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51.
    
Medium-term prediction of sediment transport and morphological behaviour in the coastal zone is becoming increasingly important as a result of human interference and changing environmental conditions. The interaction of waves and tides is shown to play a pivotal role in the net (annual) sediment transport and morphodynamics of the coastal zone. The Telemac Modelling System has been applied to the Dyfi Estuary and neighbouring coastline, mid Wales, to recreate the annual wave–current conditions and the resulting sediment fluxes. ‘Input reduction’ methods have been required to produce realistic schematisations of events in practical computation times. A field campaign carried out in 2006 provided data for validation of the flow module (Telemac-2D) and also observations to verify the patterns predicted by the wave module (Tomawac). To improve model accuracy refinements were implemented with regard to the sand transport formulation used in the sand transport module (Sisyphe). Here, a parameterisation of the results from the UWB 1DV sand transport ‘research’ model, for the conditions in the Dyfi Estuary, has been introduced, allowing Sisyphe to provide greater realism in the morphological predictions. The model predictions are presented along with a discussion of the success/failure and limitations of the modelling methods applied.  相似文献   
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Variations in the location and strength of convection in the Western Pacific Warm Pool (WPWP) have a profound impact on the distribution and amount of global rainfall. Much of the variability in WPWP convection is attributed to variations in the El Ni?o-Southern Oscillation, for which the long-term trends and forcing mechanisms remain poorly understood. Despite the importance of WPWP convection to global climate change, we have very few paleohydrological reconstructions from the region. Here we present a new paleolimnologic and paleohydrologic record spanning the past 1,400 years using a multi-proxy dataset from Lake Logung, located in East Java, Indonesia that provides insights into centennial-scale trends in warm pool hydrology. Organic matter δ13C data indicate that East Java became wetter over the last millennium until ca. 1800 Common Era (CE), consistent with evidence for the southward migration of the Intertropical Convergence Zone (ITCZ) during this time. Superimposed on this long-term trend are four decade- to century-scale droughts, inferred from organic matter δ13C and calcite abundance data. They are centered at 1030, 1550, 1830, and 1996 CE. The three more recent droughts correlate with hydrologic anomalies documented in other proxy records from the WPWP region on both sides of the equator, and the two most recent droughts correlate in time with historically documented periods of multiple, intense El Ni?o events. Thus, our record provides strong evidence that century-scale hydrologic variability in this region relates to changes in the Walker Circulation. Human activity within the lake catchment is apparent since 1860 CE.  相似文献   
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This paper describes a multi‐proxy palaeoecological investigation undertaken in conjunction with an archaeological survey of the Upper Sangro Valley in the Abruzzo National Park, Central Italy. Despite being a biodiversity hotspot and regarded as a near‐pristine area, the pollen, spore and diatom data all show major changes in the vegetation extending to over 2000 m a.s.l. during the mid to late Holocene. Although there are changes in ecological composition earlier in the Holocene they are different in type and magnitude from the changes which began about 800 cal a BC. The pollen and diatom evidence do not correlate well with regional palaeoclimate data, or on‐site isotopic evidence, but do appear to be related to Samnite (later Iron Age) clearance and upland grazing associated with transhumance and later annexation (and centuriation) of the lower slopes by Roman surveyors. The greatest change in vegetation was during the period c. AD 500–600 and corresponds with the Byzantine–Gothic Wars, and Lombard–Carolingian settlement reorganization into nucleated hilltop settlements which managed upland grazing. This pattern of intensive land use at all altitudes persisted until the early 20th century and only changed following rural depopulation after World War II. These data illustrate how cultural factors had a profound effect on this mountainous region which, in this case, far outweighed the effects of climatic fluctuations which are known to have occurred from both this study area and the region. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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Spatial and seasonal variations of the oxidation of Fe(II) and As(III) have been previously documented in the Carnoulès (Gard, France) Acid Mine Drainage (AMD) by bulk analyses. These variations may be correlated with the variations in the activity of indigenous As(III)- and Fe(II)-oxidizing bacteria living in the As-rich Carnoulès water. The activity of these bacteria indeed plays an important role in the nature and composition of the solid phases that sequester arsenic at this site. In order to better understand the interactions of microbes with Fe and As in the Carnoulès AMD, we combined Transmission Electron Microscopy (TEM) and Scanning Transmission X-ray Microscopy (STXM) to collect near-edge X-ray absorption fine structure (NEXAFS) spectra at high spatial and energy resolution and to perform high spatial resolution imaging at the 30-50 nm scale. Spectromicroscopy was performed at the C K-edge, Fe L2,3-edge, and As L2,3-edge, which allowed us to locate living and/or mineralized bacterial cells and to characterize Fe and As oxidation states in the vicinity of those cells. TEM was used to image the same areas, providing higher resolution images and complementary crystallographic and compositional information through electron diffraction and EDXS analysis. This approach provides unique information on heterogeneous geochemical processes that occur in a complex microbial community in an AMD environment at the micrometer and submicrometer-scale. Bacterial cells in the Carnoulès AMD were frequently associated with mineral precipitates, and a variety of biomineralization patterns were observed. While many mineral precipitates were not associated with bacterial cells, they were associated with pervasive organic carbon. Finally, abundant biomineralized organic vesicles were observed in the Carnoulès AMD. Such vesicles may have been overlooked in highly mineralized extreme environments in the past and may represent an important component in a common biomineralization process in such environments.  相似文献   
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Metamorphic temperatures of 330°–400° C are inferred for rocks from the Shuksan blueschist terrane in the North Cascades, Washington. The temperatures are calculated from 18O fractionations between coexisting quartz and magnetite using the equations of Bottinga and Javoy (1973). Pressures of approximately 7 kilobars are indicated by the Jadeite content of clinopyroxene coexisting with quartz+albite. Published experimental and theoretical studies of the stability of lawsonite and pumpellyite are consistent with the oxygen isotope temperatures and occurrence of these minerals in the Shuksan Suite.  相似文献   
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A series of kerogens and kerogen precursors isolated from DSDP samples, oil shales and Recent algal mats have been examined by Curie point pyrolysis-high resolution gas chromatography and gas chromatography-mass spectrometry. This study has shown that the three main types of kerogens (marine, terrestrial and mixtures of both) can be characterized using these techniques. The marine (algal) kerogens yield principally aliphatic products and the terrestrial kerogens yield more aromatic and phenolic products with some n-alkanes and n-alkenes. The yields of n-alkanes and n-alkenes increase and phenols decrease with increasing geologic age, however, pyrolysis-GC cannot be used to characterize the influence of short term diagenesis on the kerogen structure.  相似文献   
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The short-term (5 day) accumulation of Cu and Zn in different tissues of the marine gastropod, Littorina littorea, has been studied in the presence of 10 mg l−1 of antifouling paint particles and pre- or simultaneously contaminated algal food (Ulva lactuca). Accumulation of Cu was observed in the head–foot, digestive gland–gonad complex and gills to extents dependent on how and when food was contaminated and administered. However, retention of Zn was only observed in the gills and only when L. littorea and U. lactuca were simultaneously exposed to paint particles. Relative to the alga, faecal material was highly enriched in Zn, suggesting that the animal is able to rapidly eliminate this metal, most likely through the formation and egestion of insoluble phosphate granules. Thus, L. littorea is a useful biomonitor of marine contamination by antifouling applications in respect of Cu but not Zn.  相似文献   
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