Geochemistry of Rare Earth Elements in the Ocean

This work briefly outlines modern ideas on geochemistry of rare earth elements (REE) in the ocean. Sources of REE and chemical properties of these elements, which govern their migration ability in natural processes, are considered. The REE behavior in the river water–seawater mixing zone is analyzed. The fractionation of dissolved and suspended REE in oceanic water in both aerobic and anaerobic conditions is also considered. It is shown that the variability of REE composition in pelagic sediments reflects the fractionation of these elements in the oceanic water as a consequence of material differentiation in the ocean. The REE distribution in terrigenous, authigenic, hydrothermal, and biogenic constituents of sediments, such as clay, bone debris, barite, phillipsite, Fe–Mn oxyhydroxides (ferromanganese nodules and micronodules), Fe–Ca hydroxo-phosphate, diatoms, and foraminifers, is considered.     

Simultaneous Sv and TS measurements on Young-of-the-Year (YOY) freshwater fish using three frequencies

When this article was originally published     

Mapping of sound scattering objects in the northern part of the Barents Sea and their geological interpretation

On cruises 25 (2007) and 28 (2011) of the R/V Akademik Nikolai Strakhov in the northern part of the Barents Sea, the Geological Institute, Russian Academy of Sciences, conducted comprehensive research on the bottom relief and upper part of the sedimentary cover profile under the auspices of the International Polar Year program. One of the instrument components was the SeaBat 8111 shallow-water multibeam echo sounder, which can map the acoustic field similarly to a side scan sonar, which records the response both from the bottom and from the water column. In the operations area, intense sound scattering objects produced by the discharge of deep fluid flows are detected in the water column. The sound scattering objects and pockmarks in the bottom relief are related to anomalies in hydrocarbon gas concentrations in bottom sediments. The sound scattering objects are localized over Triassic sequences outcropping from the bottom. The most intense degassing processes manifest themselves near the contact of the Triassic sequences and Jurassic clay deposits, as well as over deep depressions in a field of Bouguer anomalies related to the basement of the Jurassic–Cretaceous rift system     

Hydrogeochemistry of the Koyna River basin,India

Hydrogeochemistry of the Koyna River basin, famous for the Koyna earthquake (magnitude 7) of 1967, has been studied. Basalt is the primary aquifer; laterites, alluvium, and talus deposits form aquifers of secondary importance. Groundwater generally occurs under water table conditions in shallow aquifers. Deeper aquifers are associated only with basalts. One hundred and 87 water samples were collected from various sources, such as dugwells, borewells, springs, and surface water, including 40 samples for analysis of iron. Only major constituents were analyzed. Analyses show that the concentrations of Ca²⁺ exceed that of Mg²⁺ in almost all water samples; the concentrations of Na⁺ are generally next to Ca²⁺ and are always higher than that of K⁺; and CO₃ ^2– and SO₄ ^2– are very low and are often negligible. Groundwater in borewells tapping deeper aquifers has higher mineralization compared to that in dugwells representing shallow aquifers. Majority of the water samples are dominated by alkaline earths (Ca²⁺, Mg²⁺) and weak acids (HCO₃ ⁻, CO₃ ^2–). Groundwater from shallow aquifers is generally calcium-bicarbonate type (53%) and calcium-magnesium-bicarbonate type (27%). In case of deeper aquifer, it is mostly calcium-magnesium-bicarbonate type (29%), sodium-bicarbonate type (24%), calcium-bicarbonate type (19%), calcium-magnesium-sodium-bicarbonate type (19%) and sodium-calcium-bicarbonate type (9%). Groundwater water is generally fit for drinking and irrigation purposes, except in the lower reaches of the Koyna River basin, which is affected by near water logging conditions.     

Interpretation of210Pb profiles and verification of the CRS dating model in PIRLA project lake sediment cores

This paper reports results and analysis of²¹⁰Pb-activity measurements in 51 lake-sediment cores from 32 lakes in the four PIRLA (Paleoecological Investigations of Recent Lake Acidification) project regions (Adirondack Mountains [New York], Northern New England, Northern Florida, and the Northern Great Lakes States). General application of the Constant Rate of Supply (Constant Flux) model for²¹⁰Pb dating is valid for lakes in the PIRLA study, although application of the model is equivocal in a few lakes.²¹⁰Pb inventories and profiles are replicable among closely spaced cores within a lake. Specific²¹⁰Pb activity in surface sediments is negatively correlated with bulk sediment accumulation rate in seepage lakes, but not in drainage lakes. Drainage lakes with lower pH have lower unsupported²¹⁰Pb inventories in sediments, but the relationship does not occur in seepage lakes.²¹⁰Pb profiles in only seven of the cores, all from either the Adirondacks or the northern Great Lakes states, exhibit exponential decay curves. Deviations from an exponential profile include a flattening of the profile in the top few cm or excursions of one or a few measurements away from an exponential curve.²¹⁰Pb dates typically agree with other chronostratigraphic markers, most of which are subject to greater uncertainty. Several hypotheses, including sediment mixing, hydrologic regime, sediment focusing, and acidification, are proposed to explain variation of²¹⁰Pb distribution among lakes and regions. Hydrologic factors exert control on unsupported²¹⁰Pb inventories in PIRLA lakes, and there is a strong focusing effect in drainage lakes but a weak focusing effect in seepage lakes.This is the third of a series of papers to be published by this journal following the 20^th anniversary of the first application of²¹⁰Pb dating of lake sediments. Dr P. G. Appleby is guest editing this series.     

