The GeoForschungsZentrum Potsdam/Groupe de Recherche de Gèodésie Spatiale satellite-only and combined gravity field models: EIGEN-GL04S1 and EIGEN-GL04C

The recent improvements in the Gravity Recovery And Climate Experiment (GRACE) tracking data processing at GeoForschungsZentrum Potsdam (GFZ) and Groupe de Recherche de Géodésie Spatiale (GRGS) Toulouse, the availability of newer surface gravity data sets in the Arctic, Antarctica and North-America, and the availability of a new mean sea surface height model from altimetry processing at GFZ gave rise to the generation of two new global gravity field models. The first, EIGEN-GL04S1, a satellite-only model complete to degree and order 150 in terms of spherical harmonics, was derived by combination of the latest GFZ Potsdam GRACE-only (EIGEN-GRACE04S) and GRGS Toulouse GRACE/LAGEOS (EIGEN-GL04S) mean field solutions. The second, EIGEN-GL04S1 was combined with surface gravity data from altimetry over the oceans and gravimetry over the continents to derive a new high-resolution global gravity field model called EIGEN-GL04C. This model is complete to degree and order 360 and thus resolves geoid and gravity anomalies at half- wavelengths of 55 km at the equator. A degree-dependent combination method has been applied in order to preserve the high accuracy from the GRACE satellite data in the lower frequency band of the geopotential and to form a smooth transition to the high-frequency information coming from the surface data. Compared to pre-CHAMP global high-resolution models, the accuracy was improved at a spatial resolution of 200 km (half-wavelength) by one order of magnitude to 3 cm in terms of geoid heights. The accuracy of this model (i.e. the commission error) at its full spatial resolution is estimated to be 15 cm. The model shows a reduced artificial meridional striping and an increased correlation of EIGEN-GL04C-derived geostrophic meridional currents with World Ocean Atlas 2001 (WOA01) data. These improvements have led to select EIGEN-GL04C for JASON-1 satellite altimeter data reprocessing. Electronic Supplementary Material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Diffusion induced Li isotopic fractionation during the cooling of magmatic rocks: The case of pyroxene phenocrysts from nakhlite meteorites

Ion-microprobe was used to measure Li abundances and isotopic compositions in pyroxenes from three Martian meteorites belonging to the nakhlite family. The profiles performed across augite crystals from Northwest Africa 817 show a large isotopic zoning from crystal cores (δ⁷Li ∼ 0‰) to rims (δ⁷Li ∼ +20‰) while Li abundances are almost constant (∼9.2 μg/g). Unlike NWA 817, the pyroxene studied in the Miller Range 03346 nakhlite shows a zoning in Li abundance, with concentrations increasing from ∼2.5 μg/g in the core to ∼9 μg/g in the rim. The augite rim (δ⁷Li = +7‰) is slightly enriched in ⁷Li with regard to the core (δ⁷Li = +4‰), but most of the isotopic variations observed occur at an intermediate position along the profile, where δ⁷Li falls down to ∼−11‰. In the case of Nakhla, Li concentrations in augite increase from cores (∼3.5 μg/g) to rims (∼6.5 μg/g), while the δ⁷Li variation is restricted (i.e., between δ⁷Li = +6.0 and +12.6‰). For the three meteorites the Li abundances were also measured in the groundmass, which was found to be enriched in lithium (∼10 μg/g). Conventional magmatic and post-magmatic processes such as alteration and fractional crystallization, fail to explain the dataset obtained on nakhlites. Degassing processes, which were previously proposed to explain the Li distribution in shergottite crystals, cannot result in the strong decoupling between Li abundances and isotopic composition observed in nakhlites. We suggest that the original magmatic Li distributions (concentrations and isotopic compositions) in nakhlites have been modified by diffusion of Li from the Li-rich groundmass towards the pyroxene crystals during sub-solidus cooling. Diffusion appears to have been efficient for NWA 817 and MIL 03346 but, apparently, did not produce a significant migration of Li in Nakhla, possibly because of the lower abundance of groundmass in the latter. Diffusion induced Li redistributions may also affect terrestrial porphyric rocks but very specific cooling rates are required to quench the diffusion profiles as observed in two of the present nakhlites.     

High rate anaerobic treatment of Sago wastewater using HUASB with PUF as carrier

Sago industry is one of the major small-scale sectors in India and over 800 units are located in the southern State of Tamilnadu. Processing of sago generates enormous quantities of high strength wastewater requiring systematic treatment prior to disposal. The present study is an attempt to treat the sago wastewater using Hybrid Upflow Anaerobic Sludge Blanket (HUASB) reactor, which offers the advantages of both fixed film and up flow anaerobic sludge blanket treatment. HUASB reactor with a volume of 5.6 L was operated at Organic Loading Rates varying from 10.7 to 24.7 kg COD/m³.day. After 130 days of startup, the reactor produced appreciable decrease in COD of wastewater and removed solids efficiently. The COD removal varied from 91–87%. While the removal of Total Solids was in the range of 61–57%, that of volatile solids varied from 70–67%. The ideal OLR for the reactor was 23.5 kg COD/m³.day. The findings of the study open up newer possibilities of design low cost and compact onsite treatment systems with very short retention periods.     

Holocene climate variability in Sicily from a discontinuous stalagmite record and the Mesolithic to Neolithic transition

Fabric and stable isotopic composition of a Holocene stalagmite (CR1) from a cave in northern Sicily record changes in paleorainfall in the early Holocene. High δ¹³C stable isotope values in the calcite deposited from ca. 8500 to ca. 7500 yr ago are interpreted as reflecting periods of high rainfall. The wet phase was interrupted by two periods of multi-century duration characterized by relatively cool and dry winters centered at ca. 8200 and ca. 7500 yr ago, highlighted by low δ¹³C and δ¹⁸O values. A high variability of δ¹³C values is recorded from ca. 7500 to ca. 6500 yr ago and indicates that the transition from a pluvial early Holocene to the present-day climate conditions was punctuated by decadal-scale periods of relatively dry winters. In northern Sicily, the traditional elements of the Neolithic appear at ca. 7700 yr ago. It is possible that changes in rainfall influenced the passage from hunter-gathering to farming and sheep-herding economies.     

