Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

Geomechanical model for fracture deformation under hydraulic, mechanical and thermal loads

Hydraulic flow and transport (heat and solute) within crystalline rocks is dominated by the fracture systems found within them. In situ stress conditions have a significant impact on the hydraulic, mechanical and thermal coupled processes, and quantification of these processes provides a key to understanding the often transient time-dependent behaviour of crystalline rocks. In this paper, a geomechanical model is presented which describes fracture closure as a function of effective stress and the changes in parameters such as storage, permeability, porosity and aperture. Allowing the fracture closure to be defined by the change in normal effective stress provides a link to the numerical consideration of parametrical changes due to rock stress alterations caused for example by changes in fracture fluid pressure, stress release, tectonic stress, thermal stress, orientation of the natural fracture in the pervasive stress system and local changes in a rock mass due to stress alteration. The model uses geometrical considerations based on a fractal distribution of apertures on the fracture surface, and applies well-established analytical elastic deformation solutions to calculate the deformation response to changes in effective stress. Analysis of the fractal generation method allows a standard normal distribution of fracture apertures to be predicted for all common fractal dimensions relating to a 2D surface. Changes in the fracture aperture are related to hydraulic functions such as permeability, storage and porosity of the fracture. The geomechanical model is experimentally validated against laboratory scale experimental data gained from the closure of a fractured sample recovered at a depth of 3,800 m from the KTB pilot borehole. Parameters for matching the experimental data were established externally, the only fitting parameters applied were the minimum and maximum contact area between the surfaces and the number of allowable contacts. The model provides an insight into the key processes determining the closure of a fracture, and can act as a material input function for numerical models linking the effects of changes in the stress field, hydraulic or thermal conditions, to the flow and transport parameters of a fractured system.

---

Résumé L’écoulement et le transport (chaleur et soluté) dans les roches cristallines sont dominés par les systèmes de fracture. Les conditions de stress in-situ ont un impact significatif sur l’hydraulique, les processus couplés de mécanique et thermique et la quantification de ces processus apportent une clé pour comprendre le comportement transitoire des roches cristallines. Dans cet article un modèle géomécanique est présenté, modèle qui décrit la fermeture des fractures comme une fonction de la contrainte effective et des changements de paramètres tels le coefficient d’emmagasinement, la perméabilité, la porosité et l’ouverture. En s’accordant que la fermeture des fractures est définit par les changements de la contrainte effective normale, on apporte le lien avec la considération numérique des changements paramétriques dus aux altérations de la contrainte des roches, causés par exemple par des variations de la pression des fluides dans les fractures, du dégagement de la contrainte, des contraintes tectoniques et thermiques, des orientations des fractures naturelles dans le système de contraintes pénétrantes, et des changements locaux dans un massif de roches dus à l’altération des contraintes. Le modèle utilise des considérations géométriques basées sur une distribution fractale des ouvertures à la surface des fractures, et permet d’établir des solutions analytiques de la déformation élastique pour calculer la réponse de la déformation à la contrainte effective. L’analyse de la méthode par génération fractale permet de prédire une distribution normale standard de l’ouverture des fractures, pour toutes les dimensions fractales en relation avec les surfaces 2D. Les changements dans l’ouverture des fractures sont mis en relation avec les fonctions hydrauliques tels la perméabilité, l’emmagasinement et la porosité de la fracture. Le modèle géoméchanique est expérimentalement validé à l’échelle du laboratoire sur un échantillon fracturé récupéré à une profondeur de 3,800 mètres sur le puits du site pilote KTB. Les paramètres du calibrage des données expérimentales ont été établies extérieurement, les seuls paramètres utilisés étant les surfaces de contact minimum et maximum, et le nombre de contacts permis. Le modèle apporte une connaissance perspicace sur le processus clé déterminant la fermeture des fractures, et peut servir de fonction input dans les modèles numériques reliant les effets des variations de la contrainte du terrain, les conditions hydrauliques ou thermales, les paramètres de l’écoulement et du transport et les systèmes de fracture.

---

Resumen El flujo hidráulico y transporte (de calor y solutos) dentro de rocas cristalinas está dominado por los sistemas de fracturas que se encuentran en ellas. Las condiciones de esfuerzos in-situ tienen un impacto significativo en los procesos aparejados termales, mecánicos e hidráulicos y la cuantificación de estos procesos aporta una clave para entender el frecuente comportamiento transitorio dependiente de las rocas cristalinas. En este artículo se presenta un modelo geomecánico que describe el cierre de fracturas en función del esfuerzo efectivo y los cambios en parámetros tal como almacenamiento, permeabilidad, porosidad y apertura. El definir el cierre de fractura mediante el cambio en esfuerzo normal efectivo aporta un vínculo con la consideración numérica de cambios paramétricos ocasionados por alteraciones de esfuerzos en la roca causadas, por ejemplo, por cambios en presión de fluidos en fractura, liberación de esfuerzo, esfuerzo tectónico, esfuerzo termal, orientación de fracturas naturales en el sistema de esfuerzos penetrante, y cambios locales en una masa rocosa ocasionados por alteración de esfuerzos. El modelo utiliza consideraciones geométricas basadas en la distribución fractal de aperturas en la superficie de fractura y aplica soluciones analíticas bien establecidas de deformación elástica para calcular la respuesta de deformación a cambios en el esfuerzo efectivo. Los análisis del método de generación fractal permiten predecir una distribución normal standard para la distribución de aperturas de fracturas para todas las dimensiones fractales comunes que se relacionan con una superficie 2D. Los cambios en la apertura de fractura se relacionan con funciones hidráulicas tal como permeabilidad, almacenamiento y porosidad de la fractura. El modelo geomecánico se ha validado experimentalmente en contra de datos experimentales a escala de laboratorio obtenidos a partir del cierre de una muestra fracturada recuperada a una profundidad de 3,800 m en el pozo piloto KTB. Se establecieron externamente parámetros que se ajustan a los datos experimentales, con los parámetros de ajuste aplicados que fueron el área máxima y mínima de contacto entre las superficies y el número de contactos permisibles. El modelo arroja luz sobre los procesos clave que determinan el cierre de una fractura y puede actuar como un material de función de entrada para modelos numéricos que vinculan los efectos de cambios en el campo de esfuerzos, condiciones termales o hidráulicas, con los parámetros de flujo y transporte de un sistema fracturado.

