Modelling of periodic wave transformation in the inner surf zone

In this paper, we analyse the ability of the nonlinear shallow-water (NSW) equations to predict wave distortion and energy dissipation of periodic broken waves in the inner surf zone. This analysis is based on the weak-solution theory for conservative equations. We derive a new one-way model, which applies to the transformation of non-reflective periodic broken waves on gently sloping beaches. This model can be useful to develop breaking-wave parameterizations (in particular broken-wave celerity expression) in both time-averaged wave models and time-dependent Boussinesq-type models. We also derive a new wave set-up equation which provides a simple and explicit relation between wave set-up and energy dissipation. Finally, we compare numerical simulations of both, the NSW model and the simplified one-way model, with spilling wave breaking experiments and we find a good agreement.     

Use of Carbonatites in the Production of Precipitated Calcium Carbonate: A Case Study from Eppawala,Sri Lanka

The study investigates the possibility of using carbonatite in the production of precipitated calcium carbonate (PCC). We made use of fresh apatite-rich carbonatites found at the phosphate mining sites at Eppawala, Sri Lanka. Analyses of the fresh carbonatite were performed with the aid of optical microscopy, powder X-ray diffraction (XRD), atomic absorption spectrophotometry (AAS), UV/visible spectrophotometry (UVVS), and thermo gravimetric analysis (TGA). Quicklime obtained from calcinations of carbonatites was used in synthesizing PCC via a lime-soda process. The end product was analyzed with XRD, TGA, AAS, and UVVS. Results revealed that the most common CO₃ ^2? phase available in fresh carbonatites is calcite (>65%). The Ca-rich CO₃ ^2? phase can be distinguished easily from other available minerals because its mode of occurrence in carbonatite matrix is different to that of other minerals. The results of TGA show that the decomposition of CO₃ ^2? phase initiates at about 340°C, which leads to lower energy consumption during calcinations. Post-magmatic hydrothermal process may have been the cause of the formation of thermally unstable CO₃ ^2? phases. Hydration of quicklime from the carbonatite yields much higher Ca²⁺ in the solution than from marble under the same experimental conditions. The synthesized PCC particles are in the calcite polymorphic form. The purity of PCC varies from 96 to 98 wt%. The maximum precipitable CaCO₃ from 1 g of quicklime is about 1.1 g. Hence, fresh carbonatites has great economic potential for the production of PCC.     

Groundwater Development Stress: Global‐Scale Indices Compared to Regional Modeling

The increased availability of global datasets and technologies such as global hydrologic models and the Gravity Recovery and Climate Experiment (GRACE) satellites have resulted in a growing number of global‐scale assessments of water availability using simple indices of water stress. Developed initially for surface water, such indices are increasingly used to evaluate global groundwater resources. We compare indices of groundwater development stress for three major agricultural areas of the United States to information available from regional water budgets developed from detailed groundwater modeling. These comparisons illustrate the potential value of regional‐scale analyses to supplement global hydrological models and GRACE analyses of groundwater depletion. Regional‐scale analyses allow assessments of water stress that better account for scale effects, the dynamics of groundwater flow systems, the complexities of irrigated agricultural systems, and the laws, regulations, engineering, and socioeconomic factors that govern groundwater use. Strategic use of regional‐scale models with global‐scale analyses would greatly enhance knowledge of the global groundwater depletion problem.     

Effects of rainfall intensity fluctuations on infiltration and runoff: rainfall simulation on dryland soils,Fowlers Gap,Australia

