傅里叶变换红外光谱(FTIR)方法在南海定量矿物学研究中的应用:以MD01-2393孔为例

傅里叶变换红外光谱 (FTIR)方法以其测量多种矿物绝对含量的能力在古环境研究中有很大的优势 .运用FTIR方法分析了南海南部湄公河口MD0 1 - 2 393孔的矿物成分含量 ,对比运用X射线衍射 (XRD)的半定量分析方法 ,研究了青藏高原东部和湄公河盆地晚第四纪 1 90ka以来风化剥蚀演化历史 .结果显示 ,全岩高岭石 /石英和粘土粒级 ( <2 μm)高岭石 /蒙脱石比率可用作陆源区风化侵蚀的矿物学标志 .晚第四纪 190ka以来 ,青藏高原东部和湄公河盆地机械侵蚀作用在冰期比间冰期强 ,化学风化作用在间冰期比冰期强 ,揭示出亚洲季风气候驱动的风化剥蚀演化历史 .全新世期间 ,虽然全岩高岭石 /石英与粘土粒级 ( <2 μm)蒙脱石 /高岭石比率指示相同趋势的风化剥蚀作用 ,但全岩高岭石 /石英比率显示更强的机械侵蚀能力 ,这可能是受湄公河口海平面快速变化的影响     

Microbial deposits in the aftermath of the end‐Permian mass extinction: A diverging case from the Mineral Mountains (Utah,USA)

The Lower Triassic Mineral Mountains area (Utah, USA) preserves diversified Smithian and Spathian reefs and bioaccumulations that contain fenestral‐microbialites and various benthic and pelagic organisms. Ecological and environmental changes during the Early Triassic are commonly assumed to be associated with numerous perturbations (productivity changes, acidifica‐tion, redox changes, hypercapnia, eustatism and temperature changes) post‐dating the Permian–Triassic mass extinction. New data acquired in the Mineral Mountains sediments provide evidence to decipher the relationships between depositional environments and the growth and distribution of microbial structures. These data also help to understand better the controlling factors acting upon sedimentation and community turnovers through the Smithian–early Spathian. The studied section records a large‐scale depositional sequence during the Dienerian(?)–Spathian interval. During the transgression, depositional environments evolved from a coastal bay with continental deposits to intertidal fenestral–microbial limestones, shallow subtidal marine sponge–microbial reefs to deep subtidal mud‐dominated limestones. Storm‐induced deposits, microbialite–sponge reefs and shallow subtidal deposits indicate the regression. Three microbialite associations occur in ascending order: (i) a red beds microbialite association deposited in low‐energy hypersaline supratidal conditions where microbialites consist of microbial mats and poorly preserved microbially induced sedimentary structure; (ii) a Smithian microbialite association formed in moderate to high‐energy, tidal conditions where microbialites include stromatolites and associated carbonate grains (oncoids, ooids and peloids); and (iii) a Spathian microbialite association developed in low‐energy offshore conditions that is preserved as multiple decimetre thick isolated domes and coalescent domes. Data indicate that the morphologies of the three microbialite associations are controlled primarily by accommodation, hydrodynamics, bathymetry and grain supply. This study suggests that microbial constructions are controlled by changes between trapping and binding versus precipitation processes in variable hydrodynamic conditions. Due to the presence of numerous metazoans associated with microbialites throughout the Smithian increase in accommodation and Spathian decrease in accommodation, the commonly assumed anachronistic character of the Early Triassic microbialites and the traditional view of prolonged deleterious conditions during the Early Triassic time interval is questioned.     

