Modelling in-situ upgrading of heavy oil using operator splitting method

The in-situ upgrading (ISU) of bitumen and oil shale is a very challenging process to model numerically because of the large number of components that need to be modelled using a system of equations that are both highly non-linear and strongly coupled. Operator splitting methods are one way of potentially improving computational performance. Each numerical operator in a process is modelled separately, allowing the best solution method to be used for the given numerical operator. A significant drawback to the approach is that decoupling the governing equations introduces an additional source of numerical error, known as the splitting error. The best splitting method for modelling a given process minimises the splitting error whilst improving computational performance compared to a fully implicit approach. Although operator splitting has been widely used for the modelling of reactive-transport problems, it has not yet been applied to the modelling of ISU. One reason is that it is not clear which operator splitting technique to use. Numerous such techniques are described in the literature and each leads to a different splitting error. While this error has been extensively analysed for linear operators for a wide range of methods, the results cannot be extended to general non-linear systems. It is therefore not clear which of these techniques is most appropriate for the modelling of ISU. In this paper, we investigate the application of various operator splitting techniques to the modelling of the ISU of bitumen and oil shale. The techniques were tested on a simplified model of the physical system in which a solid or heavy liquid component is decomposed by pyrolysis into lighter liquid and gas components. The operator splitting techniques examined include the sequential split operator (SSO), the Strang-Marchuk split operator (SMSO) and the iterative split operator (ISO). They were evaluated on various test cases by considering the evolution of the discretization error as a function of the time-step size compared with the results obtained from a fully implicit simulation. We observed that the error was least for a splitting scheme where the thermal conduction was performed first, followed by the chemical reaction step and finally the heat and mass convection operator (SSO-CKA). This method was then applied to a more realistic model of the ISU of bitumen with multiple components, and we were able to obtain a speed-up of between 3 and 5.     

A static drilling riser model using free boundary conditions

A static three-dimensional analytical method for drilling risers experiencing large displacements and slip at the top joint is presented. The riser is described in cylindrical coordinates as a three-dimensional tensioned string, without bending or torsional stiffness. The vertical vessel displacement is not taken into account. The equilibrium configuration is obtained from the stationary condition of the total potential energy functional. Kinematic boundary conditions are introduced for the radial displacement only. The riser orientation at the top directly follows from the natural boundary conditions based on the variational treatment of the energy functional.     

Rhodamine exclusion activity in primary cultured turbot (Scophthalmus maximus) hepatocytes

Cellular detoxification by direct processes has been investigated in fish by studying the ability of hepatocytes prepared from juvenile aquarium-reared turbot (Scophthalmus maximus) to actively exclude the fluorescent dye rhodamine B (RB). Cell viability was studied by measurements of non-specific esterase activity using fluorescein diacetate. This revealed that turbot hepatocytes can be cultured for a few days with a viability decreasing to 38% after 24 h. The 24-h cultured cells have been used to study the rhodamine B exclusion activity using confocal laser microscopy. Hepatocytes accumulated the dye in a competitive manner with verapamil, thus suggesting that they express a transport system similar to the P-glycoprotein-mediated multixenobiotic resistance process. Incubation of cells with 1 μM RB and 20 μM verapamil led to a 26% increase of cellular fluorescence as compared to the accumulation in absence of competitor. Rhodamine B accumulated in the whole cytoplasm, with more concentrated areas that might correspond to the lysosomal compartment and the cell membrane.     

Rhodamine exclusion activity in primary cultured turbot (Scophthalmus maximus) hepatocytes

Cellular detoxification by direct processes has been investigated in fish by studying the ability of hepatocytes prepared from juvenile aquarium-reared turbot (Scophthalmus maximus) to actively exclude the fluorescent dye rhodamine B (RB). Cell viability was studied by measurements of non-specific esterase activity using fluorescein diacetate. This revealed that turbot hepatocytes can be cultured for a few days with a viability decreasing to 38% after 24 h. The 24-h cultured cells have been used to study the rhodamine B exclusion activity using confocal laser microscopy. Hepatocytes accumulated the dye in a competitive manner with verapamil, thus suggesting that they express a transport system similar to the P-glycoprotein-mediated multixenobiotic resistance process. Incubation of cells with 1 microM RB and 20 microM verapamil led to a 26% increase of cellular fluorescence as compared to the accumulation in absence of competitor. Rhodamine B accumulated in the whole cytoplasm, with more concentrated areas that might correspond to the lysosomal compartment and the cell membrane.     

Numerical modeling of the elastoplastic damage behavior of dry and saturated concrete targets subjected to rigid projectile penetration

The objective of the present paper is to present a numerical study on the penetration performance of concrete targets with 2 different water contents. Numerical analysis has been performed by using the finite element code Abaqus/Explicit, in which a coupled elastoplastic damage model has been developed for saturated/unsaturated concrete under a wide range of confining pressures. The performance of proposed model has been firstly verified by simulating the triaxial compression tests and penetration tests realized with saturated/dry concretes. Comparisons of available experimental results and numerical simulations show that the proposed model is able to reproduce satisfactorily the mechanical behavior of saturated and dry concretes. A higher failure stress and a more important pores closing are generally obtained in dry concrete samples with respect to saturated ones. Furthermore, the main observed patterns of penetration test realized with saturated concrete targets are also satisfactorily simulated by the numerical results. Therefore, the proposed model is used to numerically predict the penetration performance of dry concrete target, and the penetration performance of dry/saturated concrete target is discussed. We observe that in dry concrete target, the penetration of projectile is strongly declined, and a smaller damage zone is created. The numerical predictions and discussions can help engineers to enhance their understandings on the influence of hydraulic conditions on structural vulnerability of concrete structures subjected to near‐field detonations or impacts.     

