Origin and Evolution of Aquitard Porewater in the Western Coastal Plain of Bohai Bay,China

High‐salinity paleowater from low‐permeability aquitards in coastal areas can be a major threat to groundwater resources; however, such water has rarely been studied. The chemical and isotopic compositions of porewater extracted from a 200‐m‐thick Quaternary sedimentary sequence in the western coastal plain of Bohai Bay, China, were analyzed to investigate the salinity origin and chemical evolution of porewater in aquitards. Porewater samples derived at depths shallower than 32 m are characterized by Cl‐Na type saline water (total dissolved solids [TDS], 10.9–84.3 g/L), whereas those at depths greater than 32 m comprise Cl·SO₄‐Na type brackish water (TDS, 2.2–6.3 g/L). Saline porewater is interpreted as evaporated seawater prior to halite saturation, as evidenced by Cl‐Br relationships. Although substantial dilution of saline porewater with meteoric water is supported by a wider Cl^? range and δ²H‐δ¹⁸O covariance, the original marine waters were not completely flushed out. The deeper brackish porewater is determined to be a mixture of fresher porewater and brine groundwater and had a component of old brine of less than 10%, as indicated by a mixing model defined using δ²H and Cl^? tracers. Porewater δ²H‐δ¹⁸O relationships and negative deuterium excess ranging from ?25.9‰ to ?2.9‰ indicate the existence of an arid climate since Late Pleistocene in Tianjin Plain. The aquitard porewaters were chemically modified through water‐rock interactions due to the long residence time.     

Controlling factors of the δ 11B-pH proxy and its research direction

Significant boron isotope fractionation occurs in nature (?70 ‰ to +75 ‰) due to the high geochemical reactivity of boron and the large relative mass difference between ¹⁰B and ¹¹B. Since the 1990s, reconstruction of ancient seawater pH using the isotopic composition of boron in bio-carbonates (δ ¹¹B_carb), and then calculation of the past pCO₂ have become important issues for the international isotope geochemistry community, and are called the δ ¹¹B-pH proxy. Although many achievements have been made by this proxy, various aspects of boron systematics require rigorous evaluation. Based on the previous researches, mechanism of boron isotope fractionation, variation of boron isotope (δ ¹¹B) in nature (especially in bio-carbonates) and controlling factors of the δ ¹¹B-pH proxy, such as the dissociation constant of B(OH)₃ in seawater (pK_a), the δ ¹¹B of seawater (δ ¹¹B_SW), the boron isotopic fractionation factor between B(OH) ₄ ^? and B(OH)₃ (α _4–3), and the incorporated species of boron into bio-carbonates, are reviewed in detail and the research directions of this proxy are proposed. Generally, the controversy about pK_a, δ ¹¹B_sw, and α _4–3 is relatively less, but whether boron incorporated into bio-carbonates only in the form of B(OH) ₄ ^? remains doubtful. In the future, it is required that the physicochemical processes that control boron incorporation into carbonates be rigorously characterized and that the related chemical and isotopic fractionation be quantified. It is also necessary and important to establish a “best-fit empirically equation” between δ ¹¹B_carb and pH of seawater based on the precipitation experiments of inorganic or culture experiments of corals or foraminifera. In addition, extended application of the δ ¹¹B-pH proxy to the earlier part of the Phanerozoic relying on the Brachiopods is worthy of studying. Like other geochemical indicators, there are limiting factors of δ ¹¹B; however, it remains a very powerful tool in the reconstruction of past seawater pH at present.     

厚层覆盖区综合物化探方法找金试验研究——以广西兴安金石金矿为例

在兴安金石金矿外围 4号分散流异常区 ,通过地电化学提取金测量法 ,查明测区存在 5个走向规模小于 5 0 m的金异常区 ,W( Au) 最大值为 72 .4× 10 - 9,高出背景值十几倍 ,并藉综合土壤吸附汞测量 ,高精度磁测和激发极化法等多种物化探方法来确定这些异常区的地质、地球化学和地球物理特征 ,提出金矿成矿的有利部位在金的地电提取高异常区、高汞量异常区、高磁性异常区、低视电阻率异常区和中等视极化率异常区的“三高一低一中”的找矿模式。确定测区的北北东角 (右下角 )一带具备有利的金矿成矿条件     

Hydrothermal plume mapping as a prospecting tool for seafloor sulfide deposits: a case study at the Zouyu-1 and Zouyu-2 hydrothermal fields in the southern Mid-Atlantic Ridge

Seafloor hydrothermal polymetallic sulfide deposits are a new type of resource, with great potential economic value and good prospect development. This paper discusses turbidity, oxidation–reduction potential, and temperature anomalies of hydrothermal plumes from the Zouyu-1 and Zouyu-2 hydrothermal fields on the southern Mid-Atlantic Ridge. We use the known location of these vent fields and plume data collected in multiple years (2009, 2011, 2013) to demonstrate how real-time plume exploration can be used to locate active vent fields, and thus associated sulfide deposits. Turbidity anomalies can be detected 10 s of km from an active source, but the location precision is no better than a few kilometers because fine-grained particles are quasi-conservative over periods of many days. Temperature and oxidation–reduction potential anomalies provide location precision of a few hundred meters. Temperature anomalies are generally weak and difficult to reliably detect, except by chance encounters of a buoyant plume. Oxidation–reduction potential is highly sensitive (nmol concentrations of reduced hydrothermal chemicals) to discharges of all temperatures and responds immediately to a plume encounter. Real-time surveys using continuous tows of turbidity and oxidation–reduction potential sensors offer the most efficient and precise surface ship exploration presently possible.     

