Strontium isotope distribution in a regionally metamorphosed granite from the Zentralgneis,south-east Tauernfenster,Austria

The effect of Alpine (40 my) low amphibolite facies metamorphism on strontium isotopes in the Variscan (250–300 my) granitic complex of the Zentralgneis was investigated by analysing samples of a leucogranite which forms small intrusions into a tonalite. The leucogranite has Rb/Sr ratios up to 30.Two muscovites and three biotites underwent complete reequilibration during the metamorphism. The ages of 12–20 my are consistent with published K-Ar ages on micas from the same area, and reflect post-metamorphic cooling.Six whole-rock samples define an isochron with an age of 244±7 my (=1.47×10^–11yr^–1). Three further samples, collected within 30 cm of contacts with the tonalite, plus 1 cm sawn slabs of leucogranite and tonalite from either side of a contact fit a line with 10% greater slope; this line is interpreted as a mixing line, resulting from contamination of the leucogranite, near its contacts, with strontium from the enclosing tonalite. The time of contamination is uncertain but petrological evidence suggests it is the result of the metamorphism.Neither leucogranite whole rocks nor minerals from the tonalite, at contacts and in a xenolith, show any evidence for preferential mobilisation of radiogenic strontium in the course of metamorphism.The work was carried out in Heidelberg during successive tenure of the Michael Foster Memorial Scholarship from the University of Oxford and a Wates Travelling Fellowship of the Royal Society of London. Field work and sample collection was supported in part by the Geologische Bundesanstalt, Wien. For support from each of these sources I am very grateful. It is also a pleasure to acknowledge with thanks the support and facilities afforded me at the Laboratorium für Geochronologie by Dr. Hans-J. Lippolt.     

Geo-botanical evidence of late quaternary mass wasting in block field areas of Virginia

Studies of block fields at Massanutten Mountain, Virginia, document and provide information on the magnitude and frequency of mass movement on these coarse-grained slopes. Block fields, which traditionally have been considered relicts of Pleistocene climate, occur on and downslope from resistant Massanutten Sandstone in Passage Creek basin. Slopes are strewn with boulders and vegetative cover on the open block fields is absent to sparse. Several block fields were investigated for evidence of recent movement using the degree of lichen growth, differences in block weathering, and rock-fall damaged trees. Temporal and spatial aspects of geomorphic processes can be inferred through dendrogeochronology. Corrasion scars and stem ages infer a minimum age for a geomorphic or hydrologic event. High flows on Passage Creek coincided with tree-ring determined dates of block-field movement. Although, Pleistocene periglacial climate may have facilitated original formation of block fields, some block fields now continue to spread downslope during intense runoff events. Present block-field mass wasting may be the principal erosional process in these areas of resistant rock.     

The evolution of excess argon in alpine biotites — A40Ar-39Ar analysis

Alpine biotites containing excess⁴⁰Ar have been analysed by step-heating argon analysis of both neutron irradiated and unirradiated samples. In addition to age spectra the data are discussed in terms of the thermal release of⁴⁰Ar,³⁹Ar,³⁷Ar and³⁶Ar and also displayed on a correlation plot of³⁶Ar/⁴⁰Ar vs.³⁹Ar/⁴⁰Ar which is used to interpret the data and present a model of isotopic evolution during metamorphic cooling. This diagram overcomes misleading complications of isochron plots. The samples exhibit the following argon systematics: (1) flat age spectra for 80–90%³⁹Ar release with anomalously old ages but early gas fractions that approximate the accepted cooling ages; (2) each sample shows decreasing³⁶Ar/⁴⁰Ar with increasing temperature of heating step with three samples having a negative correlation of³⁶Ar/⁴⁰Ar vs.³⁹Ar/⁴⁰Ar and one a positive correlation; (3) there appear to be two³⁶Ar components, one released at high temperatures and correlated with radiogenic⁴⁰Ar and one released at low temperatures which is not correlated with radiogenic⁴⁰Ar; and (4) there is no significant effect of neutron irradiation on the release of⁴⁰Ar and³⁶Ar.Interpretation suggests that these biotites contain a record of the evolution and isotopic composition of ambient argon retained within the metamorphic host rocks during cooling. After incorporation of argon of high⁴⁰Ar/³⁶Ar another argon component, of atmospheric composition, was retained at lower temperature and argon partial pressures.     

