Using UCODE_2005 and PHREEQC to determine thermodynamic constants from experimental data

This article presents a method for estimating chemical thermodynamic constants from experimental data using the two computer programs UCODE_2005 and PHREEQC. As an example, the conditional stability constant for lead (Pb) complexation by a remediation agent (carboxymethyl-beta-cyclodextrin) is estimated, but the method can be applied to estimate other thermodynamic parameters such as sorption constants and degradation rate constants. Advantages of this technique include estimation of uncertainties associated with estimated parameters, evaluation of information content of observations, statistical evaluation of the appropriateness of the conceptual model, and statistical-based comparison of different models.     

Developing the ability to model acid-rock interactions and mineral dissolution during the RMA stimulation test performed at the Soultz-sous-Forêts EGS site,France

The Soultz Enhanced Geothermal System (EGS) reservoir's response to chemical stimulation is assessed by numerical simulation of coupled thermo-hydraulic-chemical processes. To assess chemical interactions between host rocks and a mixture of HCl and HF as well as its potential effects on the Soultz EGS reservoir, new modelling efforts using the FRACHEM code have been initiated. This article presents the model calibration and results. Simulations consider realistic conditions with available data sets from the EGS system at Soultz. Results indicate that the predicted amount of fracture sealing minerals dissolved by injection of a mixture of acids Regular Mud Acid (RMA) was consistent with the estimated amount from the test performed on GPK4 well at Soultz EGS site. Consequently reservoir porosity and permeability can be enhanced especially near the injection well by acidizing treatment.     

The Nature of Tungstenite of the Bystrinskoe Porphyry-Skarn Au–Fe–Cu Deposit (Eastern Transbaikalia,Russia)

Doklady Earth Sciences - Tungstenite of unusual shapes (spheroids, rings, threads, spirals, etc.) was found in scheelite of gold-bearing quartz–carbonate–pyrite–chalcopyrite...     

Identification of buried sinkholes using refraction tomography at Ft. Campbell Army Airfield,Kentucky

Karst aquifers are highly susceptible to contamination, with numerous points of entry for contaminants through recharge features such as sinkholes, swallow holes and solutionally enlarged fractures. These recharge features may be filled or obscured at the surface, requiring the use of geophysical or remote sensing techniques for their identification. This study uses seismic refraction data collected at the Ft. Campbell Army Airfield (CAAF), Kentucky, USA, to test the hypothesis that refraction tomography is a useful tool for imaging bedrock depressions beneath thick overburden (greater than 20 m of unconsolidated sediment). Southeast of the main taxiway of CAAF seismic velocity tomograms imaged a bedrock low, possibly a closed depression, at a depth of 25 m that had been earlier identified through delay-time analysis of the same refraction data. Tomography suggests the bedrock low is about 250-m wide by 10-m deep at its widest point. High rates of contaminant vapor extraction over the western extension of this feature suggest a high concentration of contaminants above, and within, this filled bedrock low, the base of which may contain solutionally enlarged fractures (i.e. karst conduits) that could funnel these contaminants to the upper or lower bedrock aquifers. This study thus demonstrates the viability of seismic refraction tomography as a tool for identification of filled sinkholes and bedrock depressions in karst areas.     

Palaeomagnetic results from the ca. 1130 Ma Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, Antarctica, and tectonic implications

Detailed palaeomagnetic and rock magnetic analyses provide improved palaeomagnetic results from 23 sites in the Borgmassivet intrusions in the Ahlmannryggen region of Dronning Maud Land, East Antarctica. These intrusions are of similar age to their host, the ca. 1130 Ma Ritscherflya Supergroup (RSG). A mean direction of D=235.4°, I=−7.6° with k=45.9 and α₉₅=4.5° was obtained from this study. When combined with previously reported results from 11 sites in the same region, including sites from the Ritscherflya Supergroup, it gives an overall mean direction for 34 sites from the igneous suite with D=236.5°, I=−3.6°, k=27.9 and α₉₅=4.8°. Isothermal remanent magnetization (IRM) experiments on several specimens suggest magnetite or titanomagnetite as the primary remanence carrier, while high temperature magnetic susceptibility experiments indicate the presence of single domain particles. These observations, together with field evidence and the high coercivities and unblocking temperatures, support a primary origin for the observed characteristic remanence. The Borgmassivet palaeomagnetic pole lies at 54.5°E, 8.3°N with A₉₅=3.3°. If Antarctica is moved to its Gondwanan position adjacent to southeast Africa, the Borgmassivet pole (BM) coincides with that of the African well-established, well-dated (1100 Ma) Umkondo Large Igneous Province pole, supporting the hypothesis that the Grunehogna craton of Dronning Maud Land was part of the Kalahari craton of southern Africa at ca. 1100 Ma.     

