Controls on Quaternary coastal evolution of the east-northeastern coast of Brazil: roles of sea-level history, trade winds and climate

East-northeastern Brazil has a wave-dominated, micro- to meso-tidal coast, lying entirely within the southern Atlantic trade wind belt. Integration of geologic mapping, radiocarbon dating and vibracoring data shows that the Quaternary coastal evolution of this area was controlled by three major factors: (1) sea-level history; (2) trade winds; and (3) climate change.

Sea-level history. Along the east-northeastern coast of Brazil, relative sea level has fallen approximately 5 m during the last 5000 y. Correlation of this sea-level history with the evolution of beach-ridge, lagoonal and coastal plain deposits shows that: (1) sea-level rise favours the formation of barrier island—lagoonal systems and the construction of intralagoonal deltas; (2) sea-level lowering is not conductive to barrier island formation. Rather, lagoons and bays become emergent and beach-ridge plains rapidly prograde.

Trade winds. Sediment dispersal systems along the coastal zone of east-northeastern Brazil have been highly persistent since Pleistocene time, as deduced from beach-ridge orientation. This persistence results from the fact that sediment dispersal in wave-dominated settings is ultimately controlled by atmospheric circulation which, for the east-northeastern coast of Brazil is associated with the South Atlantic high-pressure cell. The remarkable stability of this cell through time, has allowed the accumulation of extensive beach-ridge plains at the longshore drift sinks located along the coast.

Climate change. Effects of Quaternary climate changes on coastal sedimentation are twofold. Climate changes may affect rainfall patterns, thus exerting an important control on coastal dune development. Along the coast of northeastern Brazil, active coastal dunes are only present in those areas in which at least four consecutive dry months occur during the year. Mapping of these areas has shown that dune development during the Holocene has been episodic, these episodes being probably controlled by variations in rainfall patterns associated with climate changes. Secondly, despite its overall stability, the position of the high-pressure cell has experienced small shifts in position during the Holocene in response to climate changes. Changes in wind direction associated with these shifts have induced modifications in the coastal dispersion system, which are recorded in the strandplains as small truncations in the beach-ridge alignments.

These results have important implications in understanding accumulation of ancient sandstone shoreline sequences.     

The 1631 Vesuvius eruption. A reconstruction based on historical and stratigraphical data

The eruption of 1631 A.D. was the most violent and destructive event in the recent history of Vesuvius. More than fifty primary documents, written in either Italian or Latin, were critically examined, with preference given to the authors who eyewitnessed volcanic phenomena. The eruption started at 7 a.m. on December 16 with the formation of an eruptive column and was followed by block and lapilli fallout east and northeast of the volcano until 6 p.m. of the same day. At 10 a.m. on December 17, several nuées ardentes were observed to issue from the central crater, rapidly descending the flanks of the cone and devastating the villages at the foot of Vesuvius. In the night between the 16th and 17th and on the afternoon of the 17th, extensive lahars and floods, resulting from rainstorms, struck the radial valleys of the volcano as well as the plain north and northeast.Deposits of the eruption were identified in about 70 localities on top of an ubiquitous paleosol formed during a long preeruptive volcanic quiescence. The main tephra unit consists of a plinian fallout composed of moderately vesicular dark green lapilli, crystals and lithics. Isopachs of the fallout are elongated eastwards and permit a conservative volume calculation of 0.07 km³. The peak mass flux deduced from clast dispersal models is estimated in the range 3–6 × 10⁷ kg/s, corresponding to a column height of 17–21 km. East of the volcano the plinian fallout is overlain by ash-rich low-grade ignimbrite, surges, phreatomagmatic ashes and mud flows. Ash flows occur in paleovalleys around the cone of Vesuvius but are lacking on the Somma side, suggesting that pyroclastic flows had not enough energy to overpass the caldera wall of Mt. Somma. Deposits are generally unconsolidated, massive with virtually no ground layer and occasionally bearing sparse rests of charred vegetation. Past interpretations of the products emitted on the morning of December 17 as lava flows are inconsistent with both field observations and historical data. Features of the final phreatomagmatic ashes are suggestive of alternating episodes of wet ash fallout and rainfalls. Lahars interfingered with primary ash fallout confirm episodes of massive remobilization of loose tephra by heavy rainfalls during the final stage of the eruption.Chemical analyses of scoria clasts suggest tapping of magma from a compositionally zoned reservoir. Leucite-bearing, tephritic-phonolite (SiO₂ 51.17%) erupted in the early plinian phase was in fact followed by darker and slightly more mafic magma richer in crystals (SiO₂ 49.36%). During the nuées ardentes phase the composition returned to that of the early phase of the eruption.The reconstruction of the 1631 eruptive scenario supplies new perspectives on the hazards related to plinian eruptions of Vesuvius.     

