The Sensitivity of Four Monitoring Well Sampling Systems to Low Concentrations of Three Volatile Organics

Four state-of-the-art ground water sampling systems were analyzed to determine their reliability in providing representative samples of the volatile chlorinated hydrocarbons trichloroethylene (TCE), perchloroethylene (PCE), and 1,1,1-trichloroethane (TCA) from a simulated monitoring well. The sampling systems studied represent four commonly used devices, including a stainless steel and Teflon® piston pump, a Teflon bailer, a Teflon bladder pump, and a PVC air-lift pump.
Controlled laboratory sampling experiments were conducted in a tank and well test chamber designed to approximate field conditions. A well purging and sampling procedure was used in the test apparatus to determine the accuracy and precision of each device for detecting low concentrations of the compounds in ground water. The compounds selected are some of the most ubiquitous hazardous contaminants found in shallow aquifers near hazardous waste sites throughout the United States.
No significant statistical difference was found among the four sampling systems in detecting the compounds.     

On low-frequency errors of uniformly modulated filtered white-noise models for ground motions

Low-frequency errors of a commonly used non-stationary stochastic model (uniformly modulated filtered white-noise model) for earthquake ground motions are investigated. It is shown both analytically and by numerical simulation that uniformly modulated filter white-noise-type models systematically overestimate the spectral response for periods longer than the effective duration of the earthquake, because of the built-in low-frequency errors in the model. The errors, which are significant for low-magnitude short-duration earthquakes, can be eliminated by using the filtered shot-noise-type models (i.e. white noise, modulated by the envelope first, and then filtered).     

Temporal variations in bedload transport rates associated with the migration of bedforms

Temporal variations in bedload transport rates that occur at a variety of timescales, even under steady flow conditions, are accepted as an inherent component of the bedload transport process. Rarely, however, has the cause of such variations been explained clearly. We consider three data sets, obtained from laboratory experiments, that refer to measurements of bedload transport made with continuously recording bedload traps. Each data set is characterized by a predominant low-frequency oscillation, on which additional higher-frequency oscillations generally are superimposed. The period of these oscillations, as isolated through the use of spectral analysts, ranged between 0·47 and 168 minutes, and was associated unequivocally with the migration of bedforms such as ripples, dunes, and bars. The extent to which such oscillatory behaviour may be recognized in a data set depends on the duration of sampling and the length of the sampling time, with respect to the period of a given bedform. Several theoretical probability distribution functions have been developed to describe the frequency distributions of (relative) bedload transport rates that are associated with the migration of bedforms (Einstein, 1937b; Hamamori, 1962; Carey and Hubbell, 1986). These distribution functions were derived without reference to a sampling interval. We present a modification of Hamamori's (1962) probability distribution function, generated by Monte Carlo simulation, which permits one to specify the sampling interval, in relation to the length of a bedform. Comparisons between the simulated and observed frequency distributions, that were undertaken on the basis of the data described herein, are good (significant at the 90 per cent confidence level). Finally, the implications that temporal variability, which is associated with the migration of bedforms, have for the accurate determination of bedload transport rates are considered.     

Annual heat balance and equilibrium temperature of Lake Aegeri,Switzerland

The mean heat budget of Lake Aegeri, Switzerland, is 950 MJ·m^–2, comparable to that of neighbouring lakes. The annual variation in the net heat flux can be adequately described using a six-term heat balance equation based on 12 years of monthly mean meteorological and surface temperature data. Although the magnitude of the net heat flux is dominated by the radiative terms of the equation, the one-month backward shift of the net flux and total heat content extrema from the solstices and equinoxes respectively is due to the phase shift of the non-radiative with respect to the radiative terms. A linear approximation was used to express the net heat flux in terms of a heat exchange coefficient and an equilibrium temperature. The former varies from 17 to 28 W·m^–2·K^–1 in the course of a year; fluctuations in the latter are found to depend mainly on fluctuations in cloud cover and relative humidity, whilst the effect of fluctuations in air temperature and wind speed is slight.     

