Calculations of river-runoff in the GISS GGM: impact of a new land-surface parameterization and runoff routing model on the hydrology of the Amazon River

This study examines the impact of a new land-surface parameterization and a river routing scheme on the hydrology of the Amazon basin, as depicted by the NASA/Goddard Institute of Space Studies (GISS) global climate model (GCM). The more physically realistic land surface scheme introduces a vegetation canopy resistance and a six-layer soil system. The new routing scheme allows runoff to travel from a river's headwater to its mouth according to topography and other channel characteristics and improves the timing of the peak flow. River runoff is examined near the mouth of the Amazon and for all of its sub-basins. With the new land-surface parameterization, river run-off increases significantly and is consistent with that observed in most basins and at the mouth. The representation of the river hydrology in small basins is not as satisfactory as in larger basins. One positive impact of the new land-surface parameterization is that it produces more realistic evaporation over the Amazon basin, which was too high in the previous version of the GCM. The realistic depiction of evaporation also affects the thermal regime in the lower atmosphere in the Amazon. In fact, the lower evaporation in some portions of the basin reduces the cloudiness, increases the solar radiation reaching the ground, increases the net radiation at the surface, and warms the surface as compared to observations. Further GCM improvement is needed to obtain a better representation of rainfall processes.     

Evaluating data stability in aggregation structures across spatial scales: revisiting the modifiable areal unit problem

ABSTRACT

Socioeconomic and health analysts commonly rely on areally aggregated data, in part because government regulations on confidentiality prohibit data release at the individual level. Analytical results from areally aggregated data, however, are sensitive to the modifiable areal unit problem (MAUP). Levels of aggregation as well as the arbitrary and modifiable sizes, shapes, and arrangements of zones affect the validity and reliability of findings from analyses of areally aggregated data. MAUP, long acknowledged, remains unresolved. We present an exploratory spatial data analytical approach (ESDA) to understand the scalar effects of MAUP. To characterize relationships between data aggregation structures and spatial scales, we develop a method for statistically and visually exploring the local indicators of spatial association (LISA) exhibited between a variable and itself across varying levels of aggregation. We demonstrate our approach by analyzing the across-scale relationships of aggregated 2010 median income for the State of Pennsylvania and 2005–2009 cancer diagnosis rates for the State of New York between county–tract, tract–block group, and county–block group level US census designated enumeration units. This method for understanding the relationship between MAUP and spatial scale provides guidance to researchers in selecting the most appropriate scales to aggregate, analyze, and represent data for problem-specific analyses.     

Assessment of the UV camera sulfur dioxide retrieval for point source plumes

Digital cameras, sensitive to specific regions of the ultra-violet (UV) spectrum, have been employed for quantifying sulfur dioxide (SO₂) emissions in recent years. The instruments make use of the selective absorption of UV light by SO₂ molecules to determine pathlength concentration. Many monitoring advantages are gained by using this technique, but the accuracy and limitations have not been thoroughly investigated. The effect of some user-controlled parameters, including image exposure duration, the diameter of the lens aperture, the frequency of calibration cell imaging, and the use of the single or paired bandpass filters, have not yet been addressed. In order to clarify methodological consequences and quantify accuracy, laboratory and field experiments were conducted. Images were collected of calibration cells under varying observational conditions, and our conclusions provide guidance for enhanced image collection. Results indicate that the calibration cell response is reliably linear below 1500 ppm m, but that the response is significantly affected by changing light conditions. Exposure durations that produced maximum image digital numbers above 32 500 counts can reduce noise in plume images. Sulfur dioxide retrieval results from a coal-fired power plant plume were compared to direct sampling measurements and the results indicate that the accuracy of the UV camera retrieval method is within the range of current spectrometric methods.     

