Minor and trace elements in bornite and associated Cu-(Fe)-sulfides: A LA-ICP-MS studyBornite mineral chemistry

In situ laser ablation inductively-coupled mass spectroscopy (LA-ICP-MS) has been used to provide a baseline dataset on the minor element contents in hypogene bornite and accompanying Cu-sulfides from 12 deposits with emphasis on syn-metamorphic Cu-vein systems in Norway, and skarn, porphyry and epithermal systems in SE Europe.Bornite contains significant concentrations of both Ag and Bi, especially in the vein and skarn deposits studied and has the potential to be a major Ag-carrier in such ores. Concentrations of up to >1 wt.% of both elements are documented. Measured concentrations appear to be independent of whether discrete Ag- and/or Bi-minerals are present within the analyzed sulfide. Where bornite and chalcocite (or mixtures of Cu-sulfides) coexist, Ag is preferentially partitioned into chalcocite over co-existing bornite and Bi is partitioned into the bornite. Bornite is a relatively poor host for Au, which mimics Ag by being typically richer in coexisting chalcocite. Most anomalous Au concentrations in bornite can be readily tracked to micron- and submicron-scale inclusions, but bornite and chalcocite containing up to 3 and 28 ppm Au in solid solution can be documented. Selenium and Te concentrations in bornite may be as high as several thousand ppm and correlate with the abundance of selenides and tellurides within the sample. Selenium distributions show some promise as a vector in exploration, offering the possibility to track a fluid source. Bornite and chalcocite are poor hosts for a range of other elements such as Co, Ni, Ga and Ge, etc. which have been reported to be commonly substituted within sulfides. Hypogene bornite and chalcocite may have significantly different trace element geochemical signatures from secondary (supergene) bornite.     

Simplified Wave Models Applicability to Shallow Mud Flows Modeled as Power-Law Fluids

Simplified wave models- such as kinematic,diffusion and quasi-steady- are widely employed as a convenient replacement of the full dynamic one in the analysis of unsteady open-channel flows,and especially for flood routing.While their use may guarantee a significant reduction of the computational effort,it is mandatory to define the conditions in which they may be confidently applied.The present paper investigates the applicability conditions of the kinematic,diffusion and quasisteady dynamic shallow wave models for mud flows of power-law fluids.The power-law model describes in an adequate and convenient way fluids that at low shear rates fluids do not posses yield stress,such as clay or kaolin suspensions,which are frequently encountered in Chinese rivers.In the framework of a linear analysis,the propagation characteristics of a periodic perturbation of an initial steady uniform flow predicted by the simplified models are compared with those of the full dynamic one.Based on this comparison,applicability criteria for the different wave approximations for mud flood of power-law fluids are derived.The presented results provide guidelines for selecting the appropriate approximation for a given flow problem,and therefore they may represent a useful tool for engineering predictions.     

Amenity value in post-industrial Chinese cities: the case of Nanjing

Many Chinese cities are in a transition from industrial to post-industrial urban economies. In this process of urban restructuring, land use becomes polycentric and fragmented. More sophisticated models are needed to estimate the amenity effects of this complex residential environment. This article assesses the relative housing price effects of neighborhood characteristics and accessibility in Nanjing, China. This is achieved with a hedonic price model that incorporates detailed spatial measures, geographical contingency, and a modified version of Alonso’s (1964) general theory of land rent. A crucial finding is that the effect of job accessibility on house price varies depending upon the specific sector of employment. Accessibility to jobs in the public and private service sectors has strong positive effects. However, housing proximity to heavy industries has a spatially nonlinear effect: negative in close proximity, but positive at a larger distance. Second, when we control for job accessibility, access to public transport has an added positive effect. Finally, neighborhood “quality” (defined in terms of nearby amenities) is also relevant, but far less than access to service employment. This research shows that Nanjing’s housing prices are affected by different residential characteristics than those with dominant price effects in Western cities.     

