Tidal river sediments in the Washington,D.C. area. III. Biological effects associated with sediment contamination

Sediment toxicity and benthic macroinvertebrate community structure were measured as one component of a study cohceived to determine the distribution and effect of sediment contamination in tidal freshwater portions of the Potomac and Anacostia rivers in the Washington, D.C., area. Samples were collected at 15 sites. Analyses included a partial life cycle (28 d) whole sediment test using the amphipod Hyalella azteca (Talitridae) and an assessment of benthic community structure. Survival and growth (as estimated by amphipod length) were experimental endopoints for the toxicity test. Significant mortality was observed in 5 of 10 sites in the lower Anacostia River basin and at the main channel Potomac River site. Sublethal toxicity, as measured by inhibition of amphipod growth, was not observed. Toxicity test results were in general agreement with synoptically measured sediment contaminant concentrations. Porewater total ammonia (NH₃+NH₄ ⁺) appears to be responsible for the toxicity of sediments from the Potomac River, while correlation analysis and simultaneously extracted metals: acid volatile sulfide (SEM∶AVS) results suggest that the toxicity associated with Anacostia River sediments was due to organic compounds. Twenty-eight macroinvertebrate taxa were identified among all sites, with richness varying from 5 to 17 taxa per site. Groups of benthic assemblages identified by group-average cluster analysis exhibited variable agreement with sediment chemical and sediment toxicity results. Integration of toxicological, chemical, and ecological components suggests that adverse environmental effects manifest in the lower Anacostia River benthos result from chemical contamination of sediment.     

Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

The energy balance experiment EBEX-2000. Part II: Intercomparison of eddy-covariance sensors and post-field data processing methods

The eddy-covariance method is the primary way of measuring turbulent fluxes directly. Many investigators have found that these flux measurements often do not satisfy a fundamental criterion—closure of the surface energy balance. This study investigates to what extent the eddy-covariance measurement technology can be made responsible for this deficiency, in particular the effects of instrumentation or of the post-field data processing. Therefore, current eddy-covariance sensors and several post-field data processing methods were compared. The differences in methodology resulted in deviations of 10% for the sensible heat flux and of 15% for the latent heat flux for an averaging time of 30 min. These disparities were mostly due to different sensor separation corrections and a linear detrending of the data. The impact of different instrumentation on the resulting heat flux estimates was significantly higher. Large deviations from the reference system of up to 50% were found for some sensor combinations. However, very good measurement quality was found for a CSAT3 sonic together with a KH20 krypton hygrometer and also for a UW sonic together with a KH20. If these systems are well calibrated and maintained, an accuracy of better than 5% can be achieved for 30-min values of sensible and latent heat flux measurements. The results from the sonic anemometers Gill Solent-HS, ATI-K, Metek USA-1, and R.M. Young 81000 showed more or less larger deviations from the reference system. The LI-COR LI-7500 open-path H₂O/CO₂ gas analyser in the test was one of the first serial numbers of this sensor type and had technical problems regarding direct solar radiation sensitivity and signal delay. These problems are known by the manufacturer and improvements of the sensor have since been made. The National Center for Atmospheric Research is supported by the National Science Foundation.     

European floods during the winter 1783/1784: scenarios of an extreme event during the ‘Little Ice Age’

The Lakagígar eruption in Iceland during 1783 was followed by the severe winter of 1783/1784, which was characterised by low temperatures, frozen soils, ice-bound watercourses and high rates of snow accumulation across much of Europe. Sudden warming coupled with rainfall led to rapid snowmelt, resulting in a series of flooding phases across much of Europe. The first phase of flooding occurred in late December 1783–early January 1784 in England, France, the Low Countries and historical Hungary. The second phase at the turn of February–March 1784 was of greater extent, generated by the melting of an unusually large accumulation of snow and river ice, affecting catchments across France and Central Europe (where it is still considered as one of the most disastrous known floods), throughout the Danube catchment and in southeast Central Europe. The third and final phase of flooding occurred mainly in historical Hungary during late March and early April 1784. The different impacts and consequences of the above floods on both local and regional scales were reflected in the economic and societal responses, material damage and human losses. The winter of 1783/1784 can be considered as typical, if severe, for the Little Ice Age period across much of Europe.     

