Density constraints on the formation of the continental Moho and crust

The densities of mantle magmas such as MORB-like tholeiites, picrites, and komatiites at 10 kilobars are greater than densities for diorites, quartz diorites, granodiorites, and granites which dominate the continental crust. Because of these density relations primary magmas from the mantle will tend to underplate the base of the continental crust. Magmas ranging in composition from tholeiites which are more evolved than MORB to andesite can have densities which are less than rocks of the continental crust at 10 kilobars, particularly if they have high water contents. The continental crust can thus be a density filter through which only evolved magmas containing H₂O may pass. This explains why primary magmas from the mantle such as the picrites are so rare. Both the over-accretion (i.e., Moho penetration) and the under-accretion (i.e., Moho underplating) of magmas can readily explain complexities in the lithological characteristics of the continental Moho and lower crust. Underplating of the continental crust by dense magmas may perturb the geotherm to values which are characteristic of those in granulite to greenschist facies metamorphic sequences in orogenic belts. An Archean continental crust floating on top of a magma flood or ocean of tholeiite to komatiite could have undergone a major cleansing process; dense blocks of peridotite, greenstone, and high density sediments such as iron formation could have been returned to the mantle, granites sweated to high crustal levels, and a high grade felsic basement residue established.     

A gender analysis of quality of life in Saskatoon, Saskatchewan

While many community initiatives have attempted to assess the nature and determinants of their citizens’ quality of life (QOL), these initiatives have produced little about whether the key determinants of life quality differ by gender. Using both quantitative and qualitative data from a recent QOL research project in Saskatoon, Saskatchewan, Canada, this study explores whether factors that predict poor QOL are similar for women and men. The study also examines whether the nature of these gender differences varies across low, medium and high socio-economic status locales. Results showed that men and women were very similar in: (1) their QOL ratings, (2) reports of deterioration in neighborhood QOL, and (3) rating particular aspects of their neighborhood. Few gender differences were also found when analyzing data referring to place characteristics and social cohesion. Multivariate analysis revealed further similarities: (1) being divorced/widowed was a significant predictor of poor QOL, and (2) a negative view of community security issues was associated with deterioration in perceived neighborhood quality of life. For women, however, other variables were important predictors of QOL: being middle aged, being single, and having a poor opinion of the overall quality of their neighborhood. Qualitative analysis revealed that while men and women shared concern about general areas such as safety and neighborhood supports, their perceptions of the details around these issues differed. The multi-method results suggest that urban policy actions should include a gendered discussion of common QOL issues.     

Finding the repeat times of the GPS constellation

Single-epoch estimates of position using GPS are improved by removing multipath signals, which repeat when the GPS constellation does. We present two programs for finding this repeat time, one using the orbital period and the other the topocentric positions of the satellites. Both methods show that the repeat time is variable across the constellation, at the few-second level for most satellites, but with a few showing much different values. The repeat time for topocentric positions, which we term the aspect repeat time, averages 247 s less than a day, with fluctuations through the day that may be as much as 2.5 s at high latitudes.     

A LA-ICP-MS Comparison of Reference Materials Used in Cassiterite U-Pb Geochronology

Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is used to compare the suitability of four cassiterite (SnO₂) materials (SPG, Yankee, AY-4 and Jian-1), and three matrix-mismatched reference materials (NIST SRM 612, NIST SRM 614 and 91500 zircon) for normalisation of U-Pb and Pb-Pb isotope ratios in cassiterite. The excess variance of ages determined by LA-ICP-MS is estimated to be ±0.33% for ²⁰⁷Pb/²⁰⁶Pb vs. ²⁰⁸Pb/²⁰⁶Pb isochron ages and ± 1.8% and for U-Pb ages. Incorporation of this excess variance in cassiterite ages is necessary for realistic uncertainties. ²⁰⁷Pb-²⁰⁶Pb ages are advantageous for dating Precambrian cassiterite such as SPG compared with U-Pb ages as matrix effect on instrumental mass fractionation of Pb isotopes are generally considered to be minor. We note minor bias in ²⁰⁷Pb/²⁰⁶Pb vs. ²⁰⁸Pb/²⁰⁶Pb isochron ages (~ 0.6%) when using either the NIST SRM 614 or 91500 zircon reference materials and emphasise the requirement for uncertainty propagation of all sources of error and reference materials with comparable U and Pb mass fraction to the cassiterite. The ²³⁸U/²⁰⁶Pb isotopic ratios from normalisation to matrix-mismatched reference materials show varied results, which emphasises the need to use matrix-matched reference materials for calculating U-Pb ages. When cross-calibrated against each other, LA-ICP-MS U-Pb ages of the ca. 1535 Ma SPG, ca. 245 Ma Yankee and ca. 155 Ma Jian-1 cassiterites are all consistent with their ID-TIMS values.     

