Possible Non-melted Remnants of Subducted Lithosphere: Experimental and Geochemical Evidence from Corundum-Bearing Mafic Rocks in the Horoman Peridotite Complex, Japan

We report experimental results and whole-rock trace-elementcharacteristics of a corundum-bearing mafic rock from the Horomanperidotite complex, Japan. Coronitic textures around corundumin the sample suggest that corundum was not stable in maficrock compositions during the late-stage P–T conditionsrecorded in the complex (P < 1 GPa, T < 800°C). Basedon the experimental results, corundum is stable in aluminousmafic compositions at pressures of 2–3 GPa under dry conditions,suggesting that the corundum-bearing mineral assemblages developedunder upper-mantle conditions, probably within the surroundingperidotite. Variations in the trace-element compositions ofthe corundum-bearing mafic rock and related rocks can be controlledby modal variations of plagioclase, clinopyroxene and olivine,suggesting that they formed as gabbroic rocks at low-pressureconditions, and that the corundum-bearing mafic rock was derivedfrom a plagioclase-rich protolith. A complex P–T trajectory,involving metamorphism of the plagioclase-rich protolith ata pressure higher than that at which it was first formed, isneeded to explain the origin of the corundum-bearing mafic rocks.They show no evidence for partial melting after their formationas low-pressure cumulates. The Horoman complex is an exampleof a large peridotite body containing possible remnants of subductedoceanic lithosphere still retaining their original geochemicalsignatures without chemical modification during subduction andexhumation. KEY WORDS: Horoman; mafic rock; corundum; experiment; P–T history; recycling     

Ultra-calcic Magmas Generated from Ca-depleted Mantle: an Experimental Study on the Origin of Ankaramites

Ultra-calcic ankaramitic magmas or melt inclusions are ubiquitousin arc, ocean-island and mid-ocean ridge settings. They areprimitive in character (X_Mg > 0·65) and have highCaO contents (>14 wt %) and CaO/Al₂O₃ (>1·1). Experimentson an ankaramite from Epi, Vanuatu arc, demonstrate that itsliquidus surface has only clinopyroxene at pressures of 15 and20 kbar, with X_CO2 in the volatile component from 0 to 0·86.The parental Epi ankaramite is thus not an unfractionated magma.However, forcing the ankaramite experimentally into saturationwith olivine, orthopyroxene and spinel results in more magnesian,ultra-calcic melts with CaO/Al₂O₃ of 1·21–1·58.The experimental melts are not extremely Ca-rich but high inCaO/Al₂O₃ and in MgO (up to 18.5 wt %), and would evolve tohigh-CaO melts through olivine fractionation. Fractionationmodels show that the Epi parent magma can be derived from suchultra-calcic experimental melts through mainly olivine fractionation.We show that the experimental ultra-calcic melts could formthrough low-degree melting of somewhat refractory mantle. Thelatter would have been depleted by previous melt extraction,which increases the CaO/Al₂O₃ in the residue as long as someclinopyroxene remains residual. This finding corrects the commonassumption that ultra-calcic magmas must come from a Ca-richpyroxenite-type source. The temperatures necessary for the generationof ultra-calcic magmas are     

Oxidation During Magmatic Differentiation, Finnmarka Complex, Oslo Area, Norway: Part 2, The Mafic Silicates1

