The chemistry of geothermal waters in Iceland. III. Chemical geothermometry in geothermal investigations

New data from geothermal wells in Iceland have permitted empirical calibration of the chalcedony and $\text{Na}\text{K}$ geothermometers in the range of 25–180°C and 25–250°C respectively. The temperature functions are:

$\text{t°C=}\text{1112}\text{4.91?}\text{log SiO}{}_2\text{?273.15}$

$\text{t°C=}\text{933}\text{0.993+}\text{log Na/K}\text{?273.15}$

Concentrations are expressed in ppm. These temperature functions correspond well with the chalcedony solubility data of Fournier (1973) and the thermodynamic data for low-albite/microcline/solution equilibria of Heloeson (1969).A new CO₂ geothermometer is proposed which is considered to be useful in estimating underground temperatures in fumarolic geothermal fields. Its application involves analysis of CO₂ concentrations in the fumarole steam. The temperature function which applies in the range 180?300°C is: logCO₂ = 37.43 + 73192/T- 11829· 10₃/T² + 0.18923T- 86.187·logT where T is in °K and CO₂ in moles per kg of steam.     

Neotectonics of the Pontides: implications for ‘incompatible’ structures along the North Anatolian fault

Data for the post-Serravallian, ‘neotectonic’ evolution of the Pontides in northern Turkey indicate predominant ENE-WSW shortening with complementary NNW-SSE extension. We present a new fault plane solution for the Bartin earthquake (3 September 1968) and compare its mechanism with the movement picture of other neotectonic faults in the Pontides and northern Greece together with that of the Thessaloniki earthquake (20 May 1978). The general strain pattern exhibited by these structures agrees remarkably well with that inferred from early Tortonian-early Pleistocene structures reported from within the North Anatolian fault zone, which have been interpreted as indicating a possible reversal of the sense of movement along the North Anatolian transform fault. Here, we argue that such ‘incompatible’ structures may be related to the overall E-W shortening of Anatolia and the southern parts of the Black Sea resulting from the sideways continental escape from around the African and the Arabian promontories, rather than to hypothetical reversal of motion along the North Anatolian fault, for which there is no evidence other than the above-mentioned ‘incompatible’ structures. This new model also has important implications for seismicity and earthquake risk in regions contained within the southern part of the Black Sea plate.     

Meridional Motions of Stable Recurrent Sunspot Groups

Stable recurrent sunspot groups from the Greenwich data set which were identified in at least two subsequent solar rotations were traced and meridional motions were determined from the two central meridian passages. In total, 327 meridional velocities were calculated and the results for the northern and the southern solar hemisphere were compared. A dependence of the solar meridional velocity vectors on the development status, latitude and position respectively to the activity belt of sunspots is investigated. The results indicate that sunspot groups are moving on the average away from the center of activity. This was found for sunspot groups growing and decreasing in area.     

Global high resolution versus Limited Area Model climate change projections over Europe: quantifying confidence level from PRUDENCE results

Four high resolution atmospheric general circulation models (GCMs) have been integrated with the standard forcings of the PRUDENCE experiment: IPCC-SRES A2 radiative forcing and Hadley Centre sea surface temperature and sea-ice extent. The response over Europe, calculated as the difference between the 2071–2100 and the 1961–1990 means is compared with the same diagnostic obtained with nine Regional Climate Models (RCM) all driven by the Hadley Centre atmospheric GCM. The seasonal mean response for 2m temperature and precipitation is investigated. For temperature, GCMs and RCMs behave similarly, except that GCMs exhibit a larger spread. However, during summer, the spread of the RCMs—in particular in terms of precipitation—is larger than that of the GCMs. This indicates that the European summer climate is strongly controlled by parameterized physics and/or high-resolution processes. The temperature response is larger than the systematic error. The situation is different for precipitation. The model bias is twice as large as the climate response. The confidence in PRUDENCE results comes from the fact that the models have a similar response to the IPCC-SRES A2 forcing, whereas their systematic errors are more spread. In addition, GCM precipitation response is slightly but significantly different from that of the RCMs.     

Effect of rod friction on vane shear tests in very soft organic harbour mud

Very soft organic harbour mud is increasingly used as a filling and construction material in harbour construction and reorganization. The undrained shear strength of such soft sediments is the critical geotechnical soil parameter with regard to any specific construction design. Field and laboratory vane shear testing is a standard method to quickly determine this important parameter. So far, the effect of rod friction on vane shear tests in very soft organic soils is unclear. In this study we present results from laboratory experiments on harbour mud from a construction site in northern Germany. Relations among vane and rod geometry, penetration depth, water content, rod friction and undrained shear strength are derived. Based on these relations the influence of rod friction on vane shear test results is investigated. The results indicate that field and laboratory vane shear test measurements may be significantly influenced by rod friction. Methods are proposed to correct for the rod influence, which is shown to increase with rising water contents.     

Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

A numerically calibrated reference level (MP28) for the terrestrial mammal-based biozonation of the European Upper Oligocene

The fauna of the Enspel (Westerwald) and the neighbouring Kärlich (Neuwied basin) fossil deposits correspond to the Upper Oligocene Mammal Paleogene (MP) reference level 28 and 28–30, respectively. Basaltic flows and a trachyte tuff terminating and predating the fossil deposit sedimentation allow to numerically calibrate the MP reference levels by radioisotope dating. Laser fusion ⁴⁰Ar/³⁹Ar step heating on volcanic feldspars yield a time interval of 24.9–24.5 Ma for reference level MP28 at Enspel and a maximum age of 25.5 Ma for the time interval MP28–MP30 at Kärlich. Interpolation between the time intervals determined for the Enspel reference level MP28 and the age of the global Oligocene/Miocene boundary of 24.0 ± 0.1 Ma taken from literature results in time intervals of 24.5–24.2 Ma and 24.2–23.9 Ma for the younger reference levels MP29 and MP30, respectively. These intervals of ≤ 0.4 m.y. for MP reference levels of the latest Oligocene are short relative to older Oligocene MP reference levels 21–27 between 34 and 25 Ma. Since subdivision into MP reference levels essentially is based on assemblages of mammal taxa and on evolutionary changes in tooth morphology of mammals short MP time intervals during the latest Oligocene indicate a rapid evolutionary change relative to the early Oligocene.