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111.
Matthew B.J. Lindsay Peter D. Condon John L. Jambor Kerry G. Lear David W. Blowes Carol J. Ptacek 《Applied Geochemistry》2009
Mineralogical, geochemical and microbial characterization of tailings solids from the Greens Creek Mine, Juneau, Alaska, was performed to evaluate mechanisms controlling aqueous geochemistry of near-neutral pH pore water and drainage. Core samples of the tailings were collected from five boreholes ranging from 7 to 26 m in depth. The majority of the 51 samples (77%) were collected from the vadose zone, which can extend >18 m below the tailings surface. Mineralogical investigation indicates that the occurrence of sulfide minerals follows the general order: pyrite [FeS2] >> sphalerite [(Zn,Fe)S] > galena [PbS], tetrahedrite [(Fe,Zn,Cu,Ag)12Sb4S13] > arsenopyrite [FeAsS] and chalcopyrite [CuFeS2]. Pyrite constitutes <20 to >35 wt.% of the tailings mineral assemblage, whereas dolomite [CaMg(CO3)2] and calcite [CaCO3] are present at ?30 and 3 wt.%, respectively. The solid-phase geochemistry generally reflects the mineral assemblage. The presence of additional trace elements, including Cd, Cr, Co, Mo, Ni, Se and Tl, is attributed to substitution into sulfide phases. Results of acid–base accounting (ABA) underestimated both acid-generating potential (AP) and neutralization potential (NP). Recalculation of AP and NP based on solid-phase geochemistry and quantitative mineralogy yielded more representative results. Neutrophilic S-oxidizing bacteria (nSOB) and SO4-reducing bacteria (SRB) are present with populations up to 107 and 105 cells g−1, respectively. Acidophilic S-oxidizing bacteria (aSOB) and iron-reducing bacteria (IRB) were generally less abundant. Primary influences on aqueous geochemistry are sulfide oxidation and carbonate dissolution at the tailings surface, gypsum precipitation–dissolution reactions, as well as Fe reduction below the zone of sulfide oxidation. Pore-water pH values generally ranged from 6.5 to 7.5 near the tailings surface, and from approximately 7–8 below the oxidation zone. Elevated concentrations of dissolved SO4, S2O3, Fe, Zn, As, Sb and Tl persisted under these conditions. 相似文献
112.
This study reports the result of deep ocean-bottom seismometer recording of an undersea volcanic event in progress. An array of five three-component, isolated sensor ocean-bottom seismometers (ISOBS) was deployed for 28 days on the summit and flanks of Loihi Seamount, Hawaii, to monitor seismicity. The deployment was prompted by reports from the Hawaiian Volcano Observatory (HVO) of a swarm of small-magnitude events located beneath the active submarine volcano in late September, 1986. Monitoring of this earthquake swarm by the University of Hawaii commenced 1 October 1986. Although seismicity tapered off rapidly after 11 October, more than 200 events were located. Systematic changes in spatial clustering during the initial swarm activity suggest changing patterns of stress within this crustal volume, possibly due to induced stress resulting from magma movement in the underlying crust or deep portions of the edifice.Most of the very shallow (< 10 km) events were located beneath the summit and southwest flank of the elongate edifice. No shallow tremor was observed despite a search through the data, although such tremor may have ceased prior to deployment of the ocean-bottom seismometers (OBS). Constraints on the association between seismicity and observed topographic and tectonic elements of Loihi are also of primary importance. Many of the earthquakes located near the steep flanks generated rock falls that were recorded on the OBSs. This is consistent with the results of dredge and bottom photography data indicating that the flanks are covered with fragments of shattered lava pillows and flows. Dike intrusion and mass wasting are major influences on the morphology of Loihi. Intact flows have been observed near the deep portion of the south rift zone; however, few events were located in that region during this swarm. 相似文献
113.