Electron-microprobe analyses are presented for pyroxene, amphibole,and biotite from monzonite, granodiorite, and granite at Finnmarka,Norway. Compositional trends measured in biotite, present inall three rock types, and in amphibole, present in the monzoniteand granodiorite, are markedly atypical and are interpretedas reflecting crystallization under progressively more oxidizingconditions. The average Fe/Fe + Mg for biotites from successivelymore silicic rock types changes from 0.64 0.35 0.28, and foramphiboles changes from 0.58 in the monzonite to 0.29 in thegranodiorite. Analyses of selected areas within amphibole grains in the granodioriteshow marked chemical variations, although single-crystal X-rayphotographs are sharp and do not reveal multiple phases. Onthe basis of 33 such analyses, four coupled substitutions areidentified as operative; the most unusual finding is the relationof 1 Ti cation to 4 Al^IV cations in the unit cell. Variationswithin individual amphibole grains of the granodiorite resemblechanges noted in evolution of amphibole composition from monzoniteto granodiorite and are interpreted as reflecting progressiveoxidation. Consideration of these data for the mafic silicates, data forthe opaque oxides, and the extensive formation of sphene inthe granodiorite, has allowed development of schematic reactionsand an overall picture of magmatic environment and evolutionat Finnmarka. Crystallization apparently took place at PH₂oof 1000 bars or less and a temperature of about 700 °C.The trend of oxidation during differentiation is more extremethan any heretofore reported. Amphiboles, as well as biotites,may participate in oxidation reactions and may reflect the oxidation-reductionprocesses that occurred during magmatic evolution.     

Stability Relations of the Ferruginous Biotite, Annite

Annite, KFe₃AISi₃O₁₀(OH)₂ a member of the iron biotites andthe ferrous analogue of phlogopite, has been synthesized andits phase relations have been determined as functions of temperature,fugacity of oxygen (fo₂), and total pressure (P_totalPH₂O+PH₂).A method for controlling fo₂at high total pressures is described,and data for the ‘oxygen buffers’ used are given.Buffers range from quartz+iron+fayalite assemblages (low fo₂)to magnetite-hematite assemblages (high fo₂). Optical propertiesand unit-cell dimensions of synthetic annites depend on theconditions of synthesis. By recalculating published analyses of natural iron-rich biotitesit can be shown that one cannot assume a constant hydrogen contentfor such biotites. Oxidation may have occurred by drying at115?C. Octahedral occupancy therefore cannot be calculated fromsuch data. Phase relations of annite are presented in 2,070 and 1,035 barsections. Depending on fo₂-T values annite was found to decomposeto one of the following assemblages: hematite+ sanidine, magnetite+sanidine,fayalite+leucite+kalsilite, iron+sanidine. All decompositionsare dehydration and redox reactions and are sensitive to changesin fH₂0 and fo₂ (or fH₂0 and fH₂). At 2, 070 bars total pressureannite+magnetite+sanidine can coexist between 425?C and 825?C, depending upon the magnitude of fo₂. In the presence of quartz the stability field of annite is morerestricted. Phase equilibria in the system KAlSiO₄–SiO₂–Fe–O₂–H₂have been summarized schematically. Wherever possible, thermodynamic extrapolations are made totest the internal consistency of the data. Enthalpies of formationare calculated for both annite and phlogopite. Ranges of fo₂values in nature as well as mechanisms for changes in fo₂ areinvestigated. It is useful to distinguish between assemblageswhich are internally buffered with respect to fo₂changes andthose which are not buffered. The applications of individualreactions involving annite to specific geologic problems arediscussed with respect to igneous, metamorphic, and sedimentaryrocks.     

Emplacement and Differentiation of the York Haven Diabase Sheet, Pennsylvania

Many of the high-Ti quartz-normative tholeiitic intrusive sheetsin the early Mesozoic rift basins of the Eastern USA exhibitlateral differentiation from mafic cumulate units, through diabase,to relatively evolved iron-rich rock types. We have investigateda representative example in detail, the York Haven sheet inthe Gettysburg basin of south–central Pennsylvania. Itranges in thickness from 330 m to 675 m, and we have sampledit from base to top along four separate stratigraphic sectionsevenly spaced over the extent of the intrusion. The easternmostsection (York Haven) is entirely basaltic bronzite cumulate(average 15 vol. % bronzite), whereas the westernmost (ReesersSummit) consists of diabase and low-MgO diabase with a middleto upper ‘sandwich zone’ of ferrogabbro. The interveningsections feature rock types transitional between the two end-membersequences. Chemically, the rock series shows a gradual eastto west depletion of compatible elements (Mg, Ca, Ni, and Cr),and enrichment of incompatible elements [Ti, Fe, Na, K, P, Cu,Zr, Th, Ta, Hf, Sb, Cs, As, platinum group elements (PGEs),and rare earth elements (REEs)]. We suggest two main processes for the trends observed in theYork Haven sheet. First, flow differentiation during ascentand lateral injection of the parental magma produced a tongueof basaltic bronzite cumulate that thins from southeast to northwestand passes laterally into diabase, and, at the distal end ofthe intrusion, into low-MgO diabase. Then, in the latter stagesof crystallization, densitydriven hydrothermal fluids transportedincompatible elements westward, into structurally higher partsof the intrusion. Reaction of this residual aqueous fluid withpartly crystallized low-MgO diabase produced a zone of ferrogabbrorich in hydrothermal replacement products (e.g., Cl-amphibole,biotite, ferrohypersthene, and skeletal ilmenite) and precipitates(e.g., quartz, fayalite, Cl-apatite, sulfides, and PGE minerals). ^* Present address: US Geological Survey, Hawaiian Volcano Observatory, Hawaii National Park, Hawaii 96718     