Optima系列电感耦合等离子体-发射光谱法测定啤酒中多元素

~~Optima系列电感耦合等离子体-发射光谱法测定啤酒中多元素@Hergenreder Randy$PerkinElmer Life and Analytical Sciences,710 Bridgeport Avenue,Shelton,CT 06484,USA@Bosnak Cynthia P$PerkinElmer Life and Analytical Sciences,710 Bridgeport Avenue,Shelton,CT 06484,USA[1]Ch airman D Sedin Elemental an alysis of beer and wort by i     

Nutrient availability in support of Karenia brevis blooms on the central West Florida Shelf: What keeps Karenia blooming?

Identifying nutrient sources, primarily nitrogen (N) and phosphorus (P), sufficient to support high biomass blooms of the red tide dinoflagellate, Karenia brevis, has remained problematic. The West Florida Shelf is oligotrophic, yet populations >10⁶ cells L⁻¹ frequently occur and blooms can persist for months. Here we examine the magnitude and variety of sources for N and P that are available to support blooms. Annual average in situ or background concentrations of inorganic N in the region where blooms occur range 0.02–0.2 μM while inorganic P ranges 0.025–0.24 μM. Such concentrations would be sufficient to support the growth of populations up to ∼3×10⁴ cells L⁻¹ with at least a 1 d turnover rate. Organic N concentrations average 1–2 orders of magnitude greater than inorganic N, 8–14 μM while organic P concentrations average 0.2–0.5 μM. Concentrations of organic N are sufficient to support blooms >10⁵ cells L⁻¹ but the extent to which this complex mixture of N species is utilizable is unknown. Other sources of nutrients included in our analysis are aerial deposition, estuarine flux, benthic flux, zooplankton excretion, N₂-fixation, and subsequent release of organic and inorganic N by Trichodesmium spp., and release of N and P from dead and decaying fish killed by the blooms. Inputs based on atmospheric deposition, benthic flux, and N₂-fixation, were minor contributors to the flux required to support growth of populations >2.6×10⁴ cells L⁻¹. N and P from decaying fish could theoretically maintain populations at moderate concentrations but insufficient data on the flux and subsequent mixing rates does not allow us to calculate average values. Zooplankton excretion rates, based on measured zooplankton population estimates and excretion rates could also supply all of the N and P required to support populations of 10⁵ and 10⁶ cells L⁻¹, respectively, but excretion is considered as “regenerated” nutrient input and can only maintain biomass rather than contribute to “new” biomass. The combined estuarine flux from Tampa Bay, Charlotte Harbor, and the Caloosahatchee River can supply a varying, but at times significant level of N and P to meet growth and photosynthesis requirements for populations of approximately 10⁵ cells L⁻¹ or below. Estimates of remineralization of dead fish could supply a significant proportion of bloom maintenance requirements but the rate of supply must still be determined. Overall, a combination of sources is required to maintain populations >10⁶ cells L⁻¹.     

Zooplankton and Karenia brevis in the Gulf of Mexico

Blooms of the toxic dinoflagellate Karenia brevis are common in the Gulf of Mexico, yet no in situ studies of zooplankton and K. brevis have been conducted there. Zooplankton abundance and taxonomic composition at non-bloom and K. brevis bloom stations within the Ecology of Harmful Algal Blooms (ECOHAB) study area were compared. At non-bloom stations, the most abundant species of zooplankton were Parvocalanus crassirostris, Oithona colcarva, and Paracalanus quasimodo at the 5-m isobath and P. quasimodo, O. colcarva, and Oikopleura dioica at the 25-m isobath. There was considerable overlap in dominance of zooplankton species between the 5 and 25-m isobaths, with nine species contributing to 90% of abundance at both isobaths. At stations within K. brevis blooms however, Acartia tonsa, Centropages velificatus, Temora turbinata, Evadne tergestina, O. colcarva, O. dioica, and P. crassirostris were dominant. Variations in abundance between non-bloom and bloom assemblages were evident, including the reduction in abundance of three key species within K. brevis blooms.     

