Etude d'un chondre extrait du lot 118-111 de sol lunaire de la Mer de la Fécondité

Two steps of crystallization can be identified in a Luna 16 chondrule: the first-formed silicates—mostly anorthitic plagioclase—acted as nuclei for the orthopyroxene fibers.     

Temporary and definitive fixation of atmospheric lead in deep-sea sediments of the Western Mediterranean Sea

Most lead brought to the Mediterranean Sea has an anthropogenic origin and is mainly transported through the atmosphere. Atmospheric Pb was continuously collected at Cap Ferrat in 1986 and 1987. From this study, the estimation of the anthropogenic Pb flux on the whole Western Mediterranean was, averaged on 1986 and 1987 data, 4080 t. Assuming that the atmospheric anthropogenic Pb input varied in this course of time similarly to the consumption of Pb added to gasolines in France, the mean annual flux could be calculated: 3.95 kg km⁻² yr⁻¹, that is an annual input of 3360 t yr⁻¹. Reaching the sea, this metal seems to become rapidly bound to phytoplankton. Grazing by zooplankton leads to the production of faecal pellets which frequently contain rather high metal concentrations. The sinking rate of pellets of various zooplankton species is high; within a few days pellets may reach deep-sea sediments. After deposition, Pb is released from this organic-rich material during early diagenesis. In most cases, it, therefore, returns to the overlaying water body by ascending diffusion. But, in a deep-sea area of approximately 80 000 km² where Mn oxide precipitation occurs in surficial sediments, Pb seems to remain stored by coprecipitation processes. By considering the lead stored in ‘excess’ in the surficial sediment of the deep-sea area, we estimate that a mean annual anthropogenic Pb amount ranging from 800 up to 1080 t was stored every year from 1950. On the same area, taking into account the Pb loss at the straits, the ‘direct’ atmospheric input to the sea bottom is, on average, 184 t yr⁻¹. The remaining part, that is (800–1080)−184=(616–896) t yr⁻¹, corresponds to an additional ‘indirect’ Pb flux in water due to Pb released from sediments of the surrounding areas where it does not remain stored.     

Relationships between field-aligned currents and convection observed by EISCAT and implications concerning the mechanism that produces region-2 currents: Statistical study

Fluid theories explain the origin of region-2 field-aligned currents as the closure of the ring current, driven itself by the azimuthal pressure gradients generated in the magnetospheric ring plasma by the sunward convection. Although the structure of pressure gradients appears experimentally complex, observations confirm that a close connection exists between the region-2 field-aligned currents and the ring current. The fluid linear theory of the adiabatic transport by convection of the ring plasma gives a first estimate of this process, and leads ultimately to phase quadrature (in terms of magnetic local time) between the region-2 field-aligned currents and the convection potential. When significant non-adiabatic processes are taken into account, such as precipitations at auroral latitudes, the theoretical phase difference rotates toward opposition. We determine experimentally the phase relationship between the region-2 field-aligned currents and the convection potential from recent statistics, depending on the magnetic activity index K_p, and performed from the EISCAT data base. For geometrical reasons of sufficient probing of region 2, it is only computed in the case of a moderate magnetic activity corresponding to 2\leqK_p<4. Region-2 field-aligned currents are found to be in phase opposition with the convection electrostatic potential at auroral latitudes. This confirms the importance of non adiabatic processes, especially ion losses, in the generation of region-2 field-aligned currents, as theoretically suggested.     

Topology-based proximities in spatial systems

This paper introduces several topology-based measures that characterise proximity relationships between regions in a spatial system. These measures are derived from a relative adjacency operator that is computed from the dual graph of a spatial system. The operator is flexible as the respective importance of neighbouring and outlying regions can be parameterised. Given a reference region in a spatial system, we also show how the relative adjacency supports the analysis of the relative distribution of other regions, and how these regions are clustered with respect to that reference region. Extensions of the relative adjacency integrate additional spatial and thematic criteria. The properties of the relative adjacency are illustrated by means of reference examples and a case study.The authors thank the referees for their constructive comments and suggestions that significantly improved the quality of the paper.     

