GHOST – A Novel Airborne Gas Chromatograph for In Situ Measurements of Long-Lived Tracers in the Lower Stratosphere: Method and Applications

A novel fully-automated airborne gas chromatograph for in situmeasurements of long-lived stratospheric tracers hasbeen developed, combining the high selectivity of a megabore PLOTcapillary column with recently developed sampling and separationtechniques. The Gas cHromatograph for theObservation of Stratospheric Tracers (GHOST)has been successfully operated during three STREAM campaigns(Stratosphere TRoposphere Experiment byAirborne Measurement) onboard a Cessna Citation IIaircraft in two different modes: Either N₂O andCF₂Cl₂(CFC-12) or CFC-12 and CFCl₃ (CFC-11) have been measuredsimultaneously, with a time resolution of 2 min for both modes.Under flight conditions the instrument precision (1) forthese species is better than 0.9%, and the accuracy(1) is better than 2.0% of the tropospheric values ofall measured compounds. The detection limits (3) arebelow 28 ppb for N₂O, 14 ppt for CFC-12, and 8 ppt forCFC-11, respectively, i.e., well below 10 % of the troposphericvalues of all measured compounds. Post-mission optimization of thechromatographic separation showed a possible enhancement of thetime resolution by up to a factor of 2, associated with acomparable increase in precision and detection limit. As test ofactual performance of GHOST results from an in-flight N₂Ointercomparison with a tunable diode laser absorptionspectrometer (TDLAS) are presented. They yield an excellentagreement between both instruments. Furthermore, on the basis ofthe hitherto most extensive set of upper tropospheric and lowerstratospheric data, the relative stratospheric N₂2O lifetime isre-assessed. When referenced to the WMO reference CFC-11 lifetimeof 45 ± 7 years an N₂O lifetime of 91 ± 15 yearsis derived, a value substantially smaller than the WMO referencelifetime of 120 years. Moreover, this value implies astratospheric N₂O sink strength of 16.3 ± 2.7 Tg (N)yr^–1 which is 30% larger than previous estimates.     

Numerical inverse interpretation of single-hole pneumatic tests in unsaturated fractured tuff

A numerical inverse method was used to interpret simultaneously multirate injection and recovery data from single-hole pneumatic tests in unsaturated fractured tuff at the Apache Leap Research Site near Superior, Arizona. Our model represents faithfully the three-dimensional geometry of boreholes at the site, and accounts directly for their storage and conductance properties by treating them as high-permeability and high-porosity cylinders of finite length and radius. It solves the airflow equations in their original nonlinear form and yields information about air permeability, air-filled porosity and dimensionless borehole storage coefficient. Some of this is difficult to accomplish with analytical type-curves. Air permeability values obtained by our inverse method agree well with those obtained by steady-state and type-curve analyses.     

Particle size and sorting characteristics of sand in transport on the stoss slope of a small reversing dune

Studies of the particle size and sorting characteristics of sand on the stoss slope of a 6-m high reversing dune show that the sand in transport is generally finer and better sorted than surface sand at the same position on the slope. The sand in transport becomes coarser and more poorly sorted as wind speed and rates of mass transport increase toward the dune crest. These patterns reflect changes in the competence of the wind, which is capable of transporting larger grains and a wider range of grain sizes as its speed increases in space and time. Our field observations suggest that the particle size and sorting characteristics of surface sand are highly dependent on antecedent wind conditions and are not an invariant property of the dune, as is widely assumed. The wide range of particle sizes on the surface, as well as its change through time, also has important implications for modeling sediment transport on dunes. Transport thresholds may vary by as much as 30% on the stoss slope of the study dune.     

