青海省都兰县查哈西里地区地球化学异常特征及成矿远景评述

通过1：5万水系沉积物的地球化学测量,对查哈西里地区Au、Cu等16种元素的地球化学特征进行了初步分析.综合元素富集程度、分异程度、叠加强度,发现Au、Cu、Ni、Cr、Co在研究区内有富集成矿的可能,是研究区主要成矿元素.根据异常特征与成矿地质条件,推断区内为构造蚀变岩型Au-Cu多金属矿床及热液蚀变型Cu-Ni多金属矿床.优选出4处成矿远景区,即科德日特-巴嘎哈尔散金铜多金属成矿远景区、查干热格沟铜多金属成矿远景区、乌兰可镍多金属成矿远景区和马尼特沟南铁镍多金属成矿远景区.     

Ensemble simulation of land evapotranspiration in China based on a multi-forcing and multi-model approach

In order to reduce the uncertainty of offline land surface model(LSM) simulations of land evapotranspiration(ET), we used ensemble simulations based on three meteorological forcing datasets [Princeton, ITPCAS(Institute of Tibetan Plateau Research, Chinese Academy of Sciences), Qian] and four LSMs(BATS, VIC, CLM3.0 and CLM3.5), to explore the trends and spatiotemporal characteristics of ET, as well as the spatiotemporal pattern of ET in response to climate factors over mainland China during 1982–2007. The results showed that various simulations of each member and their arithmetic mean(Ens Mean) could capture the spatial distribution and seasonal pattern of ET sufficiently well, where they exhibited more significant spatial and seasonal variation in the ET compared with observation-based ET estimates(Obs MTE). For the mean annual ET, we found that the BATS forced by Princeton forcing overestimated the annual mean ET compared with Obs MTE for most of the basins in China, whereas the VIC forced by Princeton forcing showed underestimations. By contrast, the Ens Mean was closer to Obs MTE, although the results were underestimated over Southeast China. Furthermore, both the Obs MTE and Ens Mean exhibited a significant increasing trend during 1982–98; whereas after 1998, when the last big EI Ni ?no event occurred, the Ens Mean tended to decrease significantly between 1999 and 2007, although the change was not significant for Obs MTE. Changes in air temperature and shortwave radiation played key roles in the long-term variation in ET over the humid area of China, but precipitation mainly controlled the long-term variation in ET in arid and semi-arid areas of China.     

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.     

青藏高原东南缘基于背景噪声的Rayleigh面波方位各向异性研究

青藏高原东南缘地区是现今地壳形变和地震活动最强烈的地区之一,也是研究青藏高原现今变形机制和构造演化规律的重要区域.本研究使用云南区域地震台网的55个宽频带地震台站连续地震背景噪声数据,采用双台站互相关方法获得Rayleigh(瑞利)面波经验格林函数,提取相速度频散曲线,反演得到云南地区周期5~34s范围内方位各向异性分布图像.反演结果揭示:短周期(5~12s)Rayleigh面波快波优势方向与区域断裂走向有很好的一致性,快波方向随着断裂走向的变化而变化.周期16~26s快波优势方向与反映上地壳特性的5~12s图像总体图像相似,但细节略有不同.其中,滇中块体内易门断裂和滇中块体内东侧的普渡河断裂附近,各向异性快波方向从NS向NW方向旋转;易门断裂以西呈NW向.这反映了青藏高原物质东流和川滇块体受到青藏块体的南东向挤压作用.周期30~34s范围的各向异性,滇缅泰块体和印支块体,快波优势方向为NS和NNW向;而在滇中块体内部,各向异性快波方向呈顺时针旋转变化,可能与青藏高原物质向东逃逸有关.本文还开展了与体波各向异性的对比分析,通过与近震S波分裂、Pms转换波分裂和远震SKS、PKS和SKKS(以后简称为XKS)分裂的对比研究,发现随着周期的增大,得到的快波优势方向与XKS剪切波快波偏振方向趋向一致,与地壳快剪切波偏振方向呈一定夹角.本研究认为,青藏高原东南缘地区壳幔各向异性具有不同的特征和形成机制.     