Plate kinematics, origin and tectonic emplacement of supra-subduction ophiolites in SE Asia

A unique feature of the Circum Pacific orogenic belts is the occurrence of ophiolitic bodies of various sizes, most of which display petrological and geochemical characteristics typical of supra-subduction zone oceanic crust. In SE Asia, a majority of the ophiolites appear to have originated at convergent margins, and specifically in backarc or island arc settings, which evolved either along the edge of the Sunda (Eurasia) and Australian cratons, or within the Philippine Sea Plate. These ophiolites were later accreted to continental margins during the Tertiary. Because of fast relative plate velocities, tectonic regimes at the active margins of these three plates also changed rapidly. Strain partitioning associated with oblique convergence caused arc-trench systems to move further away from the locus of their accretion. We distinguish “relatively autochthonous ophiolites” resulting from the shortening of marginal basins such as the present-day South China Sea or the Coral Sea, and “highly displaced ophiolites” developed in oblique convergent margins, where they were dismantled, transported and locally severely sheared during final docking. In peri-cratonic mobile belts (i.e. the Philippine Mobile Belt) we find a series of oceanic basins which have been slightly deformed and uplifted. Varying lithologies and geochemical compositions of tectonic units in these basins, as well as their age discrepancies, suggest important displacements along major wrench faults.We have used plate tectonic reconstructions to restore the former backarc basins and island arcs characterized by known petro-geochemical data to their original location and their former tectonic settings. Some of the ophiolites occurring in front of the Sunda plate represent supra-subduction zone basins formed along the Australian Craton margin during the Mesozoic. The Philippine Sea Basin, the Huatung basin south of Taiwan, and composite ophiolitic basements of the Philippines and Halmahera may represent remnants of such marginal basins. The portion of the Philippine Sea Plate carrying the Taiwan–Philippine arc and its composite ophiolitic/continental crustal basement might have actually originated in a different setting, closer to that of the Papua New Guinea Ophiolite, and then have been displaced rapidly as a result of shearing associated with fast oblique convergence.     

Thermochemistry of jarosite-alunite and natrojarosite-natroalunite solid solutions

The thermochemistry of jarosite-alunite and natrojarosite-natroalunite solid solutions was investigated. Members of these series were either coprecipitated or synthesized hydrothermally and were characterized by XRD, FTIR, electron microprobe analysis, ICP-MS, and thermal analysis. Partial alkali substitution and vacancies on the Fe/Al sites were observed in all cases, and the solids studied can be described by the general formula K_1-x-yNa_y(H₃O)_xFe_zAl_w(SO₄)₂(OH)_6-3(3-z-w)(H₂O)_3(3-z-w). A strong preferential incorporation of Fe over Al in the jarosite/alunite structure was observed. Heats of formation from the elements, ΔH°_f, were determined by high-temperature oxide melt solution calorimetry. The solid solutions deviate slightly from thermodynamic ideality by exhibiting positive enthalpies of mixing in the range 0 to +11 kJ/mol. The heats of formation of the end members of both solid solutions were derived. The values ΔH°_f = −3773.6 ± 9.4 kJ/mol, ΔH°_f = −4912.2 ± 24.2 kJ/mol, ΔH°_f = −3734.6 ± 9.7 kJ/mol and ΔH°_f = −4979.7 ± 7.5kJ/mol were found for K_0.85(H₃O)_0.15Fe_2.5(SO₄)₂(OH)_4.5(H₂O)_1.5, K_0.85(H₃O)_0.15Al_2.5(SO₄)₂(OH)_4.5(H₂O)_1.5, Na_0.7(H₃O)_0.3Fe_2.7(SO₄)₂(OH)_5.1(H₂O)_0.9, and Na_0.7(H₃O)_0.3Al_2.7(SO₄)₂(OH)_5.1(H₂O)_0.9 respectively. To our knowledge, this is the first experimentally-based report of ΔH°_f for such nonstoichiometric alunite and natroalunite samples. These thermodynamic data should prove helpful to study, under given conditions, the partitioning of Fe and Al between the solids and aqueous solution.     