Geomorphology of the eastern Badia basalt plateau, Jordan

The eastern Badia of the Hashemite Kingdom of Jordan is a landscape developed predominantly on late Tertiary and Quaternary basalt lava flows, which vary in age between 8.9 million and 0.1 million years. Pyroclastic deposits are associated with remnant volcanic cones. There is limited, seasonal rainfall. Natural vegetation regenerates during cool, damp months. Slopes, which range from concave to convex forms and have varying relief, can be related to different basalts and the time since emplacement. Much of the ground surface is mantled with boulders. In many places the continuity of boulder cover produces a desert pavement. Clasts show differing degrees of burial or exhumation, depending on the surrounding topography. Water and sediment movement are important to landscape development. Much sediment is deposited in pans, which evolve at topographic lows. The pans, known locally as Qa, vary in form depending on drainage network development. Transitional forms, known as Marab, develop where wadis widen out and sediments are deposited along ephemeral channels. Groundwater is significant, with three aquifers beneath much of the eastern Badia. Recharge of the upper aquifer is predominantly on the footslopes of the Druze Mountains, with north to south flow. Groundwater extraction has resulted in the expansion of agriculture, with consequent changes in soil and water quality.     

NORTH ATLANTIC OSCILLATION SIGNATURES IN WESTERN IBERIAN TREE-RINGS

Exactly dated ring-width chronologies derived from Pyrenean oak and sweet chestnut trees growing in northern Extremadura, Spain, were evaluated for their potential as proxies for regional precipitation and North Atlantic Oscillation variability. The relationships among tree-rings, instrumental climatic records, and three versions of the NAO index were computed for different time subperiods over the last century. The results indicate that tree-ring records reflect, with variable intensity, both short-term and long-term variations in climate. Multiple correlation and regression analysis revealed that summer precipitation appeared to be the major factor affecting tree growth at inter-annual timescales. Moreover, since fluctuations in accumulated variability in annual rainfall over southwest Iberia are controlled by winter precipitation, the accumulated rainfall (August of the year n -1 to July of year n ) and winter NAO indices are also strongly correlated with tree-ring records at interdecadal timescales. This relationship appears to be especially strong during the second half of the 20th century, which is consistent with an increase of the NAO signal in the annual precipitation during the later part of the century. These results indicate that tree-rings from western Iberia are potential proxies of the NAO variability, useful to be included in palaeoclimatic model studies.     

CHANGING CONCEPTIONS OF SUSTAINABILITY IN BARCELONA'S PUBLIC PARKS*

ABSTRACT. In this article we explore the relationships between public parks and a broad interpretation of sustainability, taking as a case study the city of Barcelona, Spain. Recent official discourses in Barcelona insist on sustainability as one of the fundamental assets of public parks. Yet whether these urban artifacts actually contribute to sustainability objectives in environmental and social terms remains to be examined. We compare two public parks in Barcelona‐the Parc Joan Miró (1983), and the Parc de Diagonal Mar (2002)–and show how, in the former, the integration of the social, political, and environmental dimensions of sustainability was largely achieved, whereas in the latter, only the environmental dimension appears to have been considered.