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211.
212.
We present mid-infrared spectra and images from the Gemini-N (+MICHELLE) observational campaign of Comet 9P/Tempel 1 before, during, and after its encounter with Deep Impact. We use our thermal grain model to probe the 10 μm properties of the dust grains in the coma of the comet. Before impact (3 July 2005 UT), and more than 24 h after impact (5, 16, and 28 July 2005 UT), the comet dust grains were composed mostly of amorphous olivine, and were relatively large (peak of the grain size distribution ). For the night of impact, we extract spectra by centering on the nucleus, and offset 1″ from the nucleus in the direction of the impact ejecta plume. We find small dust grains (∼0.2 μm) of a diverse mineralogy (amorphous olivine, amorphous pyroxene, amorphous carbon, and crystalline olivine) populating the ejecta. The submicron sized dust grains move faster than the other, larger grains (?0.7 μm), with amorphous olivine and amorphous carbon traveling together, and amorphous pyroxene and crystalline olivine dispersing at a similar rate. Deriving a velocity law from a time-of-flight analysis, we find that the material traveled with a velocity law scaled by and with a power of p=0.5. This velocity power-law requires a sustained release of grains for the duration of 45-60 min after impact. Since the mineral species are traveling at different speeds, and there was a sustained release of grains due to a possible “gas-plume,” we conclude that the different minerals did not originate from grain aggregates destroyed by the impact, but instead arise from an inhomogeneous nucleus. 相似文献
213.
Charles A. Geiger Edgar Dachs Gilberto Artioli 《Geochimica et cosmochimica acta》2010,74(18):5202-5215
Armenite, ideal formula BaCa2Al6Si9O30·2H2O, and its dehydrated analog BaCa2Al6Si9O30 and epididymite, ideal formula Na2Be2Si6O15·H2O, and its dehydrated analog Na2Be2Si6O15 were studied by low-temperature relaxation calorimetry between 5 and 300 K to determine the heat capacity, Cp, behavior of their confined H2O. Differential thermal analysis and thermogravimetry measurements, FTIR spectroscopy, electron microprobe analysis and powder Rietveld refinements were undertaken to characterize the phases and the local environment around the H2O molecule.The determined structural formula for armenite is Ba0.88(0.01)Ca1.99(0.02)Na0.04(0.01)Al5.89(0.03)Si9.12(0.02)O30·2H2O and for epididymite Na1.88(0.03)K0.05(0.004)Na0.01(0.004)Be2.02(0.008)Si6.00(0.01)O15·H2O. The infrared (IR) spectra give information on the nature of the H2O molecules in the natural phases via their H2O stretching and bending vibrations, which in the case of epididymite only could be assigned. The powder X-ray diffraction data show that armenite and its dehydrated analog have similar structures, whereas in the case of epididymite there are structural differences between the natural and dehydrated phases. This is also reflected in the lattice IR mode behavior, as observed for the natural phases and the H2O-free phases. The standard entropy at 298 K for armenite is S° = 795.7 ± 6.2 J/mol K and its dehydrated analog is S° = 737.0 ± 6.2 J/mol K. For epididymite S° = 425.7 ± 4.1 J/mol K was obtained and its dehydrated analog has S° = 372.5 ± 5.0 J/mol K. The heat capacity and entropy of dehydration at 298 K are Δ = 3.4 J/mol K and ΔSrxn = 319.1 J/mol K and Δ = −14.3 J/mol K and ΔSrxn = 135.7 J/mol K for armenite and epididymite, respectively. The H2O molecules in both phases appear to be ordered. They are held in place via an ion-dipole interaction between the H2O molecule and a Ca cation in the case of armenite and a Na cation in epididymite and through hydrogen-bonding between the H2O molecule and oxygen atoms of the respective silicate frameworks. Of the three different H2O phases ice, liquid water and steam, the Cp behavior of confined H2O in both armenite and epididymite is most similar to that of ice, but there are differences between the two silicates and from the Cp behavior of ice. Hydrogen-bonding behavior and its relation to the entropy of confined H2O at 298 K is analyzed for various microporous silicates.The entropy of confined H2O at 298 K in various silicates increases approximately linearly with increasing average wavenumber of the OH-stretching vibrations. The interpretation is that decreased hydrogen-bonding strength between a H2O molecule and the silicate framework, as well as weak ion-dipole interactions, results in increased entropy of H2O. This results in increased amplitudes of external H2O vibrations, especially translations of the molecule, and they contribute strongly to the entropy of confined H2O at T < 298 K. 相似文献
214.