Morphometry of micrite particles in cretaceous microporous limestones of the Middle East: Influence on reservoir properties

Microporosity may account for a significant part of the total porosity of Cretaceous limestone reservoirs of the Middle East. In these microporous facies porosity is moderate to excellent (up to 35%) while permeability is poor to moderate (up to 190 mD). Micritic limestones also may form dense layers with very low porosity and permeability values.Micritic samples were collected from three fields of the Habshan and Mishrif Formations, to examine the spatial relationship with their porosity, permeability and pore throat radius distributions. Two key parameters of the micritic particles are studied using scanning electron microscopy: their morphology (shape and inter-crystal contacts), and their crystallometry.Results reveal that micrite matrixes can be subdivided into three petrophysical classes. Class C (strictly microporous limestones with coarse punctic-to-partially coalescent micrites) is made up of coarse (>2 μm) polyhedral to rounded micritic crystals, it has good to excellent porosity (8-28%), poor to moderate permeability (0.2-190 mD) and a mean pore threshold radius of more than 0.5 μm. The class C is usually observed in rudist shoal facies where relatively high hydrodynamic energy disfavoured deposition of the finer micritic crystals. It also developed within meteoric leaching intervals below exposure surfaces. Class F (strictly microporous limestones with fine punctic-to-partially coalescent micrites) is composed of fine (<2 μm) polyhedral to rounded micrites with poor to excellent porosity (3-35%), but permeability values of less than 10 mD and a mean pore threshold radius of less than 0.5 μm. It is mostly observed in sediments deposited in a low energy muddy inner platform setting. Class D (strictly microporous mud-dominated facies with compact anhedral to fused dense micrites) comprises subhedral to anhedral crystals with sutured contacts forming a dense matrix. It has very low porosity and permeability. Class D is only found in low energy muddy inner platform facies and forms inter-reservoir or caps rock layers in close association with stylolites and clay contents that usually exceed 10%.     

Control of the repeatability of high frequency multibeam echosounder backscatter by using natural reference areas

The increased use of backscatter measurements in time series for environmental monitoring necessitates the comparability of individual results. With the current lack of pre-calibrated multibeam echosounder systems for absolute backscatter measurement, a pragmatic solution is the use of natural reference areas for ensuring regular assessment of the backscatter measurement repeatability. This method mainly relies on the assumption of a sufficiently stable reference area regarding its backscatter signature. The aptitude of a natural area to provide a stable and uniform backscatter response must be carefully considered and demonstrated by a sufficiently long time-series of measurements. Furthermore, this approach requires a strict control of the acquisition and processing parameters. If all these conditions are met, stability check and relative calibration of a system are possible by comparison with the averaged backscatter values for the area. Based on a common multibeam echosounder and sampling campaign completed by available bathymetric and backscatter time series, the suitability as a backscatter reference area of three different candidates was evaluated. Two among them, Carré Renard and Kwinte, prove to be excellent choices, while the third one, Western Solent, lacks sufficient data over time, but remains a valuable candidate. The case studies and the available backscatter data on these areas prove the applicability of this method. The expansion of the number of commonly used reference areas and the growth of the number of multibeam echosounder controlled thereon could greatly contribute to the further development of quantitative applications based on multibeam echosounder backscatter measurements.     

Numerical modeling of the flow and transport of radionuclides in heterogeneous porous media

This paper is concerned with numerical methods for the modeling of flow and transport of contaminant in porous media. The numerical methods feature the mixed finite element method over triangles as a solver to the Darcy flow equation and a conservative finite volume scheme for the concentration equation. The convective term is approximated with a Godunov scheme over the dual finite volume mesh, whereas the diffusion–dispersion term is discretized by piecewise linear conforming triangular finite elements. It is shown that the scheme satisfies a discrete maximum principle. Numerical examples demonstrate the effectiveness of the methodology for a coupled system that includes an elliptic equation and a diffusion–convection–reaction equation arising when modeling flow and transport in heterogeneous porous media. The proposed scheme is robust, conservative, efficient, and stable, as confirmed by numerical simulations.      

The high temperature reaction zone of the Oman ophiolite: new field data,microthermometry of fluid inclusions,PIXE analyses and oxygen isotopic ratios

Marine Geophysical Research - The present study is focused on the so-called High Temprature Reaction Zone of the Oman ophiolite, a thin zone located between the roots of the sheeted dyke complex...     