Small plots and a dripper rainfall simulator were used to explore the significance of the intensity fluctuations (‘event profile’) within simulated rainfall events on infiltration and runoff from bare, crusted dryland soils. Rainfall was applied at mean rain rates of 10 mm/h. Fourteen simulated rainfall events each involved more than 5000 changes of intensity and included multipeak events with a 25‐mm/h peak of intensity early in the event or late in the event and an event that included a temporary cessation of rain. These are all event profiles commonly seen in natural rain but rarely addressed in rainfall simulation. A rectangular event profile of constant intensity, as commonly used in rainfall simulation experiments, was also adopted for comparative purposes. Results demonstrate that event profile exerts an important effect on infiltration and runoff for these soils and rainfall event profiles. ‘Uniform’ events of unvarying intensity yielded the lowest total runoff, the lowest peak runoff rate and the lowest runoff ratio (0.13). These parameters increased for ‘early peak’ profiles (runoff ratio 0.24) and reached maxima for ‘late peak’ profiles (runoff ratio 0.50). Differences in runoff ratio and peak runoff rate between the ‘uniform’ event profile and those of varying intensity were all statistically significant at p ≤ 0.01. Compared with ‘uniform’ runs, the varying intensity runs yielded larger runoff ratios and peak runoff rates, exceeding those of the ‘uniform’ events by 85%–570%. These results suggest that for small‐plot studies of infiltration and erosion, the continued use of constant rainfall intensity simulations may be sacrificing important information and misrepresenting the mechanisms involved in runoff generation. The implications of these findings for the ecohydrology of the research site, an area of contour‐aligned banded vegetation in which runoff and runon are of critical importance, are highlighted. Copyright © 2011 John Wiley & Sons, Ltd.     

西藏恰功铁矿岩浆演化序列及斑岩出溶流体特征

冈底斯成矿带是碰撞造山过程形成的最重要的成矿带,恰功矽卡岩铁(铜)矿床即位于冈底斯成矿带中部.本文在详细的野外地质填图和室内研究基础上确定了恰功铁矿与成矿有关的斑岩体为二长花岗斑岩,锆石的U-Pb定年结果为68.8±2.2 Ma,明显早于冈底斯东部与后碰撞伸展有关的斑岩型矿床和主碰撞期形成的矽卡岩型矿床,其应代表了冈底斯一次尚未被充分认识到的成矿事件.通过对成矿斑岩的岩石学、岩石化学、岩浆出溶流体的包裹体岩相学、显微测温分析及包裹体成分的LRM、LA-ICP-MS和PIXE分析,本文探讨了与该矽卡岩矿床有关的斑岩的岩浆起源、斑岩侵位机制及出溶流体特征.结果表明,成矿斑岩为矿区最早的侵入岩单元,具有壳幔源混源特征,其常量元素组成与冈底斯东部斑岩铜矿带的埃达克质岩相近,但稀土和微量元素组成与东部斑岩明显不同,为地幔物质上涌并诱发角闪岩相下地壳熔融的产物,岩体侵位深度大(>7 km)、剥蚀程度高.早期岩浆出溶的流体为高温、高压、高盐度流体,其中富含Fe、Pb、Zn、Cu等成矿金属,与世界其他斑岩铜矿床相比,相对富铁、铅而贫铜.流体的沸腾作用发生于钾硅化阶段,形成了一套富气、高盐、高固相和气液包裹体组合,不同于早期出溶流体的包裹体组合.从岩浆起源和出溶流体性质可以看出,该斑岩具有形成与斑岩有关的铁铅多金属矿床的成矿潜力,但从该矿区地表出露的蚀变和包裹体测压结果可以看出,该斑岩体目前剥蚀深度较大,对斑岩型矿床保存不利,对该斑岩体及与成矿关系的认识对理解该区内的矿床成因和指导区域找矿具有重要的指示意义.     

Subduction-related mafic to felsic magmatism in the Malayer–Boroujerd plutonic complex,western Iran

