Field Test of Enhanced Remedial Amendment Delivery Using a Shear‐Thinning Fluid

Heterogeneity of hydraulic properties in aquifers may lead to contaminants residing in lower‐permeability zones where it is difficult to deliver remediation amendments using conventional injection processes. The focus of this study is to examine use of a shear‐thinning fluid (STF) to improve the uniformity of remedial amendment distribution within a heterogeneous aquifer. Previous studies have demonstrated the significant potential of STFs for improving remedial amendment delivery in heterogeneous aquifers, but quantitative evaluation of these improvements from field applications is lacking. A field‐scale test was conducted that compares data from successive injection of a tracer in water followed by injection of a tracer in an STF to evaluate the impact of the STF on tracer distribution uniformity in the presence of permeability contrasts within the targeted injection zone. Data from tracer breakthrough at multiple depth‐discrete monitoring intervals and electrical resistivity tomography (ERT) showed that inclusion of STF in the injection solution improved the distribution of the injected fluid within the targeted treatment zone. One improvement was a reduction in the movement of injected fluids through high‐permeability pathways, as evidenced by slower breakthrough of tracer at monitoring locations where breakthrough in baseline tracer‐only injection data was faster. In addition, STF‐amended injection solutions arrived faster and to a greater extent in monitoring locations within low‐permeability zones. ERT data showed that the STF injection covered a higher percentage of a two‐dimensional cross section within the injection interval between the injection well and a monitoring well about 3 m away.     

Collisional spreading of Enceladus’ neutral cloud

We describe a direct simulation Monte Carlo (DSMC) model of Enceladus’ neutral cloud and compare its results to observations of OH and O orbiting Saturn. The OH and O are observed far from Enceladus (at 3.95 R_S), as far out as 25 R_S for O. Previous DSMC models attributed this breadth primarily to ion/neutral scattering (including charge exchange) and molecular dissociation. However, the newly reported O observations and a reinterpretation of the OH observations (Melin, H., Shemansky, D.E., Liu, X. [2009] Planet. Space Sci., 57, 1743-1753, PS&S) showed that the cloud is broader than previously thought. We conclude that the addition of neutral/neutral scattering (Farmer, A.J. [2009] Icarus, 202, 280-286), which was underestimated by previous models, brings the model results in line with the new observations. Neutral/neutral collisions primarily happen in the densest part of the cloud, near Enceladus’ orbit, but contribute to the spreading by pumping up orbital eccentricity. Based on the cloud model presented here Enceladus maybe the ultimate source of oxygen for the upper atmospheres of Titan and Saturn. We also predict that large quantities of OH, O and H₂O bombard Saturn’s icy satellites.     

Operational Parameters,Data Density and Benthic Ecology: Considerations for Image-Based Classification of Multibeam Backscatter

Efforts to develop a procedurally robust method for automated classification of multibeam backscatter have taken a variety of approaches (e.g., image-based, textural, angular range analysis). For image-based classification, little research has focused on the roles of operational parameters of vessel and sonar system in affecting the final classification. Repeat multibeam surveys (2005 and 2006) conducted at the same area with different sounding densities were classified using QTC-Multiview. Comparison of class areas revealed 78% agreement between classifications derived from the two surveys. Cross-tabulation of ground truth video and class demonstrate 71% agreement in the low-density survey and 77% for the high-density. Differences between classifications are primarily attributed to variation in along track data density, errors in the compensation process, and/ or insufficient quality control of the input data. Natural change detection at the scales observed was determined not to be practically discernable from the errors associated with the classification process.     

Fecundity in the marine spiny lobster Jasus verreauxi (H. Milne Edwards) (Crustacea: Decapoda: Palinuridae)

Fecundity in Jasus verreauxi (H. Milne Edwards, 1851) has been studied by a detailed investigation of (a) the total weight of eggs carried by female specimens, (b) the average number of eggs per 1 g sample, and (c) the total number of eggs carried by females. In mid October 1966, 217 females “in berry” (that is, carrying external eggs) were examined and measured at Spirits Bay, New Zealand. The fecundity study is based on the results obtained from 21 selected specimens, with carapace lengths from 15.5 cm to 23.5 cm.