The headward extent of fluvial landforms and associated vegetation on massanutten mountain,Virginia

Variation in fluvial landforms and associated vegetation in the headward (upstream) direction has received little study and the controlling factors are not well understood. The relations among channel gradient, basin area, stream order, and the headward extent of fluvial landforms and vegetation was studied in 18 small basins and larger nearby stream reaches in the Massanutten Mountain area, northern Shenandoah Valley, Virginia. Low-order streams were traversed to their basin heads. Notice was made of the point or region of the disappearance of fluvial landforms. Indicator species were used to confirm landform identification. The studied landforms include the channel bar, channel shelf, floodplain, and terraces. Basin geomorphic characteristics were determined from topographic and geologic maps and ground surveys. Results suggest that gradient is the most important factor controlling the development of fluvial landforms. Floodplains have not developed along stream reaches where average channel gradients exceed 0.15. Channel shelves and associated vegetation occur farther upstream than floodplains.     

Resistance to shallow landslide failure through root-derived cohesion in east coast hill country soils,North Island,New Zealand

Measured shear strength (cohesion and friction) of airfall-derived east coast hill country regolith is insufficient for the maintenance of existing regolith depth/slope angle relationships in the catchment of Lake Waikopiro in northern Hawke's Bay, New Zealand. If these regoliths are attributed with an additional increment of cohesion derived mechanically from a turf mat membrane, existing depth/slope angle distributions are explicable. Sites where failure has occurred have been measured, and back-analysis used to derive a range of values for additional mechanical cohesion. Values are in the range 0·2–7·6 kPa, consistent with earlier findings. This range is narrowed further, to 0·7–6·9 kPa, with assumptions regarding soil moisture status at failure. Copyright © 1999 John Wiley & Sons, Ltd.     

Temporal Variability of Iron Speciation in Coastal Rainwater

Iron occurs in rain as particulateand dissolved Fe and includes both Fe(II) and Fe(III)species. Model calculations and correlation analysisindicate Fe(II)(aq) occurs almost exclusively as thefree ion whereas Fe(III)(aq) occurs as both ironoxalate and Fe(OH)₂ ⁺(aq) with largevariations over the pH range from 4.0 to 5.0. Complexation with humic-like compounds may also beimportant for Fe(III)(aq); however, the concentrationand structural characteristics of these compounds haveyet to be determined. 112 rain samples were collectedfor iron analysis in Wilmington, North Carolina,between 1 July 1997, and 30 June 1999. Total iron,particulate iron and Fe(III)(aq) were higher inconcentration in summer and spring rain relative towinter and autumn rain. Fe(II)(aq) concentrations, incontrast, did not vary seasonally. Particulate iron,which was approximately half the total rainwater iron,was highest between noon and 6 p.m. (EST), probably dueto more intense regional convection including land-seabreezes during that time. The ratio ofFe(II)(aq)/Fe(III)(aq) was also highest in rainreceived between noon and 6 p.m., which most likelyreflects photochemical reduction of Fe(III)(aq)complexes to form Fe(II)(aq). A conceptual modeldepicting the interplay between iron species, lightintensity and organic ligands in rainwater ispresented.     

Investigating model performance and parameter sensitivity for runoff simulation across multiple events for a large green roof

Green roofs are a form of green infrastructure aimed at retaining or slowing the movement of precipitation as stormwater runoff to sewer systems. To determine total runoff versus retention from green roofs, researchers and practitioners alike employ hydrologic models that are calibrated to one or more observed events. However, questions still remain regarding how event size may impact parameter sensitivity, how best to constrain initial soil moisture (ISM), and whether limited observations (i.e., a single event) can be used within a calibration-validation framework. We explored these questions by applying the storm water management model to simulate a large green roof located in Syracuse, NY. We found that model performance was very high (e.g., Nash Sutcliffe efficiency index > 0.8 and Kling-Gupta efficiency index > 0.8) for many events. We initially compared model performance across two parameterizations of ISM. For some events, we found similar performance when ISM was varied versus set to zero; for others, varying ISM yielded higher performance as well as greater water balance closure. Within a calibration-validation framework, we found that calibrating to larger events tended to produce moderate to high performance for other non-calibration events. However, very small storms were notoriously difficult to simulate, regardless of calibration event size, as these events are likely fully retained on the roof. Using regional sensitivity analysis, we confirmed that only a subset of model parameters was sensitive across 16 events. Interestingly, many parameters were sensitive regardless of event size, though some parameters were more sensitive when simulating smaller events. This emphasizes that storm size likely influences parameter sensitivity. Overall, we show that while calibrating to a single event can achieve high performance, exploring simulations across multiple events can yield important insight regarding the hydrologic performance of green roofs that can be used to guide the gathering of in situ properties and observations for refining model frameworks.     