巩乃斯避暑旅游气象指数分析与评价

根据巩乃斯、和静站2009—2018年6—8月的逐日平均气温、最高气温、相对湿度、风速等气象观测资料,采用对比分析、通径分析及模糊综合评价等方法对巩乃斯地区夏季避暑旅游气象资源优势进行分析和评价.结果表明:巩乃斯夏季气候凉爽、湿度适宜、风速不大,人体感觉凉爽、舒适,适合避暑旅行.人体舒适度与空气温度呈显著正相关,与相对...     

我国某些急缺矿产找矿突破的可能途径和对策

本文探讨了对我国国民经济影响很大的几种急缺矿产,包括铜、金、金刚石、钾盐找矿突破的可能途径和对策。提出深化成矿环境研究,加强矿带外围、深部及周边邻国成矿区的综合研究,加强地台边缘活动带普查工作,因地制宜选择最佳类型矿床,努力提高成矿理论研究水平是加强矿产勘查与找矿突破的重要措施。     

Multipath mitigation via component analysis methods for GPS dynamic deformation monitoring

Multipath is one of the main error sources in high-precision global positioning system (GPS) dynamic deformation monitoring, as it is difficult to be mitigated by differencing between observations. In addition, since a specific frequency threshold value between multipath and deformation signals may not exist, multipath is usually inseparable from the low-frequency vibration signal using conventional frequency-domain filter methods. However, the multipath repeats in two sidereal days when the surroundings of a GPS antenna remain unchanged. This characteristic can be exploited to model and thus mitigate multipath effectively in dynamic deformation monitoring. Unfortunately, a major issue is that the degree of repeatability decreases as the interval between first day and subsequent days increases. To overcome this problem, we develop a new sidereal filtering referred to as reference EMD-ICA (EMD-ICA-R), where empirical mode decomposition (EMD) and independent component analysis (ICA) are jointly used to model multipath and renew the reference multipath. For the successful implementation of the EMD-ICA-R, an a priori denoised multipath signal is needed as a reference. We further propose to use the principal component analysis (PCA) method to extract more accurate reference multipath signal and form a combined PCA-EMD-ICA-R approach. Simulation experiments with a motion simulation platform were conducted, and the testing results indicate that the proposed methods can mitigate the multipath by around 67 % when a reliable reference multipath signal is extracted from a static situation. Furthermore, simulation experiments with different deformation signals added into the coordinate time series of three consecutive days show that the two proposed methods are also effective in a dynamic situation. Since wavelet filtering is used to denoise the reference multipath signals in the new approaches, simulation experiments with several wavelet filters are tested, and the results indicate that the PCA-EMD-ICA-R approach can work well with various wavelet filters.     

Tracing origins of sewage and organic matter using dissolved sterols in Masan and Haengam Bay,Korea

Masan and Haengam Bays in Korea are highly polluted and semi-enclosed. Domestic and industrial effluents are directly or indirectly discharged into the bays through sewage treatment plants (STP) and creeks. In this study, 15 dissolved sterol compounds were determined in order to understand their sources and relative contribution. Freshwater samples were taken from 13 creeks and at two STP sites on a monthly basis. Total dissolved sterol concentrations ranged from 993 to 4158 ng/L. The concentrations of sterols in winter were higher than in summer. Among the sterols analyzed, cholesterol, β-sitosterol, coprostanol and cholestanone were major compounds in creek water. Seawater samples were concurrently collected at 21 stations in Masan Bay. Total sterol concentrations ranged 118–6,956 ng/L. Inner bay showed high concentrations of sterols in summer, while outer bay showed high sterol concentrations in winter. Among the sterols, cholesterol, β-sitosterol and brassicasterol were major compounds in seawater. In order to examine the contribution of urban sewage, the concentration of coprostanol and fecal sterol ratios were calculated. Most of the creek water, inner bay and near STP outlet samples were affected by sewage. Terrestrial organic matters accounted for a high proportion of dissolved organic matter origin. Fecal origins were relatively high in the inner bay areas and in the STP outlet, while sterols of marine origin were high in the outer bay areas.     

基于自适应多分辨率奇异值分解的大地电磁数据处理

针对强电磁干扰极易掩盖微弱的大地电磁有用信号,本文结合奇异值分解在去噪方面的优越性,提出基于自适应多分辨率奇异值分解（Adaptive Multi-Resolution Singular Value Decomposition,AMRSVD）的大地电磁数据处理方法.首先对大地电磁数据构建Hankel矩阵,利用MRSVD得到不同分辨率的近似信号和细节信号;然后选用近似信号和细节信号的标准差差值,对大地电磁数据进行信噪辨识;接着结合MRSVD和相邻细节信号的标准差差值,提出先验信息未知情况下的AMRSVD法;最后对辨识出的强干扰运用AMRSVD去除噪声,重构有用信号.实验结果表明,该方法的处理效率高,能有效分离出相关性较强的噪声,时间序列和视电阻率-相位曲线均得到有效改善.

     

惠民凹陷南坡石炭二叠系煤层二次生气模式

利用开放体系程序升温热模拟实验方法,对惠民凹陷南坡石炭—二叠系煤岩样品的热演化规律进行了研究,建立了该区石炭二叠系含煤地层有机质的生气模式,探讨了影响二次生气潜力的各种主控因素,为准确评价其资源潜力和计算远景资源量奠定了基础,对渤海湾盆地其他类似地区煤型气勘探具有指导意义。