Ionic medium effects in sea water — A comparison of acidity constants of carbonic acid and boric acid in sodium chloride and synthetic sea water

It is shown that the values of pK_1C and pK_2C for carbonic acid, pK_B for boric acid and the ionic product of water, pK_w, in sea water may be explained on the basis of their determination in 0.7 M_w sodium chloride and the formation of the following ion-pairs: NaSO₄^?, MgSO₄, CaSO₄, MgCO₃, CaCO₃, MgHCO₃⁺, CaHCO₃⁺, MgOH⁺, HSO₄^?, MgB(OH)₄⁺ and CaB(OH)₄⁺. On the whole the calculated stability constants are lower than those given by Garrels and Thompson (1962).     

An ocean bottom,microprocessor based seismometer

We describe the design and construction of an ocean bottom seismometer configured as a computer, based on an Intersil IM6100 microprocessor plus appropriate peripheral devices. The sensors consist of triaxial 1 Hz seismometers and a hydrophone, each sensor channel being filtered prior to digitizing so that typical noise spectra are whitened. Digital data are recorded serially on magnetic tape. The instrument is placed on the ocean bottom by allowing it to fall freely from just below the surface. An acoustic system allows precise determination of instrument position, acoustic recall, and transmission of operational information to the surface. Release from an expendable anchor is accomplished by redundant pyrotechnic bolts which can be fired by acoustic command or by precision timers.The operational flexibility provided by the micro-computer, which executes the DEC PDP8/E instruction set, enables optimum use of the 6-hr recording capacity (at 128 samples/second/channel) in the context of the particular experiment being performed.

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Validation of the stochastic distorted-wave Born approximation model with broad bandwidth total target strength measurements of Antarctic krill

In the computations of SDWBA_TTS(f) in Figure 4, the scatteredvector was integrated over all orientations in the XY plane,where X is the main axis of the krill, but a factor of 2 was     

Seasonality and selectivity in the feeding ecology and reproductive biology of deep-sea bathyal holothurians

Chlorophyll and carotenoid pigments were determined from the gut sediments of five species of bathyal holothurian in the NE Atlantic, sampled shortly after the spring/summer phytoplankton bloom in 2001 and prior to the spring bloom in 2002. Three species, Laetmogone violacea, Paroriza pallens and Bathyplotes natans, sampled within a similar depth range (900–1100 m) in the summer of 2001 showed significant differences in their chlorophyll and carotenoid pigment concentrations. This suggests they may select for slightly different components from the available food resource. Four species sampled in early spring 2002, Laetmogone violacea, Paroriza pallens, Benthogone rosea and Benthothuria funebris, also had significant differences in their pigment concentrations. These species were sampled over a wider depth range (1000–3100 m) showing a bathymetric trend in pigment concentrations. There was a distinct seasonal change in the composition and concentration of the pigments, linked to a reduction in the availability of fresh organic material during autumn and winter periods.Ovarian tissue was also examined. The carotenoid pigments found in the ovary also occurred in the OM ingested by the holothurians. The dominant gonadal carotenoid pigments were β-carotene, echinenone and zeaxanthin. The potential for using these carotenoids to gain a competitive advantage through selectivity of chlorophyll and carotenoid pigment biomarkers are discussed in relation to competition for food resources by deposit-feeders. The results were also compared with selectivity in abyssal species.     

Multi-AUV Control and Adaptive Sampling in Monterey Bay

Operations with multiple autonomous underwater vehicles (AUVs) have a variety of underwater applications. For example, a coordinated group of vehicles with environmental sensors can perform adaptive ocean sampling at the appropriate spatial and temporal scales. We describe a methodology for cooperative control of multiple vehicles based on virtual bodies and artificial potentials (VBAP). This methodology allows for adaptable formation control and can be used for missions such as gradient climbing and feature tracking in an uncertain environment. We discuss our implementation on a fleet of autonomous underwater gliders and present results from sea trials in Monterey Bay in August, 2003. These at-sea demonstrations were performed as part of the Autonomous Ocean Sampling Network (AOSN) II project     

How are large western hemisphere warm pools formed?

During the boreal summer the Western Hemisphere warm pool (WHWP) stretches from the eastern North Pacific to the tropical North Atlantic and is a key feature of the climate of the Americas and Africa. In the summers following nine El Niño events during 1950–2000, there have been five instances of extraordinarily large warm pools averaging about twice the climatological annual size. These large warm pools have induced a strengthened divergent circulation aloft and have been associated with rainfall anomalies throughout the western hemisphere tropics and subtropics and with more frequent hurricanes. However, following four other El Niño events large warm pools did not develop, such that the mere existence of El Niño during the boreal winter does not provide the basis for predicting an anomalously large warm pool the following summer.In this paper, we find consistency with the hypothesis that large warm pools result from an anomalous divergent circulation forced by sea surface temperature (SST) anomalies in the Pacific, the so-called atmospheric bridge. We also find significant explanations for why large warm pools do not always develop. If the El Niño event ends early in the eastern Pacific, the Pacific warm anomaly lacks the persistence needed to force the atmospheric bridge and the Atlantic portion of the warm pool remains normal. If SST anomalies in the eastern Pacific do not last much beyond February of the following year, then the eastern North Pacific portion of the warm pool remains normal. The overall strength of the Pacific El Niño does not appear to be a critical factor. We also find that when conditions favor a developing atmospheric bridge and the winter atmosphere over the North Atlantic conforms to a negative North Atlantic Oscillation (NAO) pattern (as in 1957–58 and 1968–69), the forcing is reinforced and the warm pool is stronger. On the other hand, if a positive NAO pattern develops the warm pool may remain normal even if other circumstances favor the atmospheric bridge, as in 1991–92. Finally, we could find little evidence that interactions internal to the tropical Atlantic are likely to mitigate for or against the formation of the largest warm pools, although they may affect smaller warm pool fluctuations or the warm pool persistence.     

Annual Cycle of Zooplankton Biomass, Abundance and Species Composition in the Neritic Area of the Balearic Sea, Western Mediterranean

Abstract. Seasonal changes in zooplankton biomass, abundance and species composition were studied at a neritic station in the Balearic Sea between April 1993 and May 1994. Sampling was carried out every 10 days in a zone influenced by the main current circulating through the Mallorca channel. Three main peaks of zooplankton biomass and abundance were observed: (1) at the beginning of summer when the thermocline developed, (2) in autumn when the thermocline broke down, and (3) in early spring. The smaller zooplankton fraction (100–250 μm) comprised on average 32 % of the total biomass and 73 % of total abundance. Copepods were the predominant group (64 % of the total abundance) with Clausocalanus, Oithona and Paracalanus being the most abundant genera. Paracalanus parvus, Clausocalanus furcatus, Acartia clausi, Oithona plumifera, Temora stylifera, Centropages typicus and Oncaea mediterranea were found to be the most important species in the area. Other abundant groups were cladocerans (15 %) and meroplankton larvae (12 %), both of which were particularly numerous during the stratified period. The copepod community was characterized by the above‐cited perennial species, which were abundant during the cycle studied. However, the influence of the hydrological conditions of the Balearic Sea, such as the Atlantic water influx and the physical structure of the water column (stratification and mixing), promoted the observed variability in zooplankton as well as the appearance of characteristic species during the annual cycle.