The Whippoorwill Formation is a gleyed diamicton that is present locally within bedrock depressions beneath the oldest glacial till in northern Missouri, USA. Stratigraphy, paleomagnetism, and cosmogenic-nuclide burial ages show that it was deposited between the Matuyama-Gauss magnetostratigraphic boundary at 2.58 Ma and the first advance of the Laurentide ice sheet into Missouri at 2.47 ± 0.19 Ma. High cosmogenic-nuclide concentrations also show that the constituents of the Whippoorwill Formation experienced long exposure at a stable landscape surface with erosion rates of 1-2 m/Ma. However, cosmogenic-nuclide concentrations are invariant with depth below the Whippoorwill Formation surface, indicating active mixing of the soil profile shortly before burial by till. The Whippoorwill Formation retains numerous features indicative of cryoturbation. Therefore, we interpret it as a buried Gelisol, a soil formed under periglacial conditions in the presence of permafrost. At the onset of Northern Hemisphere glaciation, climate cooling established permafrost conditions and accelerated erosion by inducing landscape instability. Thus, weathered regolith materials were mobilized and redeposited by gelifluction shortly before the ice sheet overrode the landscape. 相似文献
215.
Kevin R. Chamberlain Axel K. Schmitt Susan M. Swapp T. Mark Harrison Norbert Swoboda-Colberg Wouter Bleeker Tony D. Peterson Charles W. Jefferson Andrei K. Khudoley 《Precambrian Research》2010
An in situ U–Pb SIMS (IN-SIMS) method to date micro-baddeleyite crystals as small as 3 μm is presented with results from three samples that span a variety of ages and geologic settings. The method complements ID-TIMS geochronology by extending the range of dateable crystals to sizes smaller than can be recovered by physical separation. X-ray mapping and BSE imaging are used to locate target grains in thin section, followed by SIMS analysis on a CAMECA ims 1270, using the field aperture in the transfer column to screen out ions from host phases. Internal age precisions for the method are anticipated to range from 0.1% for Precambrian rocks to 3–7% for Phanerozoic rocks. Results establish a 2689 ± 5 Ma age for mafic dikes in the Wyoming craton, USA, a 1540 ± 30 Ma age for a subaerial lava flow from the Thelon Basin of northern Canada, and a 457 ± 34 Ma age for mafic dikes in the platform sequence of southeastern Siberia. The method is ideal for relatively non-destructive dating of small samples such as extraterrestrial rocks and precious terrestrial samples. 相似文献
216.
Evidence for a Long-Term Strength Threshold in Crystalline Rock 总被引:3,自引:1,他引:2
The mechanical response of brittle rock to long-duration compression loading is of particular concern in underground disposal of nuclear waste, where radionuclides must be isolated from the biosphere for periods of the order of a million years. Does the strength decrease without limit over such time, or is there, for some rock types, a lower “threshold” strength below which the rock will cease to deform? This paper examines the possibility of such a threshold in silicate crystalline rocks from several perspectives, including: (1) interpretation of the results of short-term creep tests on rock; (2) numerical analysis of the effect of decrease in fracture toughness due to stress corrosion on the strength of a crystalline rock; and (3) evidence from plate tectonics, and observations of in situ rock stress in granite quarries. The study concludes that there is clear evidence of threshold strength. The threshold is of the order of 40% of the unconfined compressive strength or higher for laboratory specimens under unconfined compressive loading, and increases rapidly in absolute value with confinement. Field evidence also leads to the conclusion that the long-term strength of crystalline rock in situ is of comparable magnitude to the laboratory value. 相似文献
217.
Human arrival in Sahul – Pleistocene Australia and New Guinea – has long been argued as the catalyst in the decline and disappearance of a suite of extinct animals referred to as megafauna. The debate concerning causality in Sahul is highly polarised, with climate change often cited as the alternative explanatory model. On continental Australia, there are few datasets available with which to explore the likely processes leading to the extinction events. At the present time, there is one site in New Guinea (Nombe Rockshelter) and one on continental Australia (Cuddie Springs) where the coexistence and temporal overlap of humans and megafauna has been identified. The Cuddie Springs Pleistocene archaeological site in southeastern Australia contains an association of fossil extinct and extant fauna with an archaeological record through two sequential stratigraphic units dating from c. 36 to c. 30 ka ago. A taphonomic study of the fossil fauna has revealed an accumulation of bone in a primary depositional context, consistent with a waterhole death assemblage. Overall the faunal assemblage studied here (n: 8146; NISP: 1355) has yielded little direct evidence of carnivore damage or human activities. Post depositional factors such as physical destruction incurred by trampling, compaction of sediments, and/or the hydrological status of the lake at that time have played important roles. As the only known site on continental Australia where megafauna and humans co-occur, the Cuddie Springs faunal assemblage yields equivocal evidence for a significant human role in the accumulation of the fauna here. At the present time there is no evidential basis to the argument that humans had a primary role in the extinction of the Australian megafauna. The first colonisers are likely to have preyed upon those few species known to have persisted to this time, but their impact may have been restricted to the tail end of a process that had been underway for millennia prior to human arrival. 相似文献
218.
