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191.
  总被引:3,自引:0,他引:3  
Samples of Calanus hyperboreus, a herbivorous copepod, were collected (n = 20) between April and July 1998, and water samples (n = 6) were collected in May 1998, in the Northwater Polynya (NOW) to examine persistent organic pollutants (POPs) in a high Arctic marine zooplankton. Lipid content (dry weight) doubled, water content (r2 = 0.88) and delta15N (r2 = 0.54) significantly decreased, and delta13C significantly increased (r2 = 0.30) in the C. hyperboreus over the collection period allowing an examination of the role of these variables in POP dynamics in this small pelagic zooplankton. The rank and concentrations of POP groups in C. hyperboreus over the entire sampling was sum of PCB (30.1 +/- 4.03 ng/g, dry weight) > sum of HCH (11.8 +/- 3.23) > sum of DDT (4.74 +/- 0.74), sum of CHLOR (4.44 +/- 1.0) > sum of CIBz (2.42 +/- 0.18), although these rankings varied considerably over the summer. The alpha- and gamma-HCH and lower chlorinated PCB congeners were the most common POPs in C. hyperboreus. The relationship between bioconcentration factor (BCF) and octanol-water partition coefficient (Kow) observed for the C. hyperboreus was linear and near 1:1 (slope = 0.72) for POPs with a log Kow between 3 and 6 but curvilinear when hydrophobic POPs (log Kow > 6) were included. Concentrations of sum of HCH. Sum of CHLOR and sum of CIBz increased over the sampling period, but no change in sum of PCB or sum of DDT was observed. After removing the effects of time, the variables lipid content, water content, delta15N and delta13C did not describe POP concentrations in C. hyperboreus. These results suggest that hydrophobic POP (log Kow = 3.86.0) concentrations in zooplankton are likely to reflect water concentrations and that POPs do not biomagnify in C. hyperboreus or likely in other small, herbivorous zooplankton.  相似文献   
192.
The cracked chevron notched Brazilian disc (CCNBD) specimen has been suggested by International Society for Rock Mechanics for measuring mode I fracture toughness of rocks. Subsequently, this specimen geometry has been widely extended to conduct mixed mode fracture tests on rocks as well. A straight through crack front during the fracturing process upon the root of the chevron notch is assumed in the testing principle, but has never been thoroughly evaluated before. In this study, for the first time, the progressive rock fracture mechanism of the CCNBD rock specimen under mixed mode loading is numerically simulated. Specimens under representative mixed mode loading angles are modelled; and the assumption of the straight through crack front growth is critically assessed. The results show that not only the notch tip but also the saw-cut chevron notch cracks during the experiments, yielding a prominent twisted front, far from being straight. The crack front never grows up to the root of the notch ligament and the straight through crack front assumption is never satisfied in the realistic rock fracture progress of this chevron notched specimen subjected to mixed mode loads. In contrast, the fracture progress features typical three-dimensional wing cracking towards the loading ends. The numerically observed progressive fracture mechanism reveals that the measuring principle of mixed mode fracture tests employing CCNBD specimens is significantly violated and the measures of both modes I and II fracture toughness are uncertain.  相似文献   
193.
Six samples were collected from a section of Peoria Loess in Eustis, North America, for optically stimulated luminescence (OSL) dating of quartz, and all except one (LV90) produced narrow dose distributions. A comparative study was conducted on this sample and on a ‘well-behaved’ sample (LV91), involving other dating methods and examination of the quartz OSL. These investigations revealed differences in the quartz OSL growth with dose, OSL response to thermal treatments and the range of components within the OSL signals. An ultra-fast component was found in LV90 that displayed a higher rate of sensitivity change than the fast component and this had a malign influence on the determination of the equivalent dose. The distinctive luminescence characteristics of LV90 imply either a change in wind dynamics and/or the source area for the silt.  相似文献   
194.