Free cupric ion concentrations and Cu complexation in selected Swiss lakes and rivers

[Cu²⁺] and Cu complexation parameters in some selected freshwater systems in Switzerland were determined by the technique of ligand-exchange and DPCSV. Results from the water columns of some eutrophic and oligotrophic lakes are presented and compared to small acid lakes. Cu is strongly complexed by organic ligands which with very high stability constants at low concentrations are probably biologically produced, as indicated by the seasonal variations in the eutrophic lakes and by the relationship between Cu complexation and algal activity in the eutrophic (pCu=15–16), oligotrophic (pCu=13–14) and acidic (pCu=9–10) lakes. The extent of Cu complexation in river waters was generally lower than in the eutrophic lakes, at similar DOC levels. No obvious correlation between Cu complexation and DOC was observed, indicating that Cu complexing ligands are specific organic compounds.     

Uncertainty propagation of hydrodispersive transfer in an aquifer: an illustration of one-dimensional contaminant transport with slug injection

It is evident that the hydrodynamic dispersion coefficient and linear flow velocity dominate solute transport in aquifers. Both of them play important roles characterizing contaminant transport. However, by definition, the parameter of contaminant transport cannot be measured directly. For most problems of contaminant transport, a conceptual model for solute transport generally is established to fit the breakthrough curve obtained from field testing, and then suitable curve matching or the inverse solution of a theoretical model is used to determine the parameter. This study presents a one-dimensional solute transport problem for slug injection. Differential analysis is used to analyze uncertainty propagation, which is described by the variance and mean. The uncertainties of linear velocity and hydrodynamic dispersion coefficient are, respectively, characterized by the second-power and fourth-power of the length scale multiplied by a lumped relationship of variance and covariance of system parameters, i.e. the Peclet number and arrival time of maximum concentration. To validate the applicability for evaluating variance propagation in one-dimensional solute transport, two cases using field data are presented to demonstrate how parametric uncertainty can be caught depending on the manner of sampling.     

Monitored Natural Attenuation of Manufactured Gas Plant Tar Mono- and Polycyclic Aromatic Hydrocarbons in Ground Water: A 14-Year Field Study

Site 24 was the subject of a 14-year (5110-day) study of a ground water plume created by the disposal of manufactured gas plant (MGP) tar into a shallow sandy aquifer approximately 25 years prior to the study. The ground water plume in 1988 extended from a well-defined source area to a distance of approximately 400 m down gradient. A system of monitoring wells was installed along six transects that ran perpendicular to the longitudinal axis of the plume centerline. The MGP tar source was removed from the site in 1991 and a 14-year ground water monitored natural attenuation (MNA) study commenced. The program measured the dissolved mono- and polycyclic aromatic hydrocarbons (MAHs and PAHs) periodically over time, which decreased significantly over the 14-year period. Naphthalene decreased to less than 99% of the original dissolved mass, with mass degradation rates of 0.30 per year (half-life 2.3 years). Bulk attenuation rate constants for plume centerline concentrations over time ranged from 0.33 ± 0.09 per year (half-life 2.3 ± 0.8 years) for toluene and 0.45 ± 0.06 per year (half-life 1.6 ± 0.2 years) for naphthalene. The hydrogeologic setting at Site 24, having a sandy aquifer, shallow water table, clay confining layer, and aerobic conditions, was ideal for demonstrating MNA. However, these results demonstrate that MNA is a viable remedial strategy for ground water at sites impacted by MAHs and PAHs after the original source is removed, stabilized, or contained.     

Palaeoenvironment reconstruction,volcanic evolution and geochronology of the Cerro Blanco subcomplex,Nevados de Chillán volcanic complex,central Chile

Nevados de Chillán Volcanic Complex, central Chile, has been active for at least 640 ka—a period spanning a number of glacial and interglacial periods. Geologic mapping, radiometric dating and geochemical analysis have identified six new volcanic units and produced four new ⁴⁰Ar/³⁹Ar ages for Cerro Blanco, the northern subcomplex of Nevados de Chillán volcano. Compositions range from dacite to basaltic-andesite and a new geologic map is presented. Examination of lava fracture structures on both newly mapped lavas and those mapped during previous studies has enabled interpretations of former eruptive environments. Palaeoenvironment reconstructions, combined with ⁴⁰Ar/³⁹Ar ages and comparison with the marine oxygen isotope record, show that at least three phases of volcanic activity have occurred during the evolution of Cerro Blanco: (1) a constructive, pre-caldera collapse period; (2) a period of caldera formation and collapse; and (3) a constructive period of dome growth forming the modern day volcanic centre. This style of volcanic evolution, whereby large-scale caldera collapse is followed by growth of a new stratocone is common at Andean volcanoes.