Reconstruction of long-term precipitation records for Edinburgh: an examination of the mechanisms responsible for temporal variability in precipitation

Summary Recent dry years (combined dry winter and summer months) within the UK (2005 and 2006) have enhanced concerns relating to long term water resources and future water provision in large conurbations. This paper examines the mechanisms responsible for precipitation variability for five different areas in Edinburgh (precipitation regions) using composite historic precipitation records for the period 1861–2005. Trend analysis and principal component analysis (PCA) were undertaken to examine precipitation variability over time and space. Annual correlation co-efficients were derived for relationships between precipitation areas, atmospheric–oceanographic variations and geographic parameters. Stepwise regression models were constructed to specify annual precipitation, through atmospheric variations, for each of the precipitation areas. Significant downward trends in precipitation (p < 0.05) were noted in two out of the five precipitation areas, with one principal component representing precipitation variability over Edinburgh and the Pentland Hills. Precipitation variability is best explained by fluctuations in pressure, altitude and proximity to coast. Precipitation trends cannot be explained by changes in atmospheric circulation patterns. Authors’ addresses: N. Macdonald, Department of Geography, University of Liverpool, Liverpool L69 7ZT, United Kingdom; I. D. Phillips, J. Thorpe, School of Geography, Earth and Environmental Sciences, University of Birmingham, Edgbaston B15 2TT, United Kingdom.     

Does continental crust transform during eclogite facies metamorphism?

Eclogites within exhumed continental collision zones indicate regional burial to depths of at least 60 km, and often more than 100 km in the coesite‐stable, ultra‐high pressure (UHP) eclogite facies. Garnet, omphacitic pyroxene, high‐Si mica, kyanite ± coesite should grow at the expense of low‐P minerals in most felsic compositions, if equilibrium obtained at these conditions. The quartzofeldspathic rocks that comprise the bulk of eclogite facies terranes, however, contain mainly amphibolite facies, plagioclase‐bearing assemblages. To what extent these lower‐P minerals persisted metastably during (U)HP metamorphism, or whether they grew afterwards, reflects closely upon crustal parameters such as density, strength and seismic character. The Nordfjord area in western Norway offers a detailed view into a large crustal section that was subducted into the eclogite facies. The degree of transformation in typical pelite, paragneiss, granitic and granodioritic gneiss was assessed by modelling the equilibrium assemblage, comparing it with existing parageneses in these rocks and using U/Th–Pb zircon geochronology from laser ablation ICPMS to establish the history of mineral growth. U–Pb dates define a period of zircon recrystallization and new growth accompanying burial and metamorphism lasting from 430 to 400 Ma. Eclogite facies mafic rock (~2 vol.% of crust) is the most transformed composition and records the ambient peak conditions. Rare garnet‐bearing pelitic rocks (<10 vol.% of crust) preserve a mostly prograde mineral evolution to near‐peak conditions; REE concentrations in zircon indicate that garnet was present after 425 Ma and feldspar broke down after 410 Ma. Felsic gneiss – by far the most abundant rock type – is dominated by quartz + biotite + feldspar, but minor zoisite/epidote, phengitic white mica, garnet and rutile point to a prograde HP overprint. Relict textures indicate that much of the microstructural framework of plagioclase, K‐feldspar, and perhaps biotite, persisted through at least 25 Ma of burial, and ultimately UHP metamorphism. The signature reaction of the eclogite facies in felsic rocks – jadeite/omphacite growth from plagioclase – cannot be deduced from the presence of pyroxene or its breakdown products. We conclude that prograde dehydration in orthogneiss leads to fluid absent conditions, impeding equilibration beyond ~high‐P amphibolite facies.