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41.
42.
Mark P. S. Krekeler Pete Probst Misha Samsonov Cynthia M. Tselepis William Bates Lance E. Kearns J. Barry Maynard 《Environmental Geology》2007,53(4):709-726
Subsurface flow constructed wetlands in the village of Akumal, Quintana Roo, Mexico were surveyed to determine the general
status of the wetland systems and provide baseline information for long term monitoring and further study. Twenty subsurface
flow wetlands were surveyed and common problems observed in the systems were overloading, poor plant cover, odor, and no secondary
containment. Bulk mineral composition of aggregate from two subsurface flow constructed wetlands was determined to consist
solely of calcite using bulk powder X-ray diffraction. Some soil structure is developed in the aggregate and aggregate levels
in wetlands drop at an estimated rate between 3 and 10 cm/year for overloaded wetlands owing to dissolution. Mineral composition
from fresh aggregate samples commonly is a mixture of calcite and aragonite. Trace amounts of Pb, Zn, Co, and Cr were observed
in fresh aggregate. Coefficients of permeability (k) varied from 0.006 to 0.027 cm/s with an average values being 0.016 cm/s. Grain size analysis of fresh aggregate samples
indicates there are unimodal and multimodal size distributions in the samples with modes in the coarse and fine sand being
common. Investigations of other geologic media from the Reforma region indicate that a dolomite with minor amounts of Fe-oxide
and palygorskite is abundant and may be a better aggregate source that the current materials used. A Ca-montmorillonite bed
was identified in the Reforma region as well and this unit is suitable to serve as a clay liner to prevent leaks for new and
existing wetland systems. These newly discovered geologic resources should aid in the improvement of subsurface flow constructed
wetlands in the region. Although problems do exist in these wetlands with respect to design, these systems represent a successful
implementation of constructed wetlands at a community level in developing regions. 相似文献
43.
Denitrification in continental shelf sediments has been estimated to be a significant sink of oceanic fixed nitrogen (N).
The significance and mechanisms of denitrification in organic-poor sands, which comprise 70% of continental shelf sediments,
are not well known. Core incubations and isotope tracer techniques were employed to determine processes and rates of denitrification
in the coarse-grained, sandy sediments of the Georgia continental shelf. In these sediments, heterotrophic denitrification
was the dominant process for fixed N removal. Processes such as coupled nitrification-denitrification, anammox (anaerobic
ammonium oxidation), and oxygen-limited autotrophic nitrification-denitrification were not evident over the 24 and 48 h time
scale of the incubation experiments. Heterotrophic denitrification processes produce 22.8–34.1 μmole N m-2 d-1 of N2 in these coarse-grained sediments. These denitrification rates are approximately two orders of magnitude lower than rates
determined in fine-grained shelf sediments. These lower rates may help reconcile unbalanced marine N budgets which calculate
global N losses exceeding N inputs. 相似文献
44.
Patricia M. Glibert Cynthia A. Heil Judith M. O'Neil William C. Dennison Mark J. H. O'Donohue 《Estuaries and Coasts》2006,29(2):209-221
Subtropical estuaries have received comparatively little attention in the study of nutrient loading and subsequent nutrient
processing relative to temperate estuaries. Australian estuaries are particularly susceptible to increased nutrient loading
and eutrophication, as 75% of the population resides within 200 km of the coastline. We assessed the factors potentially limiting
both biomass and production in one Australian estuary, Moreton Bay, through stoichiometric comparisons of nitrogen (N), phosphorus
(P), silicon (Si), and carbon (C) concentrations, particulate compositions, and rates of uptake. Samples were collected over
3 seasons in 1997–1998 at stations located throughout the bay system, including one riverine endmember site. Concentrations
of all dissolved nutrients, as well as particulate nutrients and chlorophyll, declined 10-fold to 100-fold from the impacted
western embayments to the eastern, more oceanic-influenced regions of the bay during all seasons. For all seasons and all
regions, both the dissolved nutrients and particulate biomass yielded N:P ratios <6 and N:Si ratios <1. Both relationships
suggest strong limitation of biomass by N throughout the bay. Limitation of rates of nutrient uptake and productivity were
more complex. Low C:N and C:P uptake ratios at the riverine site suggested light limitation at all seasons, low N:P ratios
suggested some degree of N limitation and high N:Si uptake ratios in austral winter suggested Si limitation of uptake during
that season only. No evidence of P limitation of biomass or productivity was evident. 相似文献
45.
46.
47.
