极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

膨胀土判别与分类的灰关联分析法

基于灰色系统理论，给出一种用于膨胀土判别与分类的新方法—灰关联分析法。实际算例表明，该法具有简单方便、结果客观可靠等优点。     

高岭石与碱剂作用后反应液中硅铝元素变化规律研究

本文系统地研究了高岭石与碱剂间的作用对反应后的液相参数进行全面测定，以查清温度，反应时间，碱性驱替剂的种类浓度等因素与液相参数和固相参数的关系。提出高岭石的非一致性溶蚀趋势，并探讨高岭石与碱性驱替剂的作用机理，丰富了化学驱油过程中化学剂与矿物作用方面的基础理论。     

Influence of gas production induced volumetric strain on permeability of coal

Summary The gas permeability of a coalbed, unlike that of conventional gas reservoirs, is influenced during gas production not only by the simultaneous changes in effective stress and gas slippage, but also by the volumetric strain of the coal matrix that is associated with gas desorption. A technique for conducting laboratory experiments to separate these effects and estimate their individual contribution is presented in this paper. The results show that for a pressure decrease from 6.2 to 0.7 MPa, the total permeability of the coal sample increased by more than 17 times. A factor of 12 is due to the volumetric strain effect, and a factor of 5 due to the gas slippage effect. Changes in permeability and porosity with gas depletion were also estimated using the measured volumetric strain and the matchstick reservoir model geometry for flow of gas in coalbeds. The resulting variations were compared with results obtained experimentally. Furthermore, the results show that when gas pressure is above 1.7 MPa, the effect of volumetric strain due to matrix shrinkage dominates. As gas pressure falls below 1.7 MPa, both the gas slippage and matrix shrinkage effects play important roles in influencing the permeability. Finally, the change in permeability associated with matrix shrinkage was found to be linearly proportional to the volumetric strain. Since volumetric strain is linearly proportional to the amount of gas desorbed, the change in permeability is a linear function of the amount of desorbing gas.     

The Natural Probability Distribution of Load and Unload Response Ratio

In this paper,the Gutenberg-Richter model is used to generate seismic events.The events that satisfy the random distribution are also generated.With those events,the natural probability distribution of Load and Unload Response Ratio(LURR),which measures quantitatively the degree of instability of a nonlinear system,is discussed.The study is based on stress energy release,which is chosen as the response of nonlinear system F3.The comparative results from the observation catalogue and generating data are also studied.It is revealed that the natural probability of LURR is mostly stable when the sample number is sufficient.The lower the natural probability of LURR,the more the precursory is information it may contain.The influence of Y3 resulting from the sample number and the magnitude range of events is also discussed.     

Numerical modeling of 3-D terrain effect on MT field

Using the boundary element method, the numerical modeling problem of three-dimensional terrain effect on magnetotelluric (MT) field is solved. This modeling technique can be run on PC in the case of adopting special net division. The result of modeling test for 2-D terrain by this modeling technique is basically coincident with that by 2-D modeling technique, but there is a great difference between the results of 3-D and 2-D modeling for 3-D terrain. Project supported by the National Natural Science Foundation of China.     

Magnetostratigraphy and palaeoclimate of Red Clay sequences from Chinese Loess Plateau

Two Red Clay profiles near Xi’an and Xifeng were investigated in an attempt to determine magnetostratigraphic and palaeoclimatic records. The results show that aeolian dust accumulation and the related East Asia palaeomonsoon system had begun by 6.5 Ma, and it is deduced that the Tibetan Plateau had reached a significant elevation at that time. The late Tertiary palaeoclimatic history of the Red Clay as reflected by magnetic susceptibility is reconstructed during the period of 6.5–2.5 Ma. Stepwise increase in susceptibility of aeolian dust accumulation appears to have a close correlation to the uplift processes of the Tibetan Plateau. The remarkable increase of aeolian dust accumulation at 3.2 Ma appears to be due to the influence of global ice volume on the East Asia monsoon. Palaeomonsoon variation during the late Tertiary as recorded in the Red Clay sequences from the Chinese Loess Plateau can be regarded as the product of a number of interacting factors, such as uplift of the Tibetan Plateau, solar radiation, global ice volume, etc. Project supported by the National Natural Science Foundation of China and the Foundation of Xi’an Laboratory of Loess and Quaternary Geology, Chinese Academy of Sciences.     

Properties of wave velocity for two types of granitoids at high pressure and temperature and their geological meaning

The wave velocity for two types of granitoids was measured using the analytic method of full-wave vibration at high pressure and high temperature. The laws of velocity changes for them differ with the pressure boost and temperature rise, and the velocity change of S-type is more violent than that of I-type. The “softening point” of compressional wave velocity (V μ) is also revealed during the measurement for two types of granitoids imitating the pressure and temperature at a certain depth. But the depth of “softening”, V_p after “softening” and the percentage of V_p’s drop around the “sofrening point” for two types of granitoids are obviously different. The depth of “softening” is 15 km approximately and V_p after “softening” is 5.62 km/s for S-type granitoid. But for I-type granitoid the depth of “softening” is 26 km approximately and V_p after “softening” is 6. 08 km/s. Through careful analysis of rock slices after the experiment, it was found that the “softening” of elastic-wave velocity is caused by the partial melting of granite. Combined with the results of geophysical prospecting, these results suggest that the low-velocity layers developing in the interior of Earth crust are related to thc partial melting of different types of granitoids. The formation of the low-velocity layer in the upper-middle Earth crust is closely related to the development of S-type granitoid, but that in the lower Earth crust is closely related to the development of I-type granitoid.