This paper investigates hydrothermal fluid circulation in pre- and syn-tectonic sediments associated with detachments faults. The study area, located in the Err Nappe (SE-Switzerland), preserves a portion of the Adriatic distal margin. Two sites were studied in combining fieldwork, petrography, geochemistry and fluid inclusion analysis: the Piz Val Lunga and Fuorcla Cotschna areas. Both preserve relationships between a spectacularly exposed rift-related extensional detachment fault and its footwall and hangingwall that consist of extensional allochthons and syn- to post-tectonic sediments. These areas register a complex fluid flow history characterized by dolomitization, de-dolomitization, calcite cementation, dolomite and quartz veining and diffuse silicification. Meso- and micro-scale observations allow defining two steps in fluid evolution, which are related to Jurassic rift activity. A first carbonate-rich event occurred before the exhumation of the granitic basement, and this was followed by a second event marked by a change in the fluid towards a silica-dominated chemistry. Homogenization temperatures of fluid inclusions (average Th = 120?130 °C), negative δ18O values and a radiogenic 87Sr/86Sr signatures of carbonate minerals support the hypothesis that both the pre-tectonic rocks constituting the allochthons and the syn-tectonic sediments overlying the detachment fault were crossed by a flux of over-pressured hydrothermal fluids originating from seawater that penetrated into the basement through fault and fracture systems. Field relationships show that this fluid circulation started latest in middle Early Jurassic time, when fault activity migrated from the proximal to the future distal margin. We propose that it evolved chemically as a result of the involvement of the granitic basement forming the footwall of the extensional detachment system. Hydrothermal activity continued until the Middle/Late Jurassic, when tectonic activity shifted outwards leading to the exhumation of mantle rocks. This paper provides an original contribution to better understand the complex evolution of hyperextended continental rift domains and to constrain their thermal regimes.  相似文献   
195.
196.
The frequency of nuisance algal blooms has been increasing during the last two decades in the shallow, headwater East Pond (Smithfield, Maine, USA). Meanwhile, the hydrologically linked North Pond has not experienced an increase in algal blooms, despite similar morphometry and higher external nutrient loads. Possible explanations for this difference include stronger trophic cascade effects from planktivorous white perch (Morone americana) in East Pond as well as differences in phosphorus (P) release from the sediments of these two lakes. We conducted a paleolimnological investigation of these two lakes to assess whether sedimentary evidence supported trophic cascade effects based on cladoceran ephippia size, diatom fossils, and fossil pigments or biogeochemical controls based on potential sedimentary P release as the primary driver of these increased algal blooms in East Pond. At the time of white perch introduction (~1930–1950), ephippia size increases in East Pond, although no changes are observed in either diatom abundance or trends in the algal pigments. Instead, algal pigments increase in recent decades (~1980 to present) along with an increase in diatom taxa with higher TP optima These results suggest that predation by white perch is not resulting in top-down effects on algal abundance in East Pond, as predicted by the trophic cascade hypothesis. While the P content of sediments from both lakes is relatively equal, the releasable P in the top 10 cm of sediment in East Pond constitutes a greater percentage of the P extracted. Also, North Pond sediments exhibit a greater capacity to permanently bury P via the mechanisms of sorption to Al(OH)3(s) and a slower mineralization of organic P compounds. The results of this investigation suggest that the ultimate driver of the recent algal blooms in East Pond is internal P release from the sediments instead of trophic cascade effects.  相似文献   
197.
The Regional Ocean Modeling System (ROMS) 4-dimensional variational (4D-Var) data assimilation systems have been systematically applied to the mesoscale circulation environment of the California Current to demonstrate the performance and practical utility of the various components of ROMS 4D-Var. In particular, we present a comparison of three approaches to 4D-Var, namely: the primal formulation of the incremental strong constraint approach; the dual formulation “physical-space statistical analysis system”; and the dual formulation indirect representer approach. In agreement with theoretical considerations all three approaches converge to the same ocean circulation estimate when using the same observations and prior information. However, the rate of convergence of the dual formulation was found to be inferior to that of the primal formulation. Other aspects of the 4D-Var performance that relate to the use of multiple outer-loops, preconditioning, and the weak constraint are also explored. A systematic evaluation of the impact of the various components of the 4D-Var control vector (i.e. the initial conditions, surface forcing and open boundary conditions) is also presented. It is shown that correcting for uncertainties in the model initial conditions exerts the largest influence on the ability of the model to fit the available observations. Various important diagnostics of 4D-Var are also examined, including estimates of the posterior error, the information content of the observation array, and innovation-based consistency checks on the prior error assumptions. Using these diagnostic tools, we find that more than 90% of the observations assimilated into the model provide redundant information. This is a symptom of the large percentage of satellite data that are used and to some extent the nature of the data processing employed. This is the second in a series of three papers describing the ROMS 4D-Var systems.  相似文献   
198.
