Volatile Phase Separation in Silicic Magmas at Bajo de la Alumbrera Porphyry Cu-Au Deposit, NW Argentina

Abstract. At the Bajo de la Alumbrera porphyry Cu-Au deposit, NW Argentina, several key textural elements preserve evidence for volatile separation. Interconnected miarolitic cavities, while being studied extensively in granites, have now been recognized in intrusions related to porphyry Cu mineralization. Pods of saccharoidal quartz are connected by narrow, anastomosing zones of graphic quartz-alkali feldspar intergrowths and ragged biotite (with lesser apatite and magnetite). Their connectivity can be as much as 15 cm; however, more commonly, the interconnected miarolitic cavities are approximately 1 to 2 mm across and 5 cm or less, long. Features such comb-quartz layered textures and magmatic-hydrothermal veins (P veins), combined with aqueous fluid phase equilibria from fluid inclusions, better constrain physical models of exsolution. We interpret these textures in the context of vapour phase formation, coalescence and accumulation in an evolving silicic magma. Recognition of textures, such as the interconnected miarolitic cavities reported here, may provide a simple exploration tool for porphyry Cu deposits, helping explorers to recognize evidence for a potentially fertile intrusions.     

Crustal constraints on the origin of mantle seismicity in the Vrancea Zone, Romania: The case for active continental lithospheric delamination

The Vrancea zone of Romania constitutes one of the most active seismic zones in Europe, where intermediate-depth (70–200 km) earthquakes of magnitude in excess of M_w = 7.0 occur with relative frequency in a geographically restricted area within the 110° bend region of the southeastern Carpathian orogen. Geologically, the Vrancea zone is characterized by (a) a laterally restricted, steeply NW-dipping seismogenic volume (30 × 70 × 200 km), situated beneath (b) thickened continental crust within the highly arcuate bend region of the Carpathian orocline, and (c) miscorrelation of hypocenters with the position of known or inferred suture zones in the Carpathian orogenic system. Geologic data from petroleum exploration in the Eastern Carpathians, published palinspastic reconstructions, and reprocessing of industry seismic data from the Carpathian foreland indicate that (1) crust of continental affinity extends significantly westward beneath the external thrust nappes (Sub-Carpathian, Marginal Folds, and Tarcau) of the Eastern Carpathians, (2) Cretaceous to Miocene strata of continental affinity can be reconstructed westward to a position now occupied by the Transylvanian basin, and (3) geologic structure in the Carpathian foreland (including the Moho) is sub-horizontal directly to the east and above the Vrancea seismogenic zone. Taken together, these geologic relationships imply that the Vrancea zone occupies a region overlain by continental crust and upper mantle, and does not appear to originate from a subducted oceanic slab along the length of the Carpathian orogen. Accordingly, the Vrancea zone appears to potentially be an important place to establish evidence for active lithospheric delamination.     

Subsidence and strike-slip tectonism of the upper continental slope off Manzanillo, Mexico

The direction of convergence between the Rivera and North American plates becomes progressively more oblique (in a counter-clockwise sense as measured relative to the trench-normal direction) northwestward along the Jalisco subduction zone. By analogy to other subduction zones, the forces resulting from this distribution of convergence directions are expected to produce a NW moving, fore-arc sliver and a NW–SE stretching of the fore-arc area. Also, a series of roughly arc parallel strike-slip faults may form in the fore-arc area, both onshore and offshore, as is observed in the Aleutian arc.In the Jalisco subduction zone, the Jalisco block has been proposed to represent such a fore-arc sliver. However, this proposal has encountered one major problem. Namely, right-lateral strike-slip faulting within the fore-arc sliver, and between the fore-arc sliver and the North American plate, should be observed. However, evidence for the expected right-lateral strike-slip faulting is sparse. Some evidence for right-lateral strike-slip faulting along the Jalisco block–North American plate boundary (the Tepic–Zacoalco rift system) has been reported, although some disagreement exists. Right-lateral strike-slip faulting has also been reported within the interior of the Jalisco block and in the southern Colima rift, which forms the SE boundary of the Jalisco block.Threefold, multi-channel seismic reflection data were collected in the offshore area of the Jalisco subduction zone off Manzanillo in April 2002 during the FAMEX campaign of the N/O L'Atalante. These data provide additional evidence for recent strike-slip motion within the fore-arc region of the Jalisco subduction zone. This faulting offsets right-laterally a prominent horst block within the southern Colima rift, from which we conclude that the sense of motion along the faulting is dextral. These data also provide additional evidence for recent subsidence within the area offshore of Manzanillo, as has been proposed.     