John R. Thorstensen Cynthia J. Taylor 《Monthly notices of the Royal Astronomical Society》2000,312(3):629-637
We report spectroscopic orbital periods of 0.147 d (=3.53 h) for V533 Her, 0.207 d (=4.97 h) for V446 Her and 1.478 d for X Ser. V533 Her (Nova Herculis 1963) shows absorption features in its He i and Balmer lines which appear only in a limited range of orbital phase, suggesting that it is a low-inclination SW Sextantis star. V446 Her is unusual in that it has started normal dwarf nova eruptions after a nova outburst, but we find nothing else unusual about it – in particular, a distance estimate based on its dwarf nova outbursts agrees nicely with another based on the rate of decline of its nova eruption, both giving d ∼1 kpc. In X Ser, unlike in other old novae with long periods, no spectral features of the secondary star are visible. This and its outburst magnitude both suggest that it is quite distant and luminous, and at least 1 kpc from the Galactic plane. 相似文献
48.
Cook Inlet volcanoes that experienced an eruption between 1989 and 2006 had mean gas emission rates that were roughly an order
of magnitude higher than at volcanoes where unrest stalled. For the six events studied, mean emission rates for eruptions
were ∼13,000 t/d CO2 and 5200 t/d SO2, but only ∼1200 t/d CO2 and 500 t/d SO2 for non-eruptive events (‘failed eruptions’). Statistical analysis suggests degassing thresholds for eruption on the order
of 1500 and 1000 t/d for CO2 and SO2, respectively. Emission rates greater than 4000 and 2000 t/d for CO2 and SO2, respectively, almost exclusively resulted during eruptive events (the only exception being two measurements at Fourpeaked).
While this analysis could suggest that unerupted magmas have lower pre-eruptive volatile contents, we favor the explanations
that either the amount of magma feeding actual eruptions is larger than that driving failed eruptions, or that magmas from
failed eruptions experience less decompression such that the majority of H2O remains dissolved and thus insufficient permeability is produced to release the trapped volatile phase (or both). In the
majority of unrest and eruption sequences, increases in CO2 emission relative to SO2 emission were observed early in the sequence. With time, all events converged to a common molar value of C/S between 0.5
and 2. These geochemical trends argue for roughly similar decompression histories until shallow levels are reached beneath
the edifice (i.e., from 20–35 to ∼4–6 km) and perhaps roughly similar initial volatile contents in all cases. Early elevated
CO2 levels that we find at these high-latitude, andesitic arc volcanoes have also been observed at mid-latitude, relatively snow-free,
basaltic volcanoes such as Stromboli and Etna. Typically such patterns are attributed to injection and decompression of deep
(CO2-rich) magma into a shallower chamber and open system degassing prior to eruption. Here we argue that the C/S trends probably
represent tapping of vapor-saturated regions with high C/S, and then gradual degassing of remaining dissolved volatiles as
the magma progresses toward the surface. At these volcanoes, however, C/S is often accentuated due to early preferential scrubbing
of sulfur gases. The range of equilibrium degassing is consistent with the bulk degassing of a magma with initial CO2 and S of 0.6 and 0.2 wt.%, respectively, similar to what has been suggested for primitive Redoubt magmas. 相似文献
49.
This paper focuses on the chemistry of DoD-relevant organic contaminants in soil. Most of the work presented here is based on the author’s experience with the environmental fate of the munition constituents, TNT and RDX, for DoD related issues. The principles and challenges of understanding the transport of nitrobenzene and triazine compounds in the environment are captured. In this work, disparities in the current scientific literature with respect to the construction of sorption experiments are discussed, in terms of soil sample handling, dispersion state of the soil, and sorption hysteresis/equilibrium. Here is discussed the concept of environmentally formulated compounds and its implications toward reduced accuracy of predicting the environmental fate of munition constituents. Also, further research linking simple but oft-forgotten basic concepts of soil fertility to the transport and environmental fate of munition constituents are discussed. 相似文献
50.
James Yan Tse J. B. Hearnshaw P. Rosenzweig E. Guzman O. Escalona A. C. Gilmore P. M. Kilmartin L. C. Watson 《Monthly notices of the Royal Astronomical Society》2001,324(3):553-559
The light curve and spectra of Nova Centauri 1995 (V888 Cen) are analysed. The spectra were obtained a few days post-maximum. The nova is found to be a very fast nova, declining by 2 mag within about 5±2 d of maximum. The light curve shows strong oscillations in the transition region, of peak-to-peak amplitude about 1.5 mag and period 12–15 d. The light curve of Nova Centauri resembles closely that of Nova Aquilae 1918 (V603 Aql).
The early blue and red spectra obtained at Mt John show broad emission lines, many with P Cygni profiles. The absorption lines are found in two velocity systems at about −1765 and −3010 km s−1 , in respectively the principal and diffuse-enhanced stages of spectral development, as defined by McLaughlin. Nova Centauri has many Fe ii lines in emission, indicating that it is a member of the Williams Fe ii class of classical novae. 相似文献
The early blue and red spectra obtained at Mt John show broad emission lines, many with P Cygni profiles. The absorption lines are found in two velocity systems at about −1765 and −3010 km s