Tellurides from Sunrise Dam gold deposit, Yilgarn Craton, Western Australia: a new occurrence of nagyágite

Summary The Cu–Fe–Au–Mo (W) deposits in southeastern Hubei are an important component of the Middle–Lower Yangtze River metallogenic belt. Molybdenite from the Fengshandong Cu- (Mo), Ruanjiawan W–Cu- (Mo), Qianjiawan Cu–Au, Tongshankou Cu–Mo and Tonglüshan Cu- (Fe) deposits yielded Re–Os ages of 144.0 ± 2.1 Ma, 143.6 ± 1.7 Ma, 137.7 ± 1.7 Ma, 142.3 ± 1.8–143.7 ± 1.8 Ma and 137.8 ± 1.7–138.1 ± 1.8 Ma, respectively. Phlogopite from the Tieshan Fe- (Cu) deposit yielded an Ar–Ar age of 140.9 ± 1.2 Ma. These data and other published isotopic ages (Re–Os molybdenite and Ar–Ar mica ages) for the Cu–Fe–Au–Mo (W) deposits in the Middle–Lower Yangtze River metallogenic belt show that Cu–Fe–Au–Mo (W) mineralisation in the Tongling, Anqing, Jiurui and Edong ore districts developed in a narrow time span between 135.5 and 144.9 Ma, reflecting an important regional metallogenic event. An integrated study of available petrological and geochronological data, together with relationships to magmatism and the regional geodynamic framework, indicate that the Cu–Fe–Au–Mo (W) mineralisation in the Middle–Lower Yangtze River belt occurred during a regime of lithospheric extension. This extension is probably related to Late Mesozoic processes of lower crustal delamination and lithospheric thinning in East China.     

The identification of distinct patterns in California temperature trends

Regional changes in California surface temperatures over the last 80 years are analyzed using station data from the US Historical Climate Network and the National Weather Service Cooperative Network. Statistical analyses using annual and seasonal temperature data over the last 80 years show distinctly different spatial and temporal patterns in trends of maximum temperature (Tmax) compared to trends of minimum temperature (Tmin). For trends computed between 1918 and 2006, the rate of warming in Tmin is greater than that of Tmax. Trends computed since 1970 show an amplified warming rate compared to trends computed from 1918, and the rate of warming is comparable between Tmin and Tmax. This is especially true in the southern deserts, where warming trends during spring (March?CMay) are exceptionally large. While observations show coherent statewide positive trends in Tmin, trends in Tmax vary on finer spatial and temporal scales. Accompanying the observed statewide warming from 1970 to 2006, regional cooling trends in Tmax are observed during winter and summer. These signatures of regional temperature change suggest that a collection of different forcing mechanisms or feedback processes must be present to produce these responses.     

Application of sodars in the study and monitoring of the environment

Summary Application of acoustic sounders (sodars) to study the atmospheric boundary layer (ABL) began in the early 1970s. During the last two decades the scope of sodars applications enlarged considerably. The proceedings of eleven symposia of the International Society for Remote Acoustic Sensing of the Atmosphere and Oceans (ISARS) are a unique collection of papers, where all directions of the sodar use since 1981 are presented. In this paper, a review of sodar applications to atmospheric research is presented based on materials published in these proceedings in the following fields: conditions of microwave and light propagation; regional climatology of the ABL; air pollution meteorology and weather forecast; mesoscale phenomena under stable and unstable stratification; micrometeorology; peculiarities of the ABL in remote and complex terrain.     

The Askervein hill project: A finite control volume prediction of three-dimensional flows over the hill

A three-dimensional nonlinear numerical model, that has been extensively used previously to predict environmental water flows, was applied to predict the flow over an isolated hill, Askervein. Predictions are reported for winds approaching the hill from 210 ° and 180 ° clockwise from north, both under almost neutral atmospheric conditions.The model predictions were compared with data collected during a major field study in 1983. From the comparisons it was concluded that the model predicts the mean flow variables with good accuracy. Larger discrepancies were found for quantities related to the turbulence, pointing to deficiencies in the turbulence model, and perhaps in some of the measurements.     

Properties of pressure fluctuations in an atmospheric boundary layer

From experimental data it is shown that there is a relationship between measured wind speed and associated micropressure levels. It is also shown that turbulent eddies associated with the wind vanish within distances of five to six times their size, and that these eddies exhibit normal dispersion. These results confirm, at the atmospheric scales, results previously observed only in model experiments.