The Malayer–Boroujerd plutonic complex (MBPC) in western Iran, consists of a portion of a magmatic arc built by the northeast verging subduction of the Neo-Tethys plate beneath the Central Iranian Microcontinent (CIMC). Middle Jurassic-aged felsic magmatic activity in MBPC is manifested by I-type and S-type granites. The mafic rocks include gabbroic intrusions and dykes and intermediate rocks are dioritic dykes and minor intrusions, as well as mafic microgranular enclaves (MMEs). MBPC Jurassic-aged rocks exhibit arc-like geochemical signatures, as they are LILE- and LREE-enriched and HFSE- and HREE-depleted and display negative Nb–Ta anomalies. The gabbro dykes and intrusions originated from metasomatically enriched garnet-spinel lherzolite [Degree of melting (f_mel) ~ 15%] and exhibit negative Nd and positive to slightly negative ε_Hf(T) (+ 3.0 to ? 1.6). The data reveal that evolution of Middle Jurassic magmatism occurred in two stages: (1) deep mantle-crust interplay zone and (2) the shallow level upper crustal magma chamber. The geochemical and isotopic data, as well as trace element modeling, indicate the parent magma for the MBPC S-type granites are products of upper crustal greywacke (f_mel: 0.2), while I-type granites formed by partial melting of amphibolitic lower crust (f_mel: 0.25) and mixing with upper crustal greywacke melt in a shallow level magma chamber [Degree of mixing (f_mix): 0.3]. Mixing between andesitic melt leaving behind a refractory dense cumulates during partial crystallization of mantle-derived magma and lower crustal partial melt most likely produced MMEs (f_mix: 0.2). However, enriched and moderately variable ε_Nd(T) (? 3.21 to ? 4.33) and high (⁸⁷Sr/⁸⁶Sr)_i (0.7085–0.7092) in dioritic intrusions indicate that these magmas are likely experienced assimilation of upper crustal materials. The interpretations of magmatic activity in the MBPC is consistent with the role considered for mantle-derived magma as heat and mass supplier for initiation and evolution of magmatism in continental arc setting, elsewhere.     

Trace metal concentrations in sediments of the Eastern Mississippi Bight

Sediments collected from 3 onshore-offshore transects (12 stations total) in the Eastern Mississippi Bight at 5 different times during 1987–1988 have been analyzed for total Ag, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sn, Th and Zn. The data show considerable variation both spatially and temporally, largely as a result of natural variability in grain size and mineralogy. Clay-rich samples from deep water were always more metal-rich than sandy samples from shallow areas. Many samples from near the Mississippi River Delta appeared to be enriched in Ba by about a factor of two, probably as a result of contamination from oil well drilling mud, but there were few other indications of pollution influences. Many samples from throughout the area gave Mn/Fe and Cd/Fe ratios a factor of two or more lower than their Mississippi River source material. This shows that biochemical activity in the sediment is capable of solubilizing reducible and adsorbed metals.     

Oscillations of galactic cosmic rays and solar indices before the arrival of relativistic solar protons

Using modern wavelet analysis techniques, we have made an attempt to search for oscillations of intensity of galactic cosmic rays (GCR), sunspot numbers (SS) and magnitudes of coronal index (CI) implying that the time evolution of those oscillations may serve as a precursor of Ground Level Enhancements (GLEs) of solar cosmic rays (SCR). From total number of 70 GLEs registered in 1942–2006, the four large events — 23 February 1956, 14 July 2000, 28 October 2003, and 20 January 2005 — have been chosen for our study. By the results of our analysis, it was shown that a frequency of oscillations of GCR decreases as time approaches to the event day. We have also studied a behaviour of common periodicities of GCR and SCR within the time interval of individual GLE. The oscillations of GLE occurrence rate (OR) at different stages of the solar activity (SA) cycle is of special interest. We have found some common periodicities of SS and CI in the range of short (2.8, 5.2, 27 and 60 days), medium (0.3, 0.5, 0.7, 1.3, 1.8 and 3.2 years) and long (4.6 and 11.0 years) periods. Short and medium periodicities, in general, are rather concentrated around the maxima of solar cycles and display the complex phase relations. When comparing these results with the behaviour of OR oscillations we found that the period of 11 years is dominating (controlling); it is continuous over the entire time interval of 1942–2006, and during all this time it displays high synchronization and clear linear ratios between the phases of oscillations of η, SS and CI. It implies that SCR generation is not isolated stochastic phenomena characteristic exclusively for chromospheric and/or coronal structures. In fact, this process may have global features and involve large regions in the Sun’s atmosphere.