A direct relation was found between the total weight of eggs carried and increase in carapace length. The total weight of eggs carried varied from about 51 g to 238 g for carapace lengths of 15.5 cm to 23.5 cm. No correlation was shown between the average number of eggs per 1 g sample and increase in carapace length. Considerable variation was noted in the number of eggs per 1 g sample, which ranged from a low count of 6,453 eggs to a high count of 8,341 eggs. The total number of eggs carried by female J. verreauxi was found to be related to an increase in carapace length. Furthermore, increase in fecundity per relative carapace length increase was noted to be greater in smaller specimens than in larger specimens. The total number of eggs carried ranged from about 385,000 for a carapace length of 15.5 cm to 1,940,000 for a carapace length of 23.5 cm.

Fecundity, as measured by the total weight of eggs carried and the total number of eggs produced, was found to be much higher in J. verreauxi than in several Jasus species previously studied by other workers.     

Respiration rates of some New Zealand echinoderms (note)

Respiratory rates were measured in four common New Zealand echinoderms, Evechinus chloroticus and Goniocidaris umbraculum (Echinoidea), and Coscinasterias calamaria and Pentagonaster pulcheilus (Asteroidea). Oxygen uptake was monitored with a polarographic oxygen electrode. The respiratory rates at 12°c ranged from 3.8 to 9.8 μl O_2.h^‐1.g^‐1 (live weight). The rates for Evechinus and Coscinasterias fall well within the range of metabolic rates of other echinoids and asteroids. Goniocidaris and Pentagonaster have relatively low respiratory rates.     

Stage‐dependent thyroxine effects on sea urchin development

Thyroxine, one of the iodinated hormones produced by vertebrate thyroids, has been reported to accelerate late larval development in several sea urchins (Chino et al. 1994) and in the crown‐of‐thorns starfish (Johnson & Cartwright 1996), but thyroxine effects on earlier portions of echinoderm development have not been reported. I investigated thyroxine effects on developmental rates during several periods spanning development from early cleavage to metamorphosis in the New Zealand sea urchin Evechinus chloroticus (Valenciennes). Thyroxine treatment slowed development between the eight‐cell stage and assembly of the four‐armed pluteus and mid‐larval development between the four‐armed and six‐armed stages. Thyroxine treatment accelerated progress of eight‐armed plutei toward settling, but did not alter the final percentages of larvae that settled and metamorphosed to juvenile urchins. Acceleration of late larval echinoderm development by thyroxine may indicate a relatively ancient evolutionary origin of thyroxine's effects on developmental processes (Johnson 1997).     

Synoptic and mesoscale controls on the isotopic composition of precipitation in the western United States

We present a new event-scale catalog of stable isotopic measurements from 5?years of storm events at 4 sites in southern California, which is used to understand the storm to storm controls on the isotopic composition of precipitation and validate the event-scale performance of an isotope-enabled GCM simulation (IsoGSM) (Yoshimura et?al. 2008). These analyses are motivated to improve the interpretation of proxy records from this region and provide guidance in testing the skill of GCMs in reproducing the hydrological variability in the western US. We find that approximately 40% of event-scale isotopic variability arises from the percentage of precipitation that is convective and the near surface relative humidity in the days prior to the storms landfall. The additional isotopic variability arises from the fact that storms arriving from different source regions advect moisture of distinct isotopic compositions. We show using both field correlation and Lagrangian trajectory analysis that the advection of subtropical and tropical moisture is important in producing the most isotopically enriched precipitation. The isotopic catalog is then used along with satellite-derived δD retrievals of atmospheric moisture to benchmark the performance of the IsoGSM model for the western US. The model is able to successfully replicate the observed isotopic variability suggesting that it is closely reproducing the moisture transport and storm track dynamics that drive the large storm-to-storm isotopic range. Notably, we find that an increase in moisture flux from the central tropical Pacific leads to a convergence of isotopically enriched water vapor in the subtropics and consequently an increase in δ¹⁸O of precipitation at sites along the entire west coast. Changes in poleward moisture flux from the central Tropical Pacific have important implications for both the global hydrological cycle and regional precipitation amounts and we suggest such changes can be captured through instrumental and proxy-reconstruction of the spatiotemporal isotopic patterns in the precipitation along the west coast of the US.     