Instrumental method for reducing error in compression-derived measurements of rainfall interception for individual trees

Abstract

This technical note presents an instrumental method for the precise and timely installation of mechanical displacement sensors to investigate stem compression and relaxation associated with whole-tree rainwater loading and evaporation, respectively. We developed this procedure in response to the conclusions of Friesen et al. (2008 Friesen, J. 2008. Tree rainfall interception measured by stem compression. Water Resources Research, 44 doi:doi:10.1029/2008 WR007074. [Google Scholar]), which called for the development of a precision mounting method for strain sensors on inherently-irregular trunk cross-sections so that rainfall interception, storage and evaporation may be distinguished from other strain-related phenomena. To supply precise sensor installation locations, high-resolution trunk profiles are generated using the LaserBark^TM automated tree measurement system. These scans are utilized to approximate the location of neutral bending axes. A routine then instructs a mobile rangefinder along the cross-section to optically indicate exact positioning for strain sensors over the bending axes. As imprecise sensor placement linearly increases error and diminishes signal-to-noise ratio, this automated installation routine is designed to remove significant distortions created by wind throw, off-centre loading within unevenly-distributed canopies, and human error that can lead to erroneous measurements of rainfall interception.

Citation Van Stan, J. T. II, Jarvis, M. T., Levia, D. F. Jr & Friesen, J. (2011) Instrumental method for reducing error in compressionderived measurements of rainfall interception for individual trees. Hydrol. Sci. J. 56(6), 1061–1066.     

Perfluorinated compounds in blood of Caretta caretta from the Mediterranean Sea

Perfluorinated compounds (PFCs), widely used for their hydro-oil repellent properties, are almost non-degradable in the environment; there is scientific evidence that indicate bioaccumulation. They represent a threat to many organisms, because they are toxic and are endocrine disruptors. Scientific studies have demonstrated the presence of PFCs in blood and liver samples of fish, turtles, birds and mammals of marine ecosystems in different geographical areas. The aim of this study was to determine the distribution of PFOS and PFOA in blood samples of the marine turtle Caretta caretta, using a minimally invasive sampling procedure. 49 blood samples of marine turtle, taken from several Italian marine turtle rescue centers, were analyzed. While PFOA was never detected, measurable concentrations of PFOS were found in 15 blood samples; the values show a range from 1.14 ng/g to 28.51 ng/g (wet wt.). No differences between groups of samples taken from different areas were found.     

Impact of interacting bark structure and rainfall conditions on stemflow variability in a temperate beech-oak forest,central Germany

ABSTRACT

Trees concentrate rainfall to near-stem soils via stemflow. When canopy structures are organized appropriately, stemflow can even induce preferential flow through soils, transporting nutrients to biogeochemically active areas. Bark structure significantly affects stemflow, yet bark-stemflow studies are primarily qualitative. We used a LaserBark to compute bark microrelief (MR), ridge-to-furrow amplitude (R) and slope (S) metrics per American Society of Mechanical Engineering standards (ASME-B46.1–2009) for two morphologically contrasting species (Fagus sylvatica L. (European beech), Quercus robur L. (pendunculate oak)) under storm conditions with strong bark water storage capacity (BWSC) influence in central Germany. Smaller R and S for F. sylvatica significantly lowered BWSC, which strongly and inversely correlated to maximum funnelling ratios and permitted stemflow generation at lower rain magnitudes. Larger R and S values in Q. robur reduced funnelling, diminishing stemflow drainage for larger storms. Quercus robur funnelling and stemflow was more reliant on intermediate rain intensities and intermittency to maintain bark channel-dependent drainage pathways. Shelter provided by Q. robur’s ridged bark also appears to protect entrained water, lengthening mean intrastorm dry periods necessary to affect stemflow. Storm conditions where BWSC plays a major role in stemflow accounted for much of 2013’s rainfall at the nearest meteorological station (Wulferstedt).

Editor M.C. Acreman; Associate editor not assigned     

Physical Characteristics of Kazan Minor Showers as Determined by Correlations with the Arecibo UHF Radar

In the northern hemisphere, the month of February is characterized by a lack of major meteor shower activity yet a number of weak minor showers are present as seen by the Kazan radar. Using the Feller transformation to obtain the distribution of true meteor velocities from the distribution of radial velocities enables the angle of incidence to be obtained for the single beam AO (Arecibo Observatory) data. Thus the loci of AO radiants become beam-centered circles on the sky and one can, with simple search routines, find where these circles intersect on radiants determined by other means. Including geocentric velocity as an additional search criterion, we have examined a set of February radiants obtained at Kazan for coincidence in position and velocity. Although some may be chance associations, only those events with probabilities of association > 0.5 have been kept. Roughly 90 of the Kazan showers have been verified in this way with mass, radius and density histograms derived from the AO results. By comparing these histograms with those of the “background” in which the minor showers are found, a qualitative scale of dynamical minor shower age can be formulated. Most of the showers are found outside the usual “apex” sporadic source areas where it is easiest to detect discrete showers with less confusion from the background.