Geodynamic implications of deep mantle upwelling in the source of Tertiary volcanics from the Veneto region (South-Eastern Alps)

Major and trace element and Sr–Nd–Hf–Pb isotopic data for the most primitive Tertiary lavas from the Veneto region (South-Eastern Alps, Italy) show the typical features of HIMU hotspot volcanism, variably diluted by a depleted asthenospheric mantle component (⁸⁷Sr/⁸⁶Sr_i=0.70306–0.70378; _Ndi=+3.9 to +6.8; _Hfi=+6.4 to +8.1, ²⁰⁶Pb/²⁰⁴Pb_i=18.786–19.574). P-wave seismic tomography of the mantle below the Veneto region shows the presence of low-velocity anomalies at depth, which is consistent with possible upwellings of plume material. Between the depths of 100–250 km the velocity anomalies are approximately 2–2.5% slower than average, implying a temperature excess of about 220–280 K, in agreement with estimates for other mantle plumes in the world. In this context, the Veneto volcanics may represent the shallow expression of a mantle upflow. The presence of a HIMU-DM component in a collision environment has significant geodynamic implications. Slab detachment and ensuing rise of deep mantle material into the lithospheric gap is proposed to be a viable mechanism of hotspot magmatism in a subduction zone setting.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Observational study of the seasonality of the submonthly and intraseasonal signal over the tropics

Summary Atmospheric variability in outgoing long-wave radiation (OLR) and tropospheric relative vorticity (VOR) over the South American region was studied from 1979 to 1996 using the complex Morlet wavelet function. The analyses focus on spatial variation in intraseasonal and submonthly scales. Scalograms were used to measure submonthly intraseasonal oscillations in convection, which were found to be predominant in the tropical regions. However, 7-day and 15-day oscillations were observed at tropical and extratropical latitudes in spring and winter, indicating that transient disturbances play a more prominent role. Regarding VOR, tropical energy intensities were highest in the spring and summer, whereas subtropical and extratropical energy intensities were highest in the autumn and winter. The dynamics of the 25-day and 45-day VOR oscillations indicates a possible correlation with Rossby waves over the eastern tropical Pacific Ocean, mainly during the summer. During winter, the 7-day and 15-day VOR oscillations are more frequent at higher latitudes and are enhanced along storm tracks. It was also observed that convection amplitudes in the regions of maximum intensity change appreciably from year to year and from season to season, showing that the behavior of the submonthly and intraseasonal oscillations is nonperiodic and correlates strongly with El Ni?o/Southern Oscillation years. These results confirm the efficiency of wavelet analysis for time-scale studies of atmospheric variability.     

Processing and quality control of flux data during LITFASS-2003

Different aspects of the quality assurance and quality control (QA/QC) of micrometeorological measurements were combined to create a comprehensive algorithm which was then applied to experimental data from LITFASS-2003 (Lindenberg Inhomogeneous Terrain—Fluxes between Atmosphere and Surface: a long term Study). Eddy-covariance measurements of the latent heat flux were the main focus of the QA/QC efforts. The results of a turbulence sensor intercomparison experiment showed deviations between the different eddy-covariance systems on the order of 15%, or less than 30 W m⁻², for the latent heat flux and 5%, or less than 10 W m⁻², for the sensible heat flux. In order to avoid uncertainties due to the post-processing of turbulence data, a comprehensive software package was used for the analysis of experimental data from LITFASS-2003, including all necessary procedures for corrections and quality control. An overview of the quality test results shows that for most of the days more than 80% of the available latent heat flux data are of high quality so long as there are no instrumental problems. The representativeness of a flux value for the target land-use type was analysed using a stochastic footprint model. Different methods to calculate soil heat fluxes at the surface are discussed and a sensitivity analysis is conducted to select the most robust method for LITFASS-2003. The lack of energy balance closure, which was found for LITFASS-2003, can probably be attributed to the presence of low-frequency flux contributions that cannot be resolved with an averaging time of 30 min. Though the QA/QC system has been developed for the requirements of LITFASS-2003, it can also be applied to other experiments dealing with similar objectives.     