Socioeconomic impacts of environmental risks in the western Makran zone (Chabahar,Iran)

Natural Hazards - The western Makran subduction zone is capable of producing considerable tsunami run-up heights that penetrate up to 5 km inland. In this study, we show how climate change...     

Nutrient dynamics at the sediment-water interface in a Mediterranean lagoon (Thau, France): influence of biodeposition by shellfish farming activities

The Thau Lagoon, a French Mediterranean shallow lagoon, is a site where extensive shellfish farming occurs. The aim of the present work is to evaluate the role of this activity on nutrient exchange at the sediment-water interface in relation to organic matter (OM) sedimentation and degradation. Two stations inside (C5) and outside (C4) of the shellfish farming areas were sampled at three seasons. Porewater chemistry surveys and calculated diffusive fluxes were used to evaluate the trophic status of the Thau lagoon. Quantitative (Particulate Organic Carbon) as well as qualitative OM (Hydrogen Index, Carbohydrates) analyses were performed on sediments to assess OM characteristics. Results emphasized that surficial sediments at C5 are always more enriched in OM. Porewater nutrient concentrations are 10-20 times higher at C5 than at C4. In June 2003, the porewater profiles exhibit a sharp gradient at the bottom waters, indicating a hypereutrophic status, leading to an anoxic crisis.     

The geology of Hotei Regio, Titan: Correlation of Cassini VIMS and RADAR

Joint Cassini VIMS and RADAR SAR data of ∼700-km-wide Hotei Regio reveal a rich collection of geological features that correlate between the two sets of images. The degree of correlation is greater than anywhere else seen on Titan. Central to Hotei Regio is a basin filled with cryovolcanic flows that are anomalously bright in VIMS data (in particular at 5 μm) and quite variable in roughness in SAR. The edges of the flows are dark in SAR data and appear to overrun a VIMS-bright substrate. SAR-stereo topography shows the flows to be viscous, 100-200 m thick. On its southern edge the basin is ringed by higher (∼1 km) mountainous terrain. The mountains show mixed texture in SAR data: some regions are extremely rough, exhibit low and spectrally neutral albedo in VIMS data and may be partly coated with darker hydrocarbons. Around the southern margin of Hotei Regio, the SAR image shows several large, dendritic, radar-bright channels that flow down from the mountainous terrain and terminate in dark blue patches, seen in VIMS images, whose infrared color is consistent with enrichment in water ice. The patches are in depressions that we interpret to be filled with fluvial deposits eroded and transported by liquid methane in the channels. In the VIMS images the dark blue patches are encased in a latticework of lighter bands that we suggest to demark a set of circumferential and radial fault systems bounding structural depressions. Conceivably the circular features are tectonic structures that are remnant from an ancient impact structure. We suggest that impact-generated structures may have simply served as zones of weakness; no direct causal connection, such as impact-induced volcanism, is implied. We also speculate that two large dark features lying on the northern margin of Hotei Regio could be calderas. In summary the preservation of such a broad suite of VIMS infrared color variations and the detailed correlation with features in the SAR image and SAR topography evidence a complex set of geological processes (pluvial, fluvial, tectonic, cryovolcanic, impact) that have likely remained active up to very recent geological time (<10⁴ year). That the cryovolcanic flows are excessively bright in the infrared, particularly at 5 μm, might signal ongoing geological activity. One study [Nelson, R.M., and 28 colleagues, 2009. Icarus 199, 429-441] reported significant 2-μm albedo changes in VIMS data for Hotei Arcus acquired between 2004 and 2006, that were interpreted as evidence for such activity. However in our review of that work, we do not agree that such evidence has yet been found.     

Odyssey: a solar system mission

The Solar System Odyssey mission uses modern-day high-precision experimental techniques to test the laws of fundamental physics which determine dynamics in the solar system. It could lead to major discoveries by using demonstrated technologies and could be flown within the Cosmic Vision time frame. The mission proposes to perform a set of precision gravitation experiments from the vicinity of Earth to the outer Solar System. Its scientific objectives can be summarized as follows: (1) test of the gravity force law in the Solar System up to and beyond the orbit of Saturn; (2) precise investigation of navigation anomalies at the fly-bys; (3) measurement of Eddington’s parameter at occultations; (4) mapping of gravity field in the outer solar system and study of the Kuiper belt. To this aim, the Odyssey mission is built up on a main spacecraft, designed to fly up to 13 AU, with the following components: (a) a high-precision accelerometer, with bias-rejection system, measuring the deviation of the trajectory from the geodesics, that is also giving gravitational forces; (b) Ka-band transponders, as for Cassini, for a precise range and Doppler measurement up to 13 AU, with additional VLBI equipment; (c) optional laser equipment, which would allow one to improve the range and Doppler measurement, resulting in particular in an improved measurement (with respect to Cassini) of the Eddington’s parameter. In this baseline concept, the main spacecraft is designed to operate beyond the Saturn orbit, up to 13 AU. It experiences multiple planetary fly-bys at Earth, Mars or Venus, and Jupiter. The cruise and fly-by phases allow the mission to achieve its baseline scientific objectives [(1) to (3) in the above list]. In addition to this baseline concept, the Odyssey mission proposes the release of the Enigma radio-beacon at Saturn, allowing one to extend the deep space gravity test up to at least 50 AU, while achieving the scientific objective of a mapping of gravity field in the outer Solar System [(4) in the above list].