Eddies and Tropical Instability Waves in the eastern tropical Pacific: A review

Mesoscale eddies and tropical instability waves in the eastern tropical Pacific, first revealed by satellite infrared imagery, play an important role in the dynamics and biology of the region, and in the transfer of mass, energy, heat, and biological constituents from the shelf to the deep ocean and across the equatorial currents.From boreal late autumn to early spring, four to 18 cyclonic or anticyclonic eddies are formed off the coastal region between southern Mexico and Panama. The anticyclonic gyres, which tend to be larger and last longer than the cyclonic ones, are the best studied: they typically are 180–500 km in diameter, depress the pycnocline from 60 to 145 m at the eddy center, have swirl speeds in excess of 1 m s⁻¹, migrate west at velocities ranging from 11 to 19 cm s⁻¹ (with a slight southward component), and maintain a height signature of up to 30 cm. The primary generating agents for these eddies are the strong, intermittent wind jets that blow across the isthmus of Tehuantepec in Mexico, the lake district in Nicaragua and Costa Rica, and the Panama canal. Other proposed eddy-generating mechanisms are the conservation of vorticity as the North Equatorial Counter Current (NECC) turns north on reaching America, and the instability of coastally trapped waves/currents.Tropical Instability Waves (TIWs) are perturbations in the SST fronts on either side of the equatorial cold tongue. They produce SST variations on the order of 1–2 °C, have periods of 20–40 days, wavelengths of 1000–2000 km, phase speeds of around 0.5 m s⁻¹ and propagate westward both north and south of the Equator. The Tropical Instability Vortices (TIVs) are a train of westward-propagating anticyclonic eddies associated with the TIWs. They exhibit eddy currents exceeding 1.3 m s⁻¹, a westward phase propagation speed between 30 and 40 km d⁻¹, a signature above the pycnocline, and eastward energy propagation. Like the TIWs, they result from the latitudinal barotropically unstable shear between the South Equatorial Current (SEC) and the NECC with a potential secondary source of energy from baroclinic instability of the vertical shear with the Equatorial Undercurrent (EUC).This review of mesoscale processes is part of a comprehensive review of the oceanography of the eastern tropical Pacific Ocean.     

Contemporary Refugee‐Border Dynamics and the Legacies of the 1919 Paris Peace Conference

While the geopolitical legacies of the World War I peace negotiations are widely recognized, this article examines the often overlooked connection between the WWI Paris Peace Conference's spatial and geopolitical logics and contemporary refugee‐border dynamics. We argue that the spatial and geopolitical logics that framed the WWI Paris Peace Conference—the creation of new states, the propagation of the Western ideal of bounded sovereign states, the nationalist goals of self‐determination and homogeneous ethnic nations, and the establishment of a system of international governance—continue to impact refugee‐border dynamics and “crises” today. The categories, ideals, and practices of the international refugee regime that emerged over the last one‐hundred years stem in great part from these logics. In this paper, we urge critical contemplation about how these foundations—including the establishment of the post of High Commissioner for Refugees in 1921, the resultant Nansen Passports, the post‐WWI minority treaties, and lastly the 1933 Convention Relating to the International Status of Refugees—connect to contemporary human (im)mobility and border violence. We also introduce the articles in this special issue and highlight key themes and future directions for research in critical migration studies.     

Biotransformation enzyme activities and PCDD/PCDF levels in pike caught in a Swedish Lake

Recently, analysis of organochlorines in sediment and in pike from Lake Vänern, Sweden, showed a north-south gradient of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs). In the present study, good correlations were found between muscle 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) equivalents and liver ethoxyresorufin-O-deethylase (EROD) activities (and P4501A levels) in pike caught at three sampling sites along the north-south gradient in the lake. This comparison between tissue levels of PCDD/PCDF and EROD activity (and P4501A) may indicate that TCDD or structural analogs could be responsible for the observed induction of the pike P450 system. It must, however, be taken into account that the analysed contaminants often do not appear alone but are, rather, accompanied by a range of other substances which may be inducers or antagonists.