Tidally dominated, rimmed-shelf facies of the Picún Leufú Formation (Jurassic/Cretaceous boundary) in southwest Gondwana, Neuquén Basin, Argentina

A palaeoenvironmental model for the Picún Leufú Formation (Jurassic/Cretaceous boundary), which crops out in the Neuquén Basin, Argentina, on the southwestern margin of Gondwana, is presented in this paper for the first time. Detailed stratigraphic sections exposed along National Road 40 where it crosses the Picún Leufú Creek (type locality) and in the Cerrito Caracoles area, were examined and sampled. Based on a combination of the sedimentological data obtained (facies/microfacies analysis) and the relationship between benthic macrofaunas and their taphonomic attributes, it is concluded that the formation reflects a tidally dominated, rimmed-shelf setting characterized by prograding bars dissected by channels and thick lagoonal facies with shoal developments. In the Cerrito Caracoles area, where only the basal part of the formation is exposed, it is interpreted to have been deposited in a shallow subtidal marine environment in which shelf margin facies with patch reefs have been recognized.     

Simulating coseismic deformation of quartz in the middle crust and fabric evolution during postseismic stress relaxation — An experimental study

Non-steady state deformation and annealing experiments on vein quartz are designed to simulate earthquake-driven episodic deformation in the middle crust. Three types of experiments were carried out using a modified Griggs-type solid medium deformation apparatus. All three start with high stress deformation at a temperature of 400 °C and a constant strain rate of 10^− 4 s^− 1 (type A), some are followed by annealing in the stability field of α-quartz for 14–15 h at zero nominal differential stress and temperatures of 800–1000 °C (type A + B), or by annealing for 15 h at 900 °C and at a residual stress (type A + C).The quartz samples reveal a very high strength > 2 GPa at a few percent of permanent strain. The microstructures after short-term high stress deformation (type A) record localized brittle and plastic deformation. Statisc annealing (type A + B) results in recrystallisation restricted to the highly damaged zones. The new grains aligned in strings and without crystallographic preferred orientation, indicate nucleation and growth. Annealing at non-hydrostatic conditions (type A + C) results in shear zones that also develop from deformation bands or cracks that formed during the preceding high stress deformation. In this case, however, the recrystallised zone is several grain diameters wide, the grains are elongate, and a marked crystallographic preferred orientation indicates flow by dislocation creep with dynamic recrystallisation. Quartz microstructures identical to those produced in type A + B experiments are observed in cores recovered from Long Valley Exploratory Well in the Quaternary Long Valley Caldera, California, with considerable seismic activity.The experiments demonstrate the behaviour of quartz at coseismic loading (type A) and subsequent static annealing (type A + B) or creep at decaying stress (type A + C) in the middle crust. The experimentally produced microfabrics allow to identify similar processes and conditions in exhumed rocks.     

Images of Gradual Millimeter Emission and Multi-Wavelength Observations of the 17 august 1994 Solar Flare

We present a comprehensive analysis of the 17 August 1994 flare, the first flare imaged at millimeter (86 GHz) wavelengths. The temporal evolution of this flare displays a prominent impulsive peak shortly after 01:02 UT, observed in hard X-rays and at microwave frequencies, followed by a gradual decay phase. The gradual phase was also detected at 86 GHz. Soft X-ray images show a compact emitting region (20), which is resolved into two sources: a footpoint and a loop top source. Nonthermal emissions at microwave and hard X-ray wavelengths are analyzed and the accelerated electron spectrum is calculated. This energy spectrum derived from the microwave and hard X-ray observations suggests that these emissions were created by the same electron population. The millimeter emission during the gradual phase is thermal bremsstrahlung originating mostly from the top of the flaring loop. The soft X-rays and the millimeter flux density from the footpoint source are only consistent with the presence of a multi-temperature plasma at the footpoint.     

A current ribbon model for energy storage and release with application to the flare of 7 January 1992

Observations of the flare on 7 January 1992 are interpreted using a topological model of the magnetic field. The model, developed here, applies a theory of three-dimensional reconnection to the inferred magnetic field configuration for 7 January. In the model field a new bipole ( 10²¹ Mx) emerges amidst pre-existing active region flux. This emergence gives rise to two current ribbons along the boundaries (separators) separating the distinct, new and old, flux systems. Sudden reconnection across these boundary curves transfers 3 ×10²⁰ Mx of flux from the bipole into the surrounding flux. The model also predicts the simultaneous (sympathetic) flaring of the two current ribbons. This explains the complex two-loop structure noted in previous observations of this flare. We subject the model predictions to comparisons with observations of the flare. The locations of current ribbons in the model correspond closely with those of observed soft X-ray loops. In addition the footpoints and apexes of the ribbons correspond with observed sources of microwave and hard X-ray emission. The magnitude of energy stored by the current ribbons compares favorably to the inferred energy content of accelerated electrons in the flare.