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Jennifer P. Cannizzaro Kendall L. Carder F. Robert Chen Cynthia A. Heil Gabriel A. Vargo 《Continental Shelf Research》2008
Karenia brevis, a toxic dinoflagellate that blooms regularly in the Gulf of Mexico, frequently causes widespread ecological and economic damage and can pose a serious threat to human health. A means for detecting blooms early and monitoring existing blooms that offers high spatial and temporal resolution is desired. Between 1999 and 2001, a large bio-optical data set consisting of spectral measurements of remote-sensing reflectance (Rrs(λ)), absorption (a(λ)), and backscattering (bb(λ)) along with chlorophyll a concentrations and K. brevis cell counts was collected on the central west Florida shelf (WFS) as part of the Ecology and Oceanography of Harmful Algal Blooms (ECOHAB) and Hyperspectral Coastal Ocean Dynamics Experiment (HyCODE) programs. Reflectance model simulations indicate that absorption due to cellular pigmentation is not responsible for the factor of ∼3–4 decrease observed in Rrs(λ) for waters containing greater than 104 cells l−1 of K. brevis. Instead, particulate backscattering is responsible for this decreased reflectivity. Measured particulate backscattering coefficients were significantly lower when K. brevis concentrations exceeded 104 cells l−1 compared to values measured in high-chlorophyll (>1.5 mg m−3), diatom-dominated waters containing fewer than 104 cells l−1 of K. brevis. A classification technique for detecting high-chlorophyll, low-backscattering K. brevis blooms is developed. In addition, a method for quantifying chlorophyll concentrations in positively flagged pixels using fluorescence line height (FLH) data obtained from the Moderate Resolution Imaging Spectroradiometer (MODIS) is introduced. Both techniques are successfully applied to Sea-viewing Wide Field-of-view Sensor (SeaWiFS) and MODIS data acquired in late August 2001 and validated using in situ K. brevis cell concentrations. 相似文献
84.
A. J. Pitman A. Henderson-Sellers C. E. Desborough Z.-L. Yang F. Abramopoulos A. Boone R. E. Dickinson N. Gedney R. Koster E. Kowalczyk D. Lettenmaier X. Liang J.-F. Mahfouf J. Noilhan J. Polcher W. Qu A. Robock C. Rosenzweig C. A. Schlosser A. B. Shmakin J. Smith M. Suarez D. Verseghy P. Wetzel E. Wood Y. Xue 《Climate Dynamics》1999,15(9):673-684
Using atmospheric forcing data generated from a general circulation climate model, sixteen land surface schemes participating
in the Project for the Intercomparison of Land-surface Parametrization Schemes (PILPS) were run off-line to equilibrium using
forcing data from a GCM representative of a tropical forest and a mid-latitude grassland grid point. The values for each land
surface parameter (roughness length, minimum stomatal resistance, soil depth etc.) were provided. Results were quality controlled
and analyzed, focusing on the scatter simulated amongst the models. There were large differences in how the models’ partitioned
available energy between sensible and latent heat. Annually averaged, simulations for the tropical forest ranged by 79 1 3;W m-2 for the sensible heat flux and 80 W m-2 for the latent heat flux. For the grassland, simulations ranged by 34 W m-2 for the sensible heat flux and 27 W m-2 for the latent heat flux. Similarly large differences were found for simulated runoff and soil moisture and at the monthly
time scale. The models’ simulation of annually averaged effective radiative temperature varied with a range, between all the
models, of 1.4 K for tropical forest and 2.2 K for the grassland. The simulation of latent and sensible heat fluxes by a standard
‘bucket’ models was anomalous although this could be corrected by an additional resistance term. These results imply that
the current land surface models do not agree on the land surface climate when the atmospheric forcing and surface parameters
are prescribed. The nature of the experimental design, it being offline and with artificial forcing, generally precludes judgements
concerning the relative quality of any specific model. Although these results were produced de-coupled from a host model,
they do cast doubt on the reliability of land surface schemes. It is therefore a priority to resolve the disparity in the
simulations, understand the reasons behind the scatter and to determine whether this lack of agreement in de-coupled tests
is reproduced in coupled experiments.
Received: 15 October 1997 / Accepted: 22 April 1999 相似文献
85.
A small-scale field test was initiated in September 1994 to evaluate the in situ remediation of groundwater contaminated with chromate using a permeable reactive barrier composed of a mixture of zero-valent Fe, sand and aquifer sediment. The site used was an old chrome-plating facility located on a U.S. Coast Guard air base near Elizabeth City, North Carolina. Dissolved chromate concentrations were reduced to less than 0.01 mg/L via reduction from Cr(VI) to Cr(III) as a result of the corrosion of the Fe. As the Fe corrodes, pH increases, oxidation-reduction potential declines, dissolved oxygen is consumed, and Fe(II) is generated. Mineral phases formed as a result of the Fe corrosion include ferrous sulfides and various Fe oxides, hydroxides, and oxyhydroxides. 相似文献
86.