Response of the Nile and its catchment to millennial-scale climatic change since the LGM from Sr isotopes and major elements of East Mediterranean sediments

Changes in ⁸⁷Sr/⁸⁶Sr and major element geochemistry, from two sediment cores (9509 and 9501) in the Eastern Mediterranean (EM), were used to resolve changes in sediment provenance and, hence, determine climate changes in the Nile catchment and Eastern Sahara desert over the past 25 ka. The sediment was described by a three end-member system comprising Blue Nile (BN; ⁸⁷Sr/⁸⁶Sr = 0.7506; Sr = 210 ppm), White Nile (WN; ⁸⁷Sr/⁸⁶Sr = 0.7094; Sr = 72.5 ppm) and Saharan dust (SD; ⁸⁷Sr/⁸⁶Sr = 0.7183; Sr = 99 ppm). The sedimentary record of these cores represents the suspended load carried down the Nile river and discharged into the S.E. Levantine basin and thus records palaeoclimatically controlled changes in erosion and transport in the catchment. During arid periods (0–5 ka BP) and prior to 11 ka BP, fluxes of BN sediment at 9509 (～6 g/cm²/yr & 10–12 g/cm²/yr, respectively) were greater than during the peak of the African Humid Period (AHP) from 5 to 11 ka BP (<2 g/cm²/yr); this latter period witnessed the deposition of the youngest organic-rich sediment, termed sapropel (S-1), in the EM basin. By contrast the flux of WN increased during the AHP from ～5 g/cm²/yr at ～13 ka BP to >15 g/cm²/yr. In the Ethiopian Highlands (BN catchment) increases in the amount and duration of the monsoon during the AHP caused more vegetation to grow resulting in less soil erosion. In the WN catchment increased rainfall caused more catchment erosion and higher sediment flux through the Sudd marshes. The sedimentation rate in core 9509 increased during the AHP because of the greater importance of the WN sediment flux relative to the BN sediment flux. Saharan dust flux also decreased during the AHP reaching a minimum at ～6 ka BP (core 9509) due to ‘greening’ of the Sahara desert. At the onset of S-1, the changes in Nile flow as determined by ⁸⁷Sr/⁸⁶Sr and climatic changes in the EM basin determined by δ¹⁸O of planktonic foraminifera were simultaneous, confirming that such isotopic tracers cannot be used directly to determine the cause of the circulation changes in the EM at this time. The increase in the proportion of BN sediment at 9509 with a somewhat higher grain size during the H-1 period (15–17 ka BP) was caused by erosion and redistribution of sediment from the Nile delta and/or the Israeli coast as sea-level rose.     

Interaction of weathering solutions with oxygen and U–Pb isotopic systems of radiation-damaged zircon from an Archean granite, Darling Range Batholith, Western Australia

Zircons from Archean granites from the Darling Range Batholith in the Yilgarn Craton of Western Australia have been shown to have complexly discordant U–Pb systems with a strong component of zero age disturbance. The only geological event that has affected the granites in recent times is the pervasive regional weathering. Our aim in this study was to investigate the effects of weathering on the U–Pb and oxygen systems of the zircons, and to this end, we report secondary ion mass spectrometry (SIMS) results of OH, oxygen and U–Pb isotope systems of six typical zircons from a sample of the granite. These results confirmed the presence of OH in highly radiation-damaged parts of the zircons, demonstrating fluid interaction within grains. The presence of OH was accompanied by significant changes in the ¹⁸O/¹⁶O ratios. The data suggest trends where δ¹⁸O values in individual grains both increase and decrease with increasing OH. SIMS measurements showed the U–Pb systems are variably and unsystematically discordant in radiation-damaged parts of the zircons, particularly those with elevated OH contents. The complex U–Pb systems are interpreted in terms of multiple disturbance events between 450 and 0 Ma involving low-temperature fluid-induced movement of radiogenic Pb, decoupled from parent U and Th, within the radiation-damaged zircons, together with some Pb loss.