Sulfur isotope signatures in gypsiferous sediments of the Estancia and Tularosa Basins as indicators of sulfate sources, hydrological processes, and microbial activity

In order to reconstruct paleo-environmental conditions for the saline playa lakes of the Rio Grande Rift, we investigated sediment sulfate sources using sulfur isotope compositions of dissolved ions in modern surface water, groundwater, and precipitated in the form of gypsum sediments deposited during the Pleistocene and Holocene in the Tularosa and Estancia Basins. The major sulfate sources are Lower and Middle Permian marine evaporites (δ³⁴S of 10.9-14.4‰), but the diverse physiography of the Tularosa Basin led to a complex drainage system which contributed sulfates from various sources depending on the climate at the time of sedimentation. As inferred from sulfur isotope mass balance constraints, weathering of sulfides of magmatic/hydrothermal and sedimentary origin associated with climate oscillations during Last Glacial Maximum contributed about 35-50% of the sulfates and led to deposition of gypsum with δ³⁴S values of −1.2‰ to 2.2‰ which are substantially lower than Permian evaporates. In the Estancia Basin, microbial sulfate reduction appears to overprint sulfur isotopic signatures that might elucidate past groundwater flows. A Rayleigh distillation model indicates that about 3-18% of sulfates from an inorganic groundwater pool (δ³⁴S of 12.6-13.8‰) have been metabolized by bacteria and preserved as partially to fully reduced sulfur-bearing minerals species (elemental sulfur, monosulfides, disulfides) with distinctly negative δ³⁴S values (−42.3‰ to −20.3‰) compared to co-existing gypsum (−3.8‰ to 22.4‰). For the Tularosa Basin microbial sulfate reduction had negligible effect on δ³⁴S value of the gypsiferous sediments most likely because of higher annual temperatures (15-33 °C) and lower organic carbon content (median 0.09%) in those sediments leading to more efficient oxidation of H₂S and/or smaller rates of sulfate reduction compared to the saline playas of the Estancia Basin (5-28 °C; median 0.46% of organic carbon).The White Sands region of the Tularosa Basin is frequently posited as a hydrothermal analogue for Mars. High temperatures of groundwater (33.3 °C) and high δ¹⁸O(H₂O) values (1.1‰) in White Sands, however, are controlled predominantly by seasonal evaporation rather than the modern influx of hydrothermal fluids. Nevertheless, it is possible that some of the geochemical processes in White Sands, such as sulfide weathering during climate oscillations and upwelling of highly mineralized waters, might be considered as valid terrestrial analogues for the sulfate cycle in places such as Meridiani Planum on Mars.     

Paleohydrology of the upper Laurentian Great Lakes from the late glacial to early Holocene

Between 10,500 and 9000 cal yr BP, δ¹⁸O values of benthic ostracodes within glaciolacustrine varves from Lake Superior range from − 18 to − 22‰ PDB. In contrast, coeval ostracode and bivalve records from the Lake Huron and Lake Michigan basins are characterized by extreme δ¹⁸O variations, ranging from values that reflect a source that is primarily glacial ( − 20‰ PDB) to much higher values characteristic of a regional meteoric source ( − 5‰ PDB). Re-evaluated age models for the Huron and Michigan records yield a more consistent δ¹⁸O stratigraphy. The striking feature of these records is a sharp drop in δ¹⁸O values between 9400 and 9000 cal yr BP. In the Huron basin, this low δ¹⁸O excursion was ascribed to the late Stanley lowstand, and in the Lake Michigan basin to Lake Agassiz flooding. Catastrophic flooding from Lake Agassiz is likely, but a second possibility is that the low δ¹⁸O excursion records the switching of overflow from the Lake Superior basin from an undocumented northern outlet back into the Great Lakes basin. Quantifying freshwater fluxes for this system remains difficult because the benthic ostracodes in the glaciolacustrine varves of Lake Superior and Lake Agassiz may not record the average δ¹⁸O value of surface water.