Temporal and spatial patterns of trace elements in the Patuxent River: A whole watershed approach 总被引:1,自引:0,他引:1
Gerhardt F. Riedel Sherry A. Williams Georgia S. Riedel Cynthia C. Gilmour James G. Sanders 《Estuaries and Coasts》2000,23(4):521-535
Trace element distributions, partitioning, and speciation were examined at 15 sites in the Patuxent River watershed from May 1995 through October 1997 to determine possible sources of trace elements to the river and estuary, to examine the relationship of the trace element discharges to freshwater discharges as well as to land use and geographic region, to validate previous estimates of loadings to the river, and to provide baseline data for trace elements in the Patuxent River watershed and estuary. Six freshwater sites were examined, representing different basins and geographic provinces, and nine sites along the estuarine salinity gradient. Subregions within the watershed varied considerably in concentrations and areal yields for some elements. Concentrations of As, Cd, Ni, Pb, and Zn were elevated in the Coastal Plain sites compared to the Piedmont sites, while Cu and Hg were more evenly distributed. Cadmium, Cu, Hg, Ni, Pb, and Zn showed overall positive correlations with river flow while As and methylHg (meHg) showed negative correlations with river flow. Concentrations of trace elements in the estuarine portion of the river were generally low, and consistent with mixing between Patuxent River water with elevated concentrations and the lower concentrations of the Chesapeake Bay. Interesting features included a local Cd maximum in the low salinity region of the estuary, probably caused by desorption from suspended sediments, and a significant input of water containing high As concentrations from the Chesapeake Bay and from As being released from bottom sediments in summer. Comparisons between the estimated annual flux of trace elements and the estimates of suspected source terms (atmospheric deposition, urban runoff, and known point sources) suggest that, except for Hg, direct atmospheric deposition is small compared to fluvial loads. Current estimates of trace element inputs from point sources or from urban runoff are inadequate for comparison with other sources, because of inappropriate techniques and/or unacceptably high detection limits. A complete examination of trace element dynamics in the Patuxent River (and in other coastal systems) will require better data for these potential sources. 相似文献
87.
Franklin W. Schwartz Ganming Liu Pradeep Aggarwal Cynthia M. Schwartz 《Ground water》2017,55(5):703-711
Concepts of simplicity and complexity in modeling have been explored in papers, editorials, and talks. The concept is not well understood because there are at least two flavors of simplicity. Modelers envision simplicity (i.e., elegant simplicity) as the sought‐after goal in modeling, but naïve simplicity, which is the focus of this paper, is commonly unrecognized and dangerous. The problem is that naïve or simple ideas are often mistaken for settled science and come with the prospect of being more wrong than right. The concept of the so‐called simplicity cycle, in relation to classical problems of carbon‐14 age and salinity in closed‐basin lakes, is used to illustrate these points. The emerging problems of water‐mosquitoes‐diseases show the value of mapping new problems to the simplicity cycle. Researchers can “know what they do not know” and avoid the dangers of naïve simplicity. 相似文献
88.
89.
Diurnal-period internal waves were observed near Point Conception California, using an array of moorings extending 120 km along the inner shelf. The waves have an along-shelf coherence scale of at least 50 km, and appear to propagate nearly straight onshore. Wave amplitudes vary over time, depending on thermal stratification and the amplitude of the diurnal sea breeze oscillation. Barotropic tides and vorticity over the mid-shelf are not correlated with internal wave amplitude. Large amplitude internal waves, with supercritical Froude numbers, are observed in mid-summer. Although such waves may drive vertical mixing and cross-shelf transport of passive particles, there is no significant correlation between wave amplitude and invertebrate settlement in the Santa Barbara Channel. 相似文献
90.
Phytoplankton community structure in coastal areas is a result of various environmental factors such as nutrients, light, grazing, temperature, and salinity. The Yucatan Peninsula is a karstic tropical region that is strongly influenced by submerged groundwater discharge (SGD) into the coastal zone. Phytoplankton community structure and its relationship with regional and local water quality variables were studied in four ports of the northwestern Yucatan Peninsula. Water quality was strongly related to SGD, and variations in phytoplankton community structure were related to local nutrient loading and hydrographic conditions, turbulence, and human impacts. Our study provides an ecological baseline for the Yucatan Peninsula and serves as a basis for establishing monitoring programs to predict changes at sites with high hydrological variation and in developing an early alert system for harmful toxic algal blooms. 相似文献