published data suggests toxicity of gold nanoparticles on algal growth to relate rather to particular coatings than to the gold core.