     

Validation of a fish farm waste resuspension model by use of a particulate tracer discharged from a point source in a coastal environment

To validate a resuspension model of particulate material (salmonid farm wastes), a UV fluorescent particle tracer was selected with similar settling characteristics. Tracer was introduced to the seabed (water depth ≈30 m) and sediment samples taken on days 0, 3, 10, 17 and 30 to measure the horizontal and vertical distribution of tracer in sediments. A concentric sampling grid was established at radii of 25, 50, 100, 150, 200, 400, 700 and 1, 000 m from the source on transects 30° apart. The bulk of the deployed tracer was initially concentrated in an area 25 m radius from the release point; tracer was observed to steadily decrease to zero over a period of 30 days. In a 200 m region measured from the release point in the direction of the residual current, the redeposition of tracer was low. A Lagrangian particle tracking model was validated using these observed data by varying resuspension model parameters within limits to obtain the best agreement between spatial and temporal distributions. The validated model generally gave good predictions of total mass budgets (±7% of total tracer released), particulary where tracer concentrations were high near the release point. Best fit model parameters (critical erosion shear stress=0.018 N m⁻², erodibility constan=60 g m⁻² d⁻¹) are at the low end of reported parameters for coastal resuspension models. Such a low critical erosion shear stress indicates that the frequency of resuspension and deposition events for freshly deposited material is high.     

成都市民消费结构与休闲活动关系研究

城市居民消费水平，消费结构会影响其休闲消费能力，消费意愿，消费方式，消费态度和休闲时空结构，文章以成都市7个城区歌舞，茶棋牌，电影及城市公园休闲活动调查为基础，探讨了城市居民消费结构及其变化与休闲活动特征的关系。研究结果表明，城市居民消费结构的改变对歌舞，茶棋牌娱乐活动影响最大。     

区域视觉形象识别系统设计的理论与实践

目前，全国各地正在兴起区域形象设计与建设的浪潮，但如何把区域形象信息系统地传递出去，这方面的理论研究大大落后于实践。文章就区域形象信息传递的有效工具－区域视觉识别系统设计的主要内容，设计的原则，设计的基本流程等在理论与实践上作了较为详细的探讨，并就区域视觉识别系统设计方案的经济学论证作了一些有益探讨。     

河南经济技术开发区发展前景与对策

文章阐述了经济技术开发区在区域经济发展过程中的作用。根据河南省经济技术开发区的发展现状和存在的问题，分析了加入WTO后开发区所面临的机遇和挑战，并在此基础上从开发区环境营造，运行机制，筹资方式，产业发展，城市建设等方面提出了加快河南省经济技术开发区发展的对策。     

土地持续利用的五维空间分析

土地资源的持续利用是人类社会发展的基础，文章较为系统地提出了时间，空间，用途，技术和制度是实现土地资源持续利用的五维空间，并对各维度的内涵进行了较为深入的分析。其中，土地持续利用的时间维主要表现为从伦理角度考虑如何在代际间合理分配土地资源，使代际间利益之和最大；空间维则要求实现土地利用在空间上的合理布局；胜任维要求将土地资源合理配置到各种用途上，从而使人们从土地所提供的产品和劳各中获得的总效用最大；技术维选择意味着土地利用的直接或间接技术的选用能够保证土地的永续使用；制度维要求制度建设适应土地利用情况的变化，通过消除不同的土地制度之间存在着的外部利润来实现土地资源的最优配置。     

旅游信息系统建设模式探讨——以佛山市为例

作为当前旅游信息系统开发的两种主要基础平台，地理信息系统和多媒体制作系统都存在一定的缺陷。多媒体制作系统缺乏旅游地图的有效管理，空间查询，分析和统计功能，旅游地理信息系统则缺乏旅游信息的多媒体表达能力。从实用性和普及性出发，集合二者优点开发模式具有更大的推广应用价值。因此，论文提出在同一界面下基于GIS和多媒体集成的旅游信息系统开发模式；（1）在GIS中增加多媒体信息表达能力，以关系数据库为核心，把多媒体文件名信息存储在地理信息系统属性库，依靠多媒休段实现多媒体数据与地理信息系统图形和属性的关联，实现查询的基本概念；（2）在多媒体系统中开发部分GIS空间查询功能。以此思路，佛山科技学院GIS技术实验室利用VB进行GIS和多媒体二次开发，成功地完成了佛山旅游信息系统的设计和开发。