Quantifying land use patterns and functions is critical for modeling urban ecological processes, and an emerging challenge is to apply models at multiple spatial scales. Methods of determining the optimum scale of land use patterns are commonly considered using landscape metrics. Landscape metrics are quantitative indicators for analyzing landscape heterogeneity at the landscape level. In this study, due to their widespread use in urban landscape analyses and well-documented effectiveness in quantifying landscape patterns, landscape metrics that represent dominance, shape, fragmentation and connectivity were selected. Five metrics include Patch Density, Contagion, Landscape Shape Index, Aggregation Index and Connectivity. Despite a wide application of landscape metrics for land use studies, the majority mainly focuses on the qualitative analysis of the characteristics of landscape metrics. The previous models are limited in exploring the optimum scale of land use patterns for their lack of quantitation. Therefore, taking the City of Wuhan as an example, the land use unit was treated as a patch, and the landscape pattern metrics at different spatial scales were calculated and compared so as to find the optimum one. Furthermore, a mathematical model of landscape metrics was proposed to quantify the scale effect of urban land use patterns, generating a complementary tool to select the optimum scale. In addition, Analytic Hierarchy Process (AHP) was introduced to determine the respective weights of the chosen landscape metrics in this model. Fractal dimension was ultimately applied to verify the chosen optimum scale of our study region. The results indicated that 60 m is confirmed to be the optimum scale for capturing the spatial variability of land use patterns in this study area.  相似文献   
199.
Man-made land or islands that are reclaimed from the sea are suitable for building airports, harbors, and industry parks for material transportation because of their broad air and land spaces. However, the reclaimed foundation settlement process is of public concern, including the continuous impact of ocean processes on its stability. The majority of the buildings and facilities of Hong Kong International Airport (HKIA) are built on a reclaimed foundation. The reclaimed foundation has been in residual settlement since completion of the filling project in 1994. In this study, we use persistent scatterer interferometry (PSI) and ENVISAT (European Satellite) advanced synthetic aperture radar (ASAR) data to detect the residual settlement rates from 19 April 2006 to 9 January 2008. We use ground truth data to develop empirical correction models for correcting systematic biases in the ASAR PSI-detected settlement rates. The corrected data follow the Lorentz distribution well, implying that the residual settlement process is dominated by two modes or categories of settlement rates. The first category represents a relatively stable state and the second category represents a continuous settlement state. A ground settlement rate map of HKIA shows that an area of the Passenger Terminal Building and an area of the Southern Runway are two relatively stable areas. There are two major continuous settlement areas. One covers the airport Midfield. Another is along the coastline, implying that attention should be paid to impacts of ocean processes on the stability of airport foundations.  相似文献   
200.
In Daye Iron Mine, the open-pit mining has ended and the underground mining started in 2003. The present pit slopes are as high as 430 m and the slope angle is up to 43°. During the process of open-pit to underground mining, the high-steep pit slopes would be affected by both open-pit mining and underground mining, and its deformation characteristics would become more complex. So in this paper, the trinity method of numerical simulation, model experiment and field test was adopted to analyze the displacement and stress fields systematically. The results show that: (1) Prominent rebound deformation occurs near the slope foot, which is induced by the unloading in open-pit mining. When it is backfilled to 0 m level, the rebound deformation decreases, which indicate that backfilling mass can restrict the deformation and improve the slope stability; (2) Subsidence dominates the slope deformation in open-pit to underground mining and it increases with an increasing elevation of monitoring point; the maximum horizontal displacement occurs in the lower part of the slopes, because the backfilled part is squeezed by both the north slope and the south slope, and it has a lower elastic modulus than the previous orebody; (3) The stress and its variability near the slope foot are much larger than other places, indicating that the slope foot is most affected by stress redistribution and stress concentration may occur here; the stress at other stress monitoring points changes little, indicating that the influence of open-pit to underground mining is local; (4) The effect of underground mining on the deformation of the faults is not prominent; (5) Mining operations in near-ground part affect more on the variation of deformation and stress of pit slopes than that in deeper part.  相似文献   
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