2012-2018年巢湖水质变化趋势分析和蓝藻防控建议

巢湖自1990s中期至2012年间水质明显改善,但是近年来水质改善效果变缓,2018年蓝藻水华面积显著增加,为有效评估巢湖水体环境的变化,通过对2012-2018年巢湖17个点位的逐月调查数据分析阐述了近年来巢湖水质和藻情的变化特征,并在流域空间尺度上分析了巢湖流域水污染治理的进展和不足,为后续治理方向的调整和确定提供支撑.2012-2018年湖区调查数据显示:巢湖湖体总磷和总氮浓度显著升高,铵态氮浓度显著下降,水华蓝藻总量显著升高.在空间上,各污染指标水平呈现由西向东呈逐渐降低的趋势,但是各指标在不同湖区随时间的变化趋势差异明显,西部湖区的总磷、总氮和水华蓝藻指标近年来略有下降或持平,中部和东部湖区则显著升高,所以巢湖湖体总氮和总磷浓度的升高主要源于中、东部湖区的升高,这也是这两个湖区水华蓝藻变动的主要驱动因素.主要入湖河口数据显示:西部4条主要入湖污染河流(南淝河、十五里河、塘西河和派河)水质明显改善,但仍处于较高污染水平,中东部入湖河流(兆河、双桥河和柘皋河)总磷浓度明显升高,是中东部湖区水体营养盐升高的主要原因.中东部河流入湖污染的增加加剧了该区域湖体的富营养化水平,尤其是总磷...     

中国市场群落发展机制

市场群落的崛起已成为21世纪初中国市场经济发展的新景观，在概述市场群落的基本特点后，揭示其形成和演化的动力机制；继而对单个市场与群落型市场上经营者的行为方式特征进行了比较分析，表明群落型市场具有多方面的竞争优势；指出市场群落的空间扩张还促进了经济国际化与本地化的有机融合发展，同时认为，市场群落持续发展的根本在于保证商人的可持续发展，并提出了相应的对策建议。     

近江牡蛎两个野生种群的遗传多样性分析

采用RAPD分子标记和rDNA-ITS1序列分析了近江牡蛎Crassostrea rivularis湛江官渡和阳江程村野生种群的遗传多样性。12个RAPD引物共扩增出8838条片段,157个位点,平均每个引物可产生13个位点,片段长度在200～2200bp之间。湛江种群和阳江种群的多态位点比例分别为89.62%和89.57%,遗传多样性指数分别为0.4170和0.4334。种群间平均遗传距离为0.0327,平均遗传相似性为0.9681,平均遗传分化系数为0.0437。得到近江牡蛎18S、5.8S部分序列和ITS1全部序列,其中ITS1序列片段长度为478～485bp,共有11个变异位点,两个为转换(A/G),其他为插入/缺失(A/-、T/-)。湛江和阳江种群各获得8个单倍型,其中有一个单倍型为两个种群共享。两个种群的CG碱基平均含量较高,分别为58.29%和58.41%。种群间的遗传分化系数0.0254。结果说明,近江牡蛎湛江种群和阳江种群间具有较高的遗传多样性和较低的遗传分化。     

东濮凹陷新生代断裂特征分析

为了研究东濮凹陷新生代断裂系统的发育特征,通过对凹陷内不同区段地震剖面的解释,根据断层活动速率分析了东濮凹陷新生代断裂的活动特征及其强度,并对凹陷内不同部位的断层特征进行了对比分析。结果显示,东濮凹陷不同区段的断层发育特征既有一定的相似性,又有一定的差异性。断裂发育受到欧亚构造域和滨太平洋构造域的共同影响,同时在各区段受到的影响又有所差异。     

建南地区东岳庙段页岩气储层“四性”特征

建南地区侏罗系下统自流井组东岳庙段泥页岩发育,邻井多口井在该段普遍见良好的油气显示。页岩气储层为自生自储型油气藏,属于泥岩性质储层,具有低孔隙、超低渗透率的特点,文章通过对建南构造自流井组东岳庙段页岩气储层岩性、物性、电性、含气性特征及储层“四性”关系的研究,结合岩心、气测录井、试气等资料统计分析出页岩气储层的物性和电性下限值,进一步建立有效厚度解释图版,定量得出页岩气层的解释下限标准,为页岩气的评价解释提供了参考。     

释放化学物质耗空电离层电子密度的研究

电离层作为电波传播的主要通道和载体,影响着无线电通信的质量,因此人工电离层扰动具有广阔的应用前景.在电离层中释放具有较强电子亲和力的化学物质可以耗空电离层F区的电子密度,是人工电离层扰动的有效手段之一.本文通过对CO2和SF6气体在电离层中的扩散和离子化学反应过程的分析,理论计算了在我国北京地区上空释放这两种气体后电离层电子密度的时空演变过程.结果表明:(1)在电离层高度上释放100 kg的CO2或SF6气体后,电离层电子密度迅速减少,释放点周围局部区域的电子密度被耗空,能够形成一定尺度的电离层空洞,上述现象能够维持数小时之久;(2)与CO2气体相比,SF6气体具有扩散慢且化学反应快的优点,对电离层的影响较大,具有更好的电离层扰动效果.