Daily rainfall projections from general circulation models with a downscaling nonhomogeneous hidden Markov model (NHMM) for south‐eastern Australia

An ensemble of stochastic daily rainfall projections has been generated for 30 stations across south‐eastern Australia using the downscaling nonhomogeneous hidden Markov model, which was driven by atmospheric predictors from four climate models for three IPCC emissions scenarios (A1B, A2, and B1) and for two periods (2046–2065 and 2081–2100). The results indicate that the annual rainfall is projected to decrease for both periods for all scenarios and climate models, with the exception of a few scenarios of no statistically significant changes. However, there is a seasonal difference: two downscaled GCMs consistently project a decline of summer rainfall, and two an increase. In contrast, all four downscaled GCMs show a decrease of winter rainfall. Because winter rainfall accounts for two‐thirds of the annual rainfall and produces the majority of streamflow for this region, this decrease in winter rainfall would cause additional water availability concerns in the southern Murray–Darling basin, given that water shortage is already a critical problem in the region. In addition, the annual maximum daily rainfall is projected to intensify in the future, particularly by the end of the 21st century; the maximum length of consecutive dry days is projected to increase, and correspondingly, the maximum length of consecutive wet days is projected to decrease. These changes in daily sequencing, combined with fewer events of reduced amount, could lead to drier catchment soil profiles and further reduce runoff potential and, hence, also have streamflow and water availability implications. Copyright © 2012 John Wiley & Sons, Ltd.     

Jari: A pulp plantation in the Brazilian Amazon

Jari plantation is the largest pulp growing operation in the humid tropics, and occupies about 1000 sqkm previously covered by tropical forest. A study of five sites at Jari in 1980 indicated declining soil fertility, and low productivity of pulpwood. Low pulp production at Jari was caused by several factors, one of which appeared to be low soil fertility. The sams sites were re-evaluated in 1987. There was no discernable trend in either nutrients or productivity since 1980.Although productivity and nutrient stocks may have stabilized, low profitability caused by low pulp production resulted in the sale of Jari in 1982, for a $ 720 million loss. Despite growth rates at Jari which were too low to produce a profit on original investment, another plantation is planned for the eastern Amazon which is 10 times the size of Jari.     

Phase equilibrium and calorimetric study of the transition of MnTiO3 from the ilmenite to the lithium niobate structure and implications for the stability field of perovskite

The phase boundary between MnTiO₃ I (ilmenite structure) and MnTiO₃ II (lithium niobate structure) has been determined by analysis of quench products from reversal experiments in a cubic anvil apparatus at 1073–1673 K and 43–75 kbar using mixtures of MnTiO₃ I and II as starting materials. Tight brackets of the boundary give P(kbar)=121.2−0.045 T(K). Thermodynamic analysis of this boundary gives ΔH^o=5300±1000 J·mol⁻¹, ΔS^o = 1.98 ±1J·K⁻¹· mol⁻¹. The enthalpy of transformation obtained directly by transposed-temperature-drop calorimetry is 8359 ±2575 J·mol⁻¹. Possible topologies of the phase relations among the ilmenite, lithium niobate, and perovskite polymorphs are constrained using the above data and the observed (reversible with hysteresis) transformation of II to III at 298 K and 20–30 kbar (Ross et al. 1989). The observed II–III transition is likely to lie on a metastable extension of the II–III boundary into the ilmenite field. However the reversed I–II boundary, with its negative dP/ dT does represent stable equilibrium between ilmenite and lithium niobate, as opposed to the lithium niobate being a quench product of perovskite. We suggest a topology in which the perovskite occurs stably at low T and high P with a triple point (I, II, III) at or below 1073 K near 70 kbar. The I–II boundary would have a negative P-T slope while the II–III and I–III boundaries would be positive, implying that entropy decreases in the order lithium niobate, ilmenite, perovskite. The inferred positive slope of the ilmenite-perovskite transition in MnTiO₃ is different from the negative slopes in silicates and germanates. These thermochemical parameters are discussed in terms of crystal structure and lattice vibrations.