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101.
Muddy sediments with their potential for containing contaminants are commonly deposited and remobilized by tidal currents in estuarine environments. We examined the mobilization and subsequent redeposition of mud in a coastal plain estuary located in the southeastern United States. Time-series data for salinity, suspended sediment concentrations and quality (percent organic matter and pigment concentrations) were obtained over a 13-hour tidal cycle. We found that fast-settling mud particles are found during the highest tidal current speeds. Particle quality analyses suggest that all the material is of similar origin, and that phaeopigment can be used as a tracer of particles in this system. These particles settle onto the bed when current speeds approach slack conditions. We speculate that the quantity of mud mobilized during neap tide is less than during spring tide resulting in an opportunity for the mud to partially consolidate on the bottom and be removed from resuspension. We further speculate that the muddy sediments are mainly derived from fringing marshes in this estuary.  相似文献   
102.
The aim of this study was to establish the source and provenance of sediments deposited in a large floodplain sink during extreme floods in the Lockyer Creek catchment, Australia, in 2011 and 2013. We place the sediment source patterns in context of the longer-term record to determine whether coarse-grained sediment sources (i.e., very fine sand to very coarse sand) and the spatio-temporal pattern of (dis)connectivity have changed over time. We do this by matching the geochemical properties and age structure of a sediment profile located in a downstream floodplain sink to the elemental composition of source sediments. One hundred and fifty-seven sediment samples from 20 sites across the catchment are analysed using X-ray fluorescence (XRF) spectrometry to compare the elemental ratio composition of the downstream floodplain sink to its source materials. We use Optically Stimulated Luminescence (OSL) dating to determine the age structure of the sediments in the floodplain sink. The northern tributaries and parts of the Lockyer River trunk stream are the primary sources of coarse sediment. These areas are connected (coupled) to the lower trunk stream and floodplain sediment sink. Southern tributaries are largely disconnected (decoupled) and supply little sediment to the floodplain sediment sink. This pattern of sediment source contribution has remained similar over the last 6.8 ka at least. Sediment sources as observed in the 2011 flood have predominated over the mid-late Holocene whilst those in the 2013 flood are rare.  相似文献   
103.
104.
This paper compares the performance of analytical and numerical approaches for modeling DNAPL dissolution with biodecay. A solution derived from a 1-D advective transport formulation (“Parker” model) is shown to agree very closely with high resolution numerical solutions. A simple lumped source mass balance solution in which with decay is assumed proportional to DNAPL mass (“Falta1” model) over- or underpredicts aqueous phase biodecay depending on the magnitude of the exponential factor governing the relationship between dissolution rate and DNAPL mass. A modification of the Falta model that assumes decay proportional to the source exit concentration is capable of accurately simulating source behavior with strong aqueous phase biodecay if model parameters are appropriately selected or calibrated (“Falta2” model). However, parameters in the lumped models exhibit complex interdependencies that cannot be quantified without consideration of transport processes within the source zone. Combining the Falta2 solution with relationships derived from the Parker model was found to resolve these limitations and track the numerical model results. A method is presented to generalize the analytical solutions to enable simulation of partial mass removal with changes in source parameters over time due to various remedial actions. The algorithm is verified by comparison with numerical simulation results. An example application is presented that demonstrates the interactions of partial mass removal, enhanced biodecay, enhanced mass transfer and source zone flow reduction applied at various time periods on contaminant flux reduction. Increasing errors that arise in numerical solutions with coarse discretization and high decay rates are shown to be controlled by using an adjusted decay coefficient derived from the Parker analytical solution.  相似文献   
105.
Lithology, pollen, macrofossils, and stable carbon isotopes from an intermontane basin bog site in southern New Zealand provide a detailed late-glacial and early Holocene vegetation and climate record. Glacial retreat occurred before 17,000 cal yr B.P., and tundra-like grassland–shrubland occupied the basin shortly after. Between 16,500 and 14,600 cal yr B.P., a minor regional expansion of forest patches occurred in response to warming, but the basin remained in shrubland. Forest retreated between 14,600 and 13,600 cal yr B.P., at about the time of the Antarctic Cold Reversal. At 13,600 cal yr B.P., a steady progression from shrubland to tall podocarp forest began as the climate ameliorated. Tall, temperate podocarp trees replaced stress-tolerant shrubs and trees between 12,800 and 11,300 cal yr B.P., indicating sustained warming during the Younger Dryas Chronozone (YDC). Stable isotopes suggest increasing atmospheric humidity from 11,800 to 9300 cal yr B.P. Mild (annual temperatures at least 1°C higher than present), and moist conditions prevailed from 11,000 to 10,350 cal yr B.P. Cooler, more variable conditions followed, and podocarp forest was completely replaced by montane Nothofagus forest at around 7500 cal yr B.P. with the onset of the modern climate regime. The Cass Basin late-glacial climate record closely matches the Antarctic ice core records and is in approximate antiphase with the North Atlantic.  相似文献   
106.