Michel Faure Alain Cocherie Eugne B Mzme Nicolas Charles Philippe Rossi 《Gondwana Research》2010,18(4):369
In France, the Devonian–Carboniferous Variscan orogeny developed at the expense of continental crust belonging to the northern margin of Gondwana. A Visean–Serpukhovian crustal melting has been recently documented in several massifs. However, in the Montagne Noire of the Variscan French Massif Central, which is the largest area involved in this partial melting episode, the age of migmatization was not clearly settled. Eleven U–Th–Pbtot. ages on monazite and three U–Pb ages on associated zircon are reported from migmatites (La Salvetat, Ourtigas), anatectic granitoids (Laouzas, Montalet) and post-migmatitic granites (Anglès, Vialais, Soulié) from the Montagne Noire Axial Zone are presented here for the first time. Migmatization and emplacement of anatectic granitoids took place around 333–326 Ma (Visean) and late granitoids emplaced around 325–318 Ma (Serpukhovian). Inherited zircons and monazite date the orthogneiss source rock of the Late Visean melts between 560 Ma and 480 Ma. In migmatites and anatectic granites, inherited crystals dominate the zircon populations. The migmatitization is the middle crust expression of a pervasive Visean crustal melting event also represented by the “Tufs anthracifères” volcanism in the northern Massif Central. This crustal melting is widespread in the French Variscan belt, though it is restricted to the upper plate of the collision belt. A mantle input appears as a likely mechanism to release the heat necessary to trigger the melting of the Variscan middle crust at a continental scale. 相似文献
219.
Medium- and Long-term Recovery of Estuarine and Coastal Ecosystems: Patterns,Rates and Restoration Effectiveness 总被引:1,自引:0,他引:1
Ángel Borja Daniel M. Dauer Michael Elliott Charles A. Simenstad 《Estuaries and Coasts》2010,33(6):1249-1260
Many estuarine and coastal marine ecosystems have increasingly experienced degradation caused by multiple stressors. Anthropogenic
pressures alter natural ecosystems and the ecosystems are not considered to have recovered unless secondary succession has
returned the ecosystem to the pre-existing condition or state. However, depending upon the scales of time, space and intensity
of anthropogenic disturbance, return along the historic trajectory of the ecosystem may: (1) follow natural restoration though
secondary succession; (2) be re-directed through ecological restoration, or (3) be unattainable. In order to address the gaps
in knowledge about restoration and recovery of estuarine and coastal ecosystems, this special feature includes the present
overview and other contributions to provide a synthesis of our knowledge about recovery patterns, rates and restoration effectiveness.
From the 51 examples collated in this contribution, we refine the recovery from the list of stressors into six recovery mechanisms:
(1) recovery from sediment modification, which includes all aspects of dredging and disposal; (2) recovery by complete removal
of stressors limiting natural ecosystem processes, which includes tidal marsh and inundation restoration; (3) recovery by
speed of organic degradation, which includes oil discharge, fish farm wastes, sewage disposal, and paper mill waste; (4) recovery
from persistent pollutants, which includes chemical discharges, such as TBT; (5) recovery from excessive biological removal,
related to fisheries and (6) recovery from hydrological and morphological modification. Drawing upon experience both from
these many examples and from an example of one comprehensive study, we show that although in some cases recovery can take
<5 years, especially for the short-lived and high-turnover biological components, full recovery of coastal marine and estuarine
ecosystems from over a century of degradation can take a minimum of 15–25 years for attainment of the original biotic composition
and diversity may lag far beyond that period. 相似文献
220.
Adnand Bitri Jean-Pierre Brun Denis Gapais Florence Cagnard Charles Gumiaux Jean Chantraine Guillaume Martelet Catherine Truffert 《Comptes Rendus Geoscience》2010,342(6):448-452
We present results and interpretation of a 72 km long deep seismic reflection profile acquired across the internal zone of the Hercynian belt of South Brittany. The profile is of excellent quality, most of the crust being highly reflective. The “ARMOR 2 South” profile, is correlated with the “ARMOR 2 North” profile that was published in 2003. Correlation of the main subsurface reflections with surface geological and structural data provides important information about the crustal structure that resulted from thickening during Late Devonian and regional-scale extension during Late Carboniferous. In particular, seismics image shows a very high reflectivity zone, lying flat over more than 40 km at about 10–12 km depth. This zone is interpreted as a major zone of ductile crustal thinning. 相似文献