Mass Spectrometry and reverse phase HPLC techniques for the identification of degraded fossil pigments in lake sediments and their application in palaeolimnology

Accurate identification of fossil pigments is essential if they are to be used as biomarker compounds in palaeolimnological studies. In recent years High Performance Liquid Chromatography (HPLC) has greatly enhanced the efficiency with which fossil pigments can be characterised and quantified. Using HPLC, undegraded pigments are typically identified through retention times, absorbance spectra and co-chromatography with authentic reference standards. However, lake sediments may also contain degraded pigments for which there are often no standards, and which may be difficult to identify using HPLC alone. In this study, we submitted HPLC fractions of fossil pigments and pigment derivatives collected from a meromictic lake in south west Tasmania, to a combination of Mass Spectrometry (MS) techniques including Electron Impact (EI) and static Liquid Secondary Ion MS (LSIMS) to identify their molecular ion characteristics and organic chemical composition. Mass Spectrometry permitted the detection of specific mass ions which were used to verify the identity of pigments and their derivatives. These included five carotenoids, chlorophyll a and derivatives, three previously described bacteriochlorophyll c derivatives with molecular weights of 770, 784, and 802, and two undescribed derivatives of bacteriochlorophyll c with molecular weights of 766 and 788. With these improved identifications we speculate on the pathways and modes of pigment degradation in the lake and asses the value of the degraded pigments as biomarkers. The use of MS permitted the identification of a greater number of signature pigments of algal and bacterial communities thus increasing the palaeolimnological value of the sediments. These methods are best applied in fossil pigment studies where there are a large number of unknown pigments and pigment degradation products, and where there are no authentic standards for co-chromatography. Practical suggestions for pigment MS are included in the discussion.     

Multivariable spatial prediction

For spatial prediction, it has been usual to predict one variable at a time, with the predictor using data from the same type of variable (kriging) or using additional data from auxiliary variables (cokriging). Optimal predictors can be expressed in terms of covariance functions or variograms. In earth science applications, it is often desirable to predict the joint spatial abundance of variables. A review of cokriging shows that a new cross-variogram allows optimal prediction without any symmetry condition on the covariance function. A bivariate model shows that cokriging with previously used cross-variograms can result in inferior prediction. The simultaneous spatial prediction of several variables, based on the new cross-variogram, is then developed. Multivariable spatial prediction yields the mean-squared prediction error matrix, and so allows the construction of multivariate prediction regions. Relationships between cross-variograms, between single-variable and multivariable spatial prediction, and between generalized least squares estimation and spatial prediction are also given.     

Block Kriging for Lognormal Spatial Processes

Lognormal spatial data are common in mining and soil-science applications. Modeling the underlying spatial process as normal on the log scale is sensible; point kriging allows the whole region of interest to be mapped. However, mining and precision agriculture is carried out selectively and is based on block averages of the process on the original scale. Finding spatial predictions of the blocks assuming a lognormal spatial process has a long history in geostatistics. In this article, we make the case that a particular method for block prediction, overlooked in past times of low computing power, deserves to be reconsidered. In fact, for known mean, it is optimal. We also consider the predictor based on the “law” of permanence of lognormality. Mean squared prediction errors of both are derived and compared both theoretically and via simulation; the predictor based on the permanence-of-lognormality assumption is seen to be less efficient. Our methodology is applied to block kriging of phosphorus to guide precision-agriculture treatment of soil on Broom's Barn Farm, UK.     

Quantum-mechanical calculation of the vibrational spectrum of beryl (Al4Be6Si12O36) at the Γ point

A quantum-mechanical calculation of the zone-centre phonon spectrum of beryl has been performed, by using an hybrid HF/DFT Hamiltonian (B3LYP). An excellent agreement with the experiment has been obtained, being the difference between the calculated and the experimental vibrational frequencies (Raman, IR-TO and IR-LO) less than 5 cm^?1 on average. In the few cases where a relatively large disagreement between calculated and experimental data is observed, an explanation can be found which attributes the reason of the discrepancies to the experimental data rather than to the calculated ones. The calculation (i) allows the identification, in the experimental spectra, of the peaks corresponding to fundamental modes, overtones, combination bands and leakage; (ii) solves problems of band assignements due to the presence of LO–TO splitting in the IR spectra; (iii) provides the frequencies of silent modes; (iv) permits a full analysis of the atomic motion corresponding to each normal mode.     

Types, Characteristics, and Geodynamic Settings of Mesozoic Epithermal Gold Deposits in Eastern China

Mesozoic epithermal gold deposits in eastern China are divided into calc‐alkaline and alkaline magma‐related gold deposits, and are also grouped as low‐sulfidation, intermediate‐sulfidation and high‐sulfidation types, of which the first two predominate. These gold deposits are distributed in the Tianshan–Yinshan–Great Xing’anling Variscan fold belt of North China craton, Qinling‐Dabie Indo‐Sinian fold belt of Yangtze craton, and South China fold belt or Cathaysian block, from north to south along the eastern China continent. Most of the epithermal gold orebodies are hosted either in volcanic rocks or their related granitoids, and volcanic breccia pipes. These orebodies are mainly associated with adularia–chalcedony–sericite, and alunite–kaolinite–quartz alteration. These orebodies formed in four mineralization pulses at 175, 145–135, 127–115, and 110–94 Ma. The first three pulses correspond to the post‐collision period between the North China and Yangtze cratons, an extension period during late‐stage rotation of the principal compressional stress from N‐S to E‐W, and a dramatic thinning period of the lithosphere, respectively. The last mineralizing pulse was the result of another extension in South China. Although the mineralizing pulses occurred at different times, they all occurred in extensional settings and were accompanied by crust and the mantle interaction.