Private standards and certification schemes are widely acknowledged as playing an increasingly important role in agri-environmental governance. While much of the existing research concludes that these mechanisms consolidate the global extension of neoliberalism – enhancing the power of corporate actors to the detriment of smaller producers – we argue that this overlooks the complex ways in which standards are used by governments and farmers in the governing of farming practices. Focusing specifically on a process standard – Environmental Management Systems (EMS) – promoted by the Australian government as a way of verifying the ‘clean and green’ status of agricultural exports, we examine how one regional group of producers has sought to use EMS standards in practice. Our analysis of a case study in the state of Victoria appears to confirm that EMS was a successful instrument for the extension of neoliberal governance, reinforcing the production of neoliberal subjectivities and practices amongst farmer participants and enabling the government to compensate for gaps in environmental provision. However, it would be a mistake to interpret the development of this EMS scheme as an example of naïve farmers manipulated by the state. In practice, farmers used the opportunities provided by government funding to undertake actions which expressed their own agri-environmental values and practices. Establishment of an EMS and associated eco-label enabled producers to demonstrate and extend their capacity to act as good environmental stewards. Our research highlights how the local application of environmental standards negotiates and shapes, rather than simply contributes to, neoliberal rule.  相似文献   
107.
Despite questions currently raised about the future of neoliberalism, it remains embedded within Australian agricultural policy and practice. This paper explores the strengths and limitations of mechanisms contributing to neoliberalism’s survival through a close examination of the restructuring of Australian agricultural production and governance processes under the influence of both globalising impulses and adherence to neoliberal strategies. We trace the changes in governance flowing from the dismantling of regulatory structures in the Australian dairy industry, and the creation of new forms of governance that have both facilitated this transition and dealt with its adverse, often unintended, consequences. The changing governance of Australian dairying is analysed through the lens of three arenas of governance: state, industry and place. Drought has played an important part in re-spacialising dairying and re-shaping the balance between farmers and industry, demonstrating the contingency at play in emerging governance structures. This study of processes of change within the highly export-oriented dairy sector of Australia focuses attention on resistance and on some of the messy actualities of the interplay between state, place and industry - and nature - in neoliberal agri-food governance.  相似文献   
108.
Vertical velocity profiles measured over various bed configurations (plane beds, ripples, and dunes) in. the meandering River South Esk, Glen Clova, Scotland are presented on semilogarithmic paper. Local bed shear stress and roughness height are calculated from the lowermost parts of the profiles using the Karman-Prandtl law of the wall; these parameters, and the geometrical properties of the profiles, are related to the various bed configurations. A graphical model is used to identify profiles developed on specific regions of dune geometry, in order to discriminate those profiles that define bed shear effective in transporting sediment over dunes. An assessment is made of the errors involved in estimating local mean velocity from extrapolating the law of the wall to the water surface. A Darcy-Weisbach friction coefficient is related to bed configuration and local stream power.  相似文献   
109.
A number of processes may modify the noble gas composition of silicate liquids so that the composition of noble gases observed in glassy margins of deep-sea basalts is not that of the upper mantle. Differential solubility enhances the light noble gases relative to the heavier gases; however, we demonstrate that the observed abundance pattern cannot be attributed to solubility of noble gases with atmospheric proportions. Partial melting and fractional crystallization increase the noble gas content of all species relative to mantle concentrations, but do not fractionate their relative abundances. Noble gases may be lost from an ascending magma in various ways, the most important, however, may be exclusion of gas from crystals forming at the time of solidification, which is shown to result in marked loss of gas from the basalt. Small amounts of low-temperature alteration of solidified basalt can produce dramatic changes in the noble gas abundance pattern, since the adsorption coefficients for the different noble gas favor uptake of heavy species relative to the light species. Atmospheric contamination can account for observed variations in the 40Ar/36Ar ratio of oceanic basalts. The degree of crystallinity of glassy margins of deep-sea basalts may control the helium abundance of these samples; however, the uniform 3He/4He values reported apparently reflect a relatively constant proportion of radiogenic and primordial helium in the mantle.  相似文献   
110.
Recent studies have highlighted the importance of understanding ecohydrological drought feedbacks to secure water resources under a changing climate and increasing anthropogenic impacts. In this study, we monitored and modelled feedbacks in the soil–plant-atmosphere continuum to the European drought summer 2018 and the following 2 years. The physically based, isotope-aided model EcH2O-iso was applied to generic vegetation plots (forest and grassland) in the lowland, groundwater-dominated research catchment Demnitzer Millcreek (NE Germany; 66 km2). We included, inter alia, soil water isotope data in the model calibration and quantified changing “blue” (groundwater recharge) and “green” (evapotranspiration) water fluxes and ages under each land use as the drought progressed. Novel plant xylem isotope data were excluded from calibration but were compared with simulated root uptake signatures in model validation. Results indicated inter-site differences in the dynamics of soil water storage and fluxes with contrasting water age both during the drought and the subsequent 2 years. Forest vegetation consistently showed a greater moisture stress, more rapid recovery and higher variability in root water uptake depths from a generally younger soil water storage. In contrast, the grassland site, which had more water-retentive soils, showed higher and older soil water storage and groundwater recharge fluxes. The damped storage and flux dynamics under grassland led to a slower return to younger water ages at depth. Such evidence-based and quantitative differences in ecohydrological feedbacks to drought stress in contrasting soil-vegetation units provide important insights into Critical Zone water cycling. This can help inform future progress in the monitoring, modelling and development of climate mitigation strategies in drought-sensitive lowlands.  相似文献   
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