Oxygen isotope compositions of phosphate from arvicoline teeth and Quaternary climatic changes, Gigny, French Jura

Oxygen isotope compositions of biogenic phosphates from mammals are widely used as proxies of the isotopic compositions of meteoric waters that are roughly linearly related to the air temperature at high- and mid-latitudes. An oxygen isotope fractionation equation was determined by using present-day European arvicoline (rodents) tooth phosphate: δ¹⁸O_p = 20.98(±0.59) + 0.572(±0.065) δ¹⁸O_w. This fractionation equation was applied to the Late Pleistocene karstic sequence of Gigny, French Jura. Comparison between the oxygen isotope compositions of arvicoline tooth phosphate and Greenland ice core records suggests to reconsider the previously established hypothetical chronology of the sequence. According to the δ¹⁸O value of meteoric water-mean air temperature relationships, the δ¹⁸O value of arvicoline teeth records variations in mean air temperatures that range from 0° to 15°C.     

Flow behaviour and runout modelling of a complex debris flow in a clay‐shale basin

Identification of debris‐flow hazard areas necessitates the knowledge of the flow thickness and the runout distance. Both have been investigated using a numerical runout model. On the Faucon stream (South French Alps), representative of clay‐shale basins, results of various rheological tests and numerical experiments are presented and discussed. The calibration of the model was undertaken using the results of both geomorphological surveys and sedimentological analyses. Rheological tests using either a parallel‐plate rheometer, a coaxial rheometer, slump tests, and an inclined plane were carried out on several samples. Results have shown that the flow behaviour could be described by an Herschel‐Bulkley constitutive equation. The rheological responses of several natural suspensions collected from surficial deposits (sandstones, moraines, weathered black marls) were also investigated. In order to model the runout of the flow, the model BING was used. The model describes well the influence of each type of sediment on the behaviour (runout distance, deposit thickness) of the flow, although the velocities were significantly overestimated. Different risk scenarios are tested and discussed. Copyright © 2005 John Wiley & Sons, Ltd.     

Frontal advance of turf-banked solifluction lobes, Kluane Range, Yukon Territory, Canada

Humus horizons associated with thirteen solifluction lobes on a single slope were radiocarbon dated at fixed distances behind the risers, as well as ahead of the lobes. The dated horizons, together with stratigraphic observations of planar discontinuities inside the lobes and shallow burial of vegetation ahead of the lobes, all suggest rapid advance of lobe fronts. We infer that lobe advance at this site results from slow accumulation of soliflucted material behind a relatively rigid riser, progressive steepening of the riser and build-up of stress, and finally rupture of the front and its collapse onto the slope. Rebuilding of the lobe usually then takes place. The time for a full cycle of development is estimated to be in the order of a few hundred years. Long-term frontal movement appears inversely related to lobe size, and is mainly controlled by soil moisture and sediment characteristics. These findings call into question the usefulness of solifluction lobe advance rates for paleoclimate reconstructions, at least at this site.     

A climatic control on the accretion of meteoric and super-chondritic iridium–platinum to the Antarctic ice cap

Meteoric smoke particles (MSPs) form through the vaporization of meteoroids and the subsequent re-condensation of metallic species in the mesosphere. Recently, iridium and platinum enrichments have been identified in Greenland ice layers and attributed to the fallout of MSPs supplying polar latitudes with cosmic matter during the Holocene. However, the MSP fallout to Antarctica during the Earth's climatic history remains essentially unknown.

We have determined iridium and platinum in deep Antarctic ice from Dome C and Vostok dated back to 240 kyrs BP. We find high super-chondritic fluxes during warm periods and low meteoric accretion during glacial times, a pattern that is opposite to any known climatic variation in dust fallout to polar regions. The proposed explanation of this accretion regime is a weaker polar vortex during warm periods, allowing peripheral air masses enriched in volcanic iridium and platinum to penetrate inland to Antarctica. The MSP signal emerges only during cold phases and is four times lower than in the Greenland ice cap where more snow accumulates. This suggests that wet deposition is an important route of cosmic material to the Earth's surface.