Range-wide population structure of shortnose sturgeonAcipenser brevirostrum based on sequence analysis of the mitochondrial DNA control region

Riverine populations of shortnose sturgeon (Acipenser brevirostrum) once occurred in rivers and estuaries along the east coast of North America from the St. John River, New Brunswick, to the St. Johns River, Florida. Within this range, 19 population segments were identified by the U.S. Federal Shortnose Sturgeon Recovery Team; empirical data supporting this structure is limited. We obtained samples from 11 (12 including a small sample from the Cape Fear River, North Carolina) of these population segments and used PCR and direct sequence analysis of 440 base pairs of the mitochondrial DNA (mtDNA) control region to define the coast-wide genetic population structure of shortnose sturgeon. Collections from most population segments exhibited significant differences in haplotype frequencies with their nearest neighbors, including from the Ogeechee and Savannah Rivers, Georgia (despite the known movement of hatchery-reared offspring from the Savannah into the Ogeechee River). Collections from the Chesapeake Bay and Delaware River exhibited similar haplotype frequencies, suggesting that specimens collected in the Chesapeake Bay had dispersed from the Delaware River. Collections from the Kennebec River and Androscoggin River within a hypothesized single population segment did not exhibit significant differentiation of mtDNA haplotype frequencies. Haplotype frequencies were almost identical between collections from above and below the Holyoke Dam on the Connecticut River, indicating that these aggregations should be managed as a single unit. Our results support the population segment status afforded to shortnose sturgeon in at least the following 9 systems; St. John River, Kennebec-Androscoggin Rivers, upper-lower Connecticut River, Hudson River, Delaware River-Chesapeake Bay, Pee Dee River, Cooper River, Savannah River, and Ogeechee-Altamaha Rivers.     

Analysis of nonintrinsic spatial variability by residual kriging with application to regional groundwater levels

A method for obtaining pointwise or spatially averaged estimates of a nonintrinsic function is introduced based on residual kriging. The method relies on a stepwise iterative regression process for simultaneously estimating the global drift and residual semivariogram. Estimates of the function are then obtained by solving a modified set of simple kriging equations written for the residuals. The modification consists of replacing the true variogram in the kriging equations by the variogram of the residual estimates as obtained from the iterative regression process. The method is illustrated by considering groundwater levels in an Arizona aquifer. The results are compared with those obtained for the aquifer by the generalized covariance package BLUEPACK-3D.     

Determination of Horizontal Aquifer Anisotropy with Three Wells

Existing methods for the determination of horizontal aquifer anisotropy by means of pumping tests require a minimum of four wells, one for water withdrawal and three for drawdown observations. This paper shows how the same methods can be used to determine anisotropy with as few as three wells, if at least two of them can be pumped in sequence. A field example is included. A method of analyzing data from more wells than the above minimum, by least squares, is also described.     

Free surface and saturated-unsaturated analyses of borehole infiltration tests above the water table

Constant head borehole infiltration tests are widely used for the in situ evaluation of saturated hydraulic conductivities of unsaturated soils above the water table. The formulae employed in analysing the results of such tests disregard the fact that some of the infiltrating water may flow under unsaturated conditions. Instead, these formulae are based on various approximations of the classical free surface theory which treats the flow region as if it were fully saturated and enclosed within a distinct envelope, the so-called ‘free surface’. A finite element model capable of solving free surface problems is used to examine the mathematical accuracy of the borehole infiltration formulae. The results show that in the hypothetical case where unsaturated flow does not exist, the approximate formulae are reasonably accurate within·a practical range of borehole conditions. To see what happens under conditions closer to those actually encountered in the field, the effect of unsaturated flow on borehole infiltration is investigated by means of two different numerical models: a mixed explicit-implicit finite element model, and a mixed explicit-implicit integrated finite difference model. Both of these models give nearly identical results; however, the integrated finite difference model is considerably faster than the finite element model. The relatively low computational efficiency of the finite element scheme is attributed to the large number of operations required in order to re-evaluate the conductivity (stiffness) matrix at each iteration in this highly non-linear saturated-unsaturated flow problem. The saturated-unsaturated analysis demonstrates that the classical free surface approach provides a distorted picture of the flow pattern in the soil. Contrary to what one would expect on the basis of this theory, only a finite region of the soil in the immediate vicinity of the borehole is saturated, whereas a significant percentage of the flow takes place under unsaturated conditions. As a consequence of disregarding unsaturated flow, the available formulae may underestimate the saturated hydraulic conductivity of fine grained soils by a factor of two, three, or more. Our saturated-unsaturated analysis leads to an improved design of borehole infiltration tests and a more accurate method for interpreting the results of such tests. The analysis also shows how one can predict the steady state rate of infiltration from data collected during the early transient period of the test.