Geochronological constraints on metamorphism, magmatism and exhumation of deep-crustal rocks of the Kramanituar Complex, with implications for the Paleoproterozoic evolution of the Archean western Churchill Province, Canada

U-Pb and Sm-Nd geochronology establishes an important Paleoproterozoic (~1.9 Ga) history for the Kramanituar Complex, located in the interior of the Archean western Churchill Province, and provides further insight into the Snowbird tectonic zone, a crustal-scale (>2000 km) feature whose role during Precambrian time remains controversial. The Kramanituar Complex is a window of deep-crustal rocks, dominated by a granulite-facies metagabbroic suite of ~1902 Ma age, with minor supracrustal rocks and charnockite. These yield peak equilibrium conditions of 12-15 kbar and 850-900 °C, which are bracketed between ~1910 Ma, the age of prograde metamorphic monazite in sillimanite- and kyanite-bearing paragneiss, and 1901 Ma, the cooling ages of titanite and rutile in gabbroic and paragneissic rocks. Although mineral assemblages reflecting peak metamorphic conditions are widespread, some rocks record near-isothermal decompression to ~8 kbar and 800 °C. The timing of uplift and exhumation is tightly bracketed between magmatic crystallization of gabbroic anorthosite under granulite-facies conditions at 1902 Ma and widespread rutile cooling ages of 1901 Ma. Time-averaged cooling rates of >100 °C/Ma are estimated for gabbroic anorthosite and leucogranite. Rocks surrounding the Kramanituar Complex are mainly amphibolite-facies Archean plutonic and supracrustal rocks. Those to the north were at deep-crustal conditions coeval with the complex, whereas those to the south appear to preserve a record of older, mainly Neoarchean tectonometamorphic assemblages and fabrics. The southern boundary of the complex is inferred to be a normal fault that accommodated tectonic unroofing of the Kramanituar Complex at ~1.9 Ga. This geochronological data set highlights the protracted history of a segment of the geophysically defined Snowbird tectonic zone, a structure along which latest significant magmatism and tectonometamorphism has been interpreted as either ~2600 or ~1800 Ma. Penetrative ~1900 Ma activity in the east-trending Chesterfield segment, as documented at the Kramanituar Complex, suggests that the complex may have represented a favorably oriented segment of a crustal-scale Archean fault that was reactivated during Paleoproterozoic time, possibly in response to collision between the Slave and Churchill cratons (Thelon Orogen) at ~1.97-1.9 Ga.     

Compositional differences in enstatite chondrites based on carbon and nitrogen stable isotope measurements

Carbon and nitrogen abundance and isotopic compositions, from four EH4, one EH5, five EL6 chondrites and one aubrite, were determined by using stepped pyrolysis (N only) and combustion (N and C) extractions in attempts to distinguish the components present. Carbon contents range from 0.15 to 0.70 wt%, with no systematic relationship between carbon content and meteorite group or petrologic type. Whole-rock δ¹³C values range from −28.5 to −4.1 %., Most C occurs as graphite and when temperature steps above 700°C are considered, there is a difference between EH4,5 (δ¹³C = −9.1 to -5.8%.) and EL6 chondrites (δ¹³C = −6.7 to +4.2%.). Carbon in Bustee aubrite is isotopically lighter (δ¹³C = −24%.) than in any enstatite chondrite.

Nitrogen occurs as osbornite, sinoite and in isostructural substitution for oxygen in silicate lattice sites. Nitrogen abundances and isotopic compositions are more variable than C, due to the heterogenous distribution of N-bearing minerals. Three EL6's containing osbornite have higher N concentrations than other type 6 enstatite chondrites. Sinoite, where present, is depleted in ¹⁵N relative to osbornite. Nitrogen in the Bustee aubrite has a similar abundance and δ¹⁵N value to those of EL6's, again dominated by the presence of osbornite.

In addition to the refractory C-and N-bearing minerals there is also organic material (largely terrestrial contamination) and evidence for at least two “exotic” components. The first is a host for Xe (HL) and is characterized by δ¹³C <-−47%. and δ¹⁵N ≤−73%., whereas the second is less well-defined, but is marked by δ¹⁵N = +269%.