Evolution of the late Cenozoic Chaco foreland basin, Southern Bolivia

Eastward Andean orogenic growth since the late Oligocene led to variable crustal loading, flexural subsidence and foreland basin sedimentation in the Chaco basin. To understand the interaction between Andean tectonics and contemporaneous foreland development, we analyse stratigraphic, sedimentologic and seismic data from the Subandean Belt and the Chaco Basin. The structural features provide a mechanism for transferring zones of deposition, subsidence and uplift. These can be reconstructed based on regional distribution of clastic sequences. Isopach maps, combined with sedimentary architecture analysis, establish systematic thickness variations, facies changes and depositional styles. The foreland basin consists of five stratigraphic successions controlled by Andean orogenic episodes and climate: (1) the foreland basin sequence commences between ～27 and 14 Ma with the regionally unconformable, thin, easterly sourced fluvial Petaca strata. It represents a significant time interval of low sediment accumulation in a forebulge‐backbulge depocentre. (2) The overlying ～14–7 Ma‐old Yecua Formation, deposited in marine, fluvial and lacustrine settings, represents increased subsidence rates from thrust‐belt loading outpacing sedimentation rates. It marks the onset of active deformation and the underfilled stage of the foreland basin in a distal foredeep. (3) The overlying ～7–6 Ma‐old, westerly sourced Tariquia Formation indicates a relatively high accommodation and sediment supply concomitant with the onset of deposition of Andean‐derived sediment in the medial‐foredeep depocentre on a distal fluvial megafan. Progradation of syntectonic, wedge‐shaped, westerly sourced, thickening‐ and coarsening‐upward clastics of the (4) ～6–2.1 Ma‐old Guandacay and (5) ～2.1 Ma‐to‐Recent Emborozú Formations represent the propagation of the deformation front in the present Subandean Zone, thereby indicating selective trapping of coarse sediments in the proximal foredeep and wedge‐top depocentres, respectively. Overall, the late Cenozoic stratigraphic intervals record the easterly propagation of the deformation front and foreland depocentre in response to loading and flexure by the growing Intra‐ and Subandean fold‐and‐thrust belt.     

Origin of the northern Indus Fan and Murray Ridge, Northern Arabian Sea: interpretation from seismic and magnetic imaging

The nature and origin of the sediments and crust of the Murray Ridge System and northern Indus Fan are discussed. The uppermost unit consists of Middle Miocene to recent channel–levee complexes typical of submarine fans. This unit is underlain by a second unit composed of hemipelagic to pelagic sediments deposited during the drift phase after the break-up of India–Seychelles–Africa. A predrift sequence of assumed Mesozoic age occurring only as observed above basement ridges is composed of highly consolidated rocks. Different types of the acoustic basement were detected, which reflection seismic pattern, magnetic anomalies and gravity field modeling indicate to be of continental character. The continental crust is extremely thinned in the northern Indus Fan, lacking a typical block-faulted structure. The Indian continent–ocean transition is marked on single MCS profiles by sequences of seaward-dipping reflectors (SDR). In the northwestern Arabian Sea, the Indian plate margin is characterized by several phases of volcanism and deformation revealed from interpretation of multichannel seismic profiles and magnetic anomalies. From this study, thinned continental crust spreads between the northern Murray Ridge System and India underneath the northern Indus Fan.     

Microstructural observations on natural syntectonic fibrous veins: implications for the growth process

Syntectonic antitaxial and ataxial fibrous veins were investigated using SEM, microprobe, cathodoluminescence (CL) and optical microscopy. In antitaxial calcite veins, fibres and surrounding selvage grew simultaneously, with similar growth rates of crystallographically differently oriented grains. New material precipitated at the vein margin in antitaxial and bi-mineralic ataxial microstructures. Bridges of country rock material formed during vein growth in an initial en-echelon vein system. In our antitaxial and bi-mineralic ataxial samples, the spacing of solid inclusions does not reflect individual crack-seal openings.     

Probability Density Functions as Botanical-Climatological Transfer Functions for Climate Reconstruction

We present a new procedure, the pdf method (pdf=probability density function), for reconstructing Quaternary climate utilizing botanical data. The procedure includes the advantages of the indicator species method by considering the fossil and modern presence and absence of taxa rather than their frequencies, thus avoiding the need for modern analog plant communities. Overcoming the problematic use of absolute limits to describe climate response ranges is the main progress of the pdf method in comparison to the indicator species method. This advantage results from estimating probability density functions (pdfs) for monthly mean January and July temperature conditional on the present day occurrence of single taxa. Gaussian distributions sufficiently approximate pdfs of many, although not all, studied taxa. On the assumption of statistical independence, the procedure calculates a joint pdf as the product of the pdfs of the individual taxa. This algorithm weights each taxon according to the extent of its climate response range expressed by its covariance structure. We interpret the maximum of the resulting pdf as the most likely climate and its confidence interval as the uncertainty range. To avoid an artificial reduction of uncertainty arising from the use of numerous similar pdfs, a preselection method is proposed based on the Mahalanobis distance between pdfs. The pdf method was applied to the Carpinus phase of a profile from Gröbern, Germany, that spans the last interglaciation (Eemian). The reconstructed most probable January and July temperatures of about 0.0°C and 18.4°C barely differ from the modern values of −0.5°C and 18.3°C.