Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.     

Fishers' responses to management measures and their socio-economic effects

This session presented a wide range of papers on cooperativeresearch, design of alternative gears and fishing strategies,and new analyses to support management. The contributed papersreflected a real desire to explore different approaches andstrategies to fishery management. It is apparent that fishery policy has had a mixed record ofsuccess and failure at best. In most regions of the world, manystocks are still being overfished or have been severely overfishedin the past. Although rebuilding programmes for overfished stockshave been developed, nationally as well as internationally,only a few have been successful, many others are works in progressand, in too many cases, rebuilding     

Isotopic and Elemental Variations of Carbon and Nitrogen in a Mangrove Estuary

Variations in elemental and isotopic ratios of suspended particulate matter (SPM) were investigated in the Guayas River Estuary Ecosystem (GREE) that empties into the Gulf of Guayaquil, Ecuador. Detritus in the system was identified on the basis of extremely high carbon:chlorophyll aratios (>1000). This material had mean δ¹³C of −26·4±0·3, δ¹⁵N of +4·8±0·2, and (C:N)_atomicof 14·1±0·9. The isotopic data were comparable to measurements reported for fresh and degrading mangrove leaves, whereas the elemental ratio was comparatively enriched in nitrogen. Isotope measurements of SPM throughout the GREE were more similar to values for riverine material and detritus compared with that for the coastal end-member. Values indicative ofin situproduced algae, sewage and shrimp pond effluent were only found at selected sites. Bacterial bioassays, which were used to document potential sources of dissolved organic matter in the GREE, were isotopically similar to SPM. This correspondence coupled with the relatively low (C:N)_aof SPM could be explained by bacterial immobolization of nitrogen onto detritus. Finally, tidal variations of (C:N)_aand δ¹³C at a brackish mangrove site were similar in magnitude to spatial variations encountered throughout the GREE. Based on these results, the authors caution that care must be taken when samples are taken for food-web studies in these systems.     

The capacity of marine plankton, macrophytes and particulate matter to adsorb Cu in the presence of Mg

A complexometric titration technique was employed to measure the total capacity of a variety of marine organisms to adsorb Cu²⁺. Measured adsorption capacities were 0.22 meq g⁻¹ for phytoplankton, 0.3–1.0 meq g⁻¹ for macrophytes, 1.0–2.5 meq g⁻¹ for zooplankton and 0.3 meq g⁻¹ for suspended particulate matter. The capacity of these materials to adsorb Cu²⁺ was reduced significantly in the presence of Mg²⁺ at seawater concentrations. Competition between Mg^t2+ and Cu²⁺ for adsorption sites at pH 6 is described by an average conditional equilibrium constant of 10^3.7. This constant is such that very little Cu²⁺ may be adsorbed onto particulates and marine phytoplankton in the presence of Mg²⁺. Further, primary productivity data and estimates of the detrital carbon sedimentation in Long Island Sound suggest that the flux of particulate carbon is insufficient to remove significant amounts of Cu from the water column to sediments by adsorption mechanisms.     

An Annotated Check-List of Planktonic Diatoms from the Gulf of Naples

Abstract. New data on the planktonic diatoms from the Gulf of Naples are presented together with those from the literature. Information is given on abundances, seasonal cycles and distributions of 183 taxa, including species, varieties and forms.     

Hydrothermal Metalliferous Sediments and Waters Off the Lesser Antilles

Considerable metal enrichments have been found in hydrothermal fluids and metalliferous sediments off the central Lesser Antilles Volcanic Arc. The elements variably enriched in the fluids as a result of the hydrothermal activity are Fe, Mn, As, Si, B, Li and in the sediments, Fe, P, Mo, As, Sb, Hg, Cu and Pb. Variations in the concentrations of these elements in both fluids and sediments along the arc result from a number of factors, the most important of which is the stage that each island's volcano has reached in its eruptive cycle. Although hydrothermal mineralization on the sea floor off the islands is only low grade, phase separation in the hydrothermal fluids at depth could be leading to higher grade stockwork mineralization below the vent fields or the discharge of metal rich brines on the lower flanks of the volcanic islands.     

A hypothesis for the formation of a mud bank in the Gulf of Papua

The riverine mud that escapes retention in the estuaries and enters the Gulf of Papua appears to be transported southeastward, across depth contours, by the prevailing currents in a series of wind-driven events. The mud deposits to the southeast of the rivers, at the mid-shelf region within a depth range of 40–60 m. Mud transported farther eastward is carried down the continental rise. Coarser riverine sediment (silt and sand) is deposited closer inshore. On the outer shelf (depth >60 m) relict carbonate debris dominates. The area of mud has maximum rates of pelagic and benthic productivity in the gulf.     

A detailed geochemical and rock magnetic study of dredged basalt from the Sheba Ridge,Gulf of Aden

We report the results of petrological, geochemical and rock magnetic studies of basalt dredged from the eastern end of the west Sheba Ridge during cruise 11/1979 of R. R. S. Shackleton to the Western Gulf of Aden. The ridge is part of the Red Sea-Gulf of Aden spreading axis and the basalts are olivine tholeiites. The abundances of some elements are characteristic of normal MORB (mid-ocean ridge basalt) but other elemental abundances suggest affinites with transitional-type MORB.The observed magnetic properties are interpreted in terms of the composition, concentration and microstructure of the magnetic mineral fraction by recourse to the available data on synthetic analogues. The analysis has been carried out in greater detail than has been attempted in previous magneto-petrological studies. It appears that submarine weathering of the magnetic minerals (maghemitization) brings about not only the expected change in composition but also a fall in concentration of the magnetic fraction. This could result from the removal-of-iron oxidation mechanism operating in the submarine environment. It is also found that the fall in remanence with increasing degree of maghemitization is not explicable in terms of the change in composition and concentration of the magnetic minerals. A further influence—probably microstructural change—significantly reduces the remanence intensity.     

Magnetic anomalies in the canary basin and the Mesozoic evolution of the central North Atlantic

The data from a recent magnetic compilation by Verhoefet al. (1991) off west Africa were used in combination with data in the western Atlantic to review the Mesozoic plate kinematic evolution of the central North Atlantic. The magnetic profile data were analyzed to identify the M-series sea floor spreading anomalies on the African plate. Oceanic fracture zones were identified from magnetic anomalies and seismic and gravity measurements. The identified sea floor spreading anomalies on the African plate were combined with those on the North American plate to calculate reconstruction poles for this part of the central Atlantic. The total separation poles derived in this paper describe a smooth curve, suggesting that the motion of the pole through time was continuous. Although the new sea floor spreading history differs only slightly from the one presented by Klitgord and Schouten (1986), it predicts smoother flowlines. On the other hand, the sea floor spreading history as depicted by the flowlines for the eastern central Atlantic deviates substantially from that of Sundvik and Larson (1988). A revised spreading history is also presented for the Cretaceous Magnetic Quiet Zone, where large changes in spreading direction occurred, that can not be resolved when fitting magnetic isochrons only, but which are evident from fracture zone traces and directions of sea floor spreading topography.Deceased 11 November 1991