Testing GISS-MM5 physics configurations for use in regional impacts studies

The Mesoscale Modeling System Version 5 (MM5) was one-way nested to the Goddard Institute for Space Studies global climate model (GISS GCM), which provided the boundary conditions for present (1990s) and future (IPCC SRES A2 scenario, 2050s) five-summer “time-slice” simulations over the continental and eastern United States. Five configurations for planetary boundary layer, cumulus parameterization, and radiation scheme were tested, and one set was selected for use in the New York City Climate and Health Project—a multi-disciplinary study investigating the effects of climate change and land-use change on human health in the New York metropolitan region. Although hourly and daily data were used in the health project, in this paper we focus on long-term current and projected mean climate change. The GISS-MM5 was very sensitive to the choice of cumulus parameterization and planetary boundary layer scheme, leading to significantly different temperature and precipitation outcomes for the 1990s. These differences can be linked to precipitation type (convective vs. non-convective), to their effect on solar radiation received at the ground, and ultimately to surface temperature. The projected changes in climate (2050s minus 1990s) were not as sensitive to choice of model physics combination. The range of the projected surface temperature changes at a given grid point among the model versions was much less than the mean change for all five model configurations, indicating relative consensus for simulating surface temperature changes among the different model projections. The MM5 versions, however, offer less consensus regarding 1990s to 2050s changes in precipitation amounts. All of the projected 2050s temperature changes were found to be significant at the 95th percent confidence interval, while the majority of the precipitation changes were not.     

A revised approach to water footprinting to make transparent the impacts of consumption and production on global freshwater scarcity

Through the interconnectedness of global business, the local consumption of products and services is intervening in the hydrological cycle throughout the world to an unprecedented extent. In order to address the unsustainable use of global freshwater resources, indicators are needed which make the impacts of production systems and consumption patterns transparent. In this paper, a revised water footprint calculation method, incorporating water stress characterisation factors, is presented and demonstrated for two case study products, Dolmio^® pasta sauce and Peanut M&M's^® using primary production data. The method offers a simple, yet meaningful way of making quantitative comparisons between products, production systems and services in terms of their potential to contribute to water scarcity. As such, capacity is created for change through public policy as well as corporate and individual action. This revised method represents an alternative to existing volumetric water footprint calculation methods which combine green and blue water consumption from water scarce and water abundant regions such that they give no clear indication about where the actual potential for harm exists.     

Intra-oceanic settings of the western Mexico Late Jurassic-Early Cretaceous arc sequences. Implications for the Pacific-Tethys geodynamic relationships during the Cretaceous

Abstract

The Guerrero suspect terrane composed of Late Jurassic-Early Cretaceous sequences, extends from Baja California up to Acapulco and is considered to be coeval with the Late Mesozoic igneous and sedimentary arc sequences of the Greater Antilles, Venezuela and Western Cordillera of Colombia. New geological, petrological and geochemical data from central and southern Mexico, led us to propose a new model for the building of the Alisitos-Teloloapan arc. This arc, partly built on the Pacific oceanic lithosphere and partly on continental fragments, could be related to the subduction of an oceanic basin - the Arperos basin - under the Paleo-Pacific plate. This subduction was dipping southwest.

At the beginning of the magmatic activity of the oceanic segment of this arc, depleted tholeiitic basalts were emitted in a submarine environnement below the CCD. While subduction was going on, the arc magmas evolved from LREE depleted tholeiites to slightly LREE enriched tholeiites and then, to calc-alkaline basalts and andesites enriched in LREE and HFSE. Concurrently, the arc sedimentary environment changed from deep oceanic to neritic with the deposition of Aptian-Albian reefal limestones, at the end of the arc building. In the continent-based segment, the arc magmas are exclusively differentiated calc-alkaline suites depleted in HREE and Y, formed of predominantly siliceous lavas and pyroclastic rocks, emitted in a sub-aerial or shallow marine environment.

Thus, taking into account this above mentioned model, the Cretaceous volcanic series, accreted to the margins of cratonal America, in Colombia, Venezuela, Greater Antilles and Mexico, could be related to the same west-south-west dipping subduction of oceanic basins, fringing the North and South American continental cratons and connected directly with the inter-American Tethys. While the subduction was proceeding, this magmatic arc drifted towards the North and South American cratons and finally, collided with the continental margins at different periods during the Cretaceous.     

Le magmatisme basique calcoalcalin d'âge dévono-dinantien du nord du Massif Central,témoin d'une marge active hercynienne: arguments géochimiques et isotopiques Sr/Nd

Abstract

Samples of volcanic rocks from the main outcrops of Devono-Dinantian series in northern Massif-Central have been studied for Sr and Nd isotopes and immobile incompatible trace elements. In addition, two intrusive bodies of dioritic composition have been dated at 365 ± 3 Ma (Aydat) and 360 ± 1 Ma (Beaumont-Huriel), using the U/Pb zircon method. Together with geochemical data, these ages show that all the studied rocks belong to the same igneous episode. Based on trace element and radiogenic isotopes (⁸⁷Sr/⁸⁶Sr_i from 0,7041 to 0,7057; εNd_i from +1.5 to +5.0), the Late Devonian and Early Carboniferous igneous rocks bear distinct similarities with magmas produced in modern active margin settings. Combined with independent evidence for the occurrence of Devonian oceanic lithosphere in the northern branch of the Variscides, these geochemical affinities suggest that southward subduction of oceanic crust prevailed during the Late Devonian in northern Massif-Central. As a corollary, it appears that true continent-continent collision did not occur before Early Carboniferous times. © 2002 Éditions scientifiques et médicales Elsevier SAS. All rights reserved.