Trophic relationships in tidepool fish assemblages of the tropical Southwestern Atlantic

Trophic studies are fundamental to understanding the dynamics of assemblages and functional roles of species within ecosystems, contributing to the identification of factors responsible for the organization and structure of communities. This study aimed to analyse the trophic organization of tidepool fish assemblages in the tropical Southwestern Atlantic, based on the underlying idea that food resources are not limiting and that trophic guild formation is not driven by food competition. Diets were based on feeding index values of food categories for 12 representative species collected in six tidepools (20º49′ S, 40º36′ W) at quarterly intervals (2005 to 2007). The main food categories were small crustaceans, polychaetes and macroalgae. Multivariate techniques evidenced two multispecific trophic guilds: small‐prey carnivores, including Bathygobius soporator, Bathygobius geminatus, Malacoctenus delalandii and Halichoeres poeyi, and herbivores, including Sparisoma axillare and Acanthurus bahianus. Other species presented significantly different diets and were classified into the following guilds: omnivores feeding on filamentous algae and copepods (Abudefduf saxatilis); large‐prey carnivores (Labrisomus nuchipinnis); omnivores feeding on polychaetes and filamentous algae (Stegastes fuscus); and polychaete feeders (Ahlia egmontis). Gymnothorax funebris and Gymnothorax moringa were classified as carcinophagores and piscivores, respectively. Trophic organization appears related to species convergence toward the use of abundant food resources, driven by a combination of factors allowing some resource partitioning through inter‐specific differences in consumer size, microhabitat, behavior, and trophic specialization.     

The stability of gypsum in marine sediments using the entire ODP/IODP porewater composition database

The stability of gypsum in marine sediments has been investigated through the calculation of its saturation index at the sediment in situ temperature and pressure, using the entire ODP/IODP porewater composition database (14416 samples recovered from sediments collected during 95 ODP and IODP Legs). Saturation is reached in sediment porewaters of 26 boreholes drilled at 23 different sites, during 12 ODP/IODP Legs. As ocean bottom seawater is largely undersaturated with respect to gypsum, the porewater Ca content or its SO₄ concentration, or both, must increase in order to reach equilibrium. At several sites equilibrium is reached either through the presence of evaporitic gypsum layers found in the sedimentary sequence, and/or through a salinity increase due to the presence of evaporitic brines with high concentrations of Ca and SO₄. Saturation can also be reached in porewaters of seawater-like salinity (≈ 35‰), provided sulfate reduction is limited. In this case, saturation is due to the alteration of volcanogenic material which releases large amounts of Ca to the porewaters, where the Ca concentration can reach 55 times its seawater value as for example at ODP Leg 134 site 833. At a few sites, saturation is reached in hydrothermal environments, or as a consequence of the alteration of the basaltic basement. In addition to the well known influence of brines on the formation of gypsum, these results indicate that the alteration of sediments rich in volcanogenic material is a major process leading to gypsum saturation in marine sediment porewaters. Therefore, the presence of gypsum in ancient and recent marine sediments should not be systematically interpreted as due to hypersaline waters, especially if volcanogenic material is present.     

The influence of pull-out load on the efficiency of jetting during spudcan extraction

Mobile jack-up drilling rigs are deployed at many locations during their service life. This necessitates retrieval of the platform’s legs and spudcan footings before the rig move. In soft soils, where the spudcans embed deeply, the extraction process can be difficult, time consuming and therefore costly. Water jetting systems, devised to ease spudcan extraction, are a common feature on modern jack-up units. However, their effectiveness in reducing the pull-out load required is questioned by the offshore industry. To investigate their efficiency, centrifuge experiments of a reduced scale spudcan model with jets have been performed at the University of Western Australia. The footing was extracted from penetrations of up to 1.5 diameters in normally consolidated clay. Similar to spudcan extraction in the field, these were carried out under load control, applying a constant extraction force. Both influences of pull-out load magnitude and jetting flow rate were investigated. The study demonstrates that jetting is efficient in facilitating spudcan extraction, as it reduces the required uplift load. Practical guidance is provided in applying the results to field conditions.