The Pacific island nation-state of Tuvalu featured significantly at the Copenhagen Conference of Parties (COP) 15 climate change negotiations, where the vulnerability of Tuvalu to sea level rise and emotional outpourings of the Tuvaluan delegation contributed to the nation's prominence. In this paper we discuss the likely impacts for Tuvalu of a 1.5°C versus 2°C global warming target and explore sadness and discomfort surrounding discussion of these targets during COP 15. We highlight tensions between science and emotion, arguing that affective encounters can be significant in climate change decision-making. Weeping by a member of the Tuvalu delegation evoked discomfort in the conference plenary. This discomfort briefly unsettled the apparently stable boundaries of convention and protocol that seek to separate emotion from science and politics. We argue that possibilities for change arise when emotions enter climate change negotiations, even though (or perhaps because) these are arenas that privilege rational exchange. Our conclusion urges that more attention be paid to how climate science and emotion are intertwined in climate change politics. 相似文献
114.
Eleonora S. Carol Eduardo E. Kruse Jorge L. Pousa Alejandro R. Roig 《Hydrogeology Journal》2009,17(7):1727-1732
A well-known analytical solution of Jacob (1950) for groundwater flow due to tidal-wave propagation, together with field measurements along a complete tidal cycle and geological data, were used to evaluate the heterogeneities in the hydraulic properties of a phreatic aquifer located next to the River Ajo in the coastal plain environment of the southern sector of the Samborombon Bay wetland, Argentina. From the analysis of water-table fluctuations in a set of monitoring wells located along a riverbank-normal transect, it was possible to quantify the piecewise spatial variations of the hydraulic diffusivity of the phreatic aquifer. The results show the strong lateral variations of the sedimentary environment due to the influence of the different transport and deposition agents that characterize the coastal plain. The known thickness of the phreatic aquifer and the estimated range of the specific yield allowed the hydraulic conductivity to be identified as the most influential factor. [Jacob CE (1950) Flow of ground water. In: Rouse H (ed) Engineering Hydraulics. Wiley, New York] 相似文献
115.
This paper presents the results of a physical model study of the performance of landfill clay cover liners subjected to extended freezing periods. Three proposed designs for a prototype cover liner were evaluated with a primary objective being the determination of frost penetration resulting from the sub-freezing temperatures imposed as an upper boundary condition to the model. The ultimate performance of the three liner designs were compared on the basis of frost penetration, leakage through the liner, and frost heave. The observed depth of frost penetration was compared to that predicted using a simplified analytical solution of the thermodynamic problem, in addition to measured field behavior.
The laboratory experiment utilizes a 1.8 m2 tank, of ca 2.1 m depth. The tank is loaded with clay to the specifications required for landfill liners. Three different landfill cover liner designs were modeled in the experimental tank. The performance of the three designs, as measured by a variety of observations, were compared. Frost heave was measured for each design and was found to vary between 3.8 and 4.3 cm. The results indicate the depth of frost penetration was similar for all designs tested (29.2–31.7 cm), although the design which included a soil drainage layer had superior leakage performance. 相似文献
116.
Nine rock samples from three Jurassic stratigraphic units of a shallow core from NW Germany were analyzed by pyrolysis-gas chromatography. The units contain a mixed Type-II/III kerogen (Dogger-α), a hydrogen-rich Type-II kerogen (Lias-), and a hydrogen-poor Type-III kerogen (Lias-δ). All of the kerogen was immature (Ro = 0.5%). Two sets of kerogen concentrates (“AD”: HCl/HF followed by a density separation, and “A”: only acid treatment) prepared from the rock samples were also analyzed to make a detailed comparison of the pyrolysates of rock and corresponding kerogen-concentrates.Hydrogen-index (HI) values of the kerogen concentrates prepared from organic-carbon poor rock were nearly 200% higher than HI values of the rock samples. Changes in HI were minimal for the samples containing Type-II kerogen. The A and AD samples from the Corg-poor rock yielded pyrolysates with n-alkane series of very different molecular lengths. Pyrograms of the rock samples had n-alkane series extending to n-C14; the chromatograms of the A samples reached the n-C14-nC20 range. The AD samples from Corg-poor rock and all three sample types from the Corg-rich rock had n-alkane series up to n-C29. The benzene/hexane and toluene/heptane ratios for the Corg-poor rock and A samples were far higher than for the AD samples, which had ratios similar to those of all three sample types from the Corg-rich rocks. These results indicate that choice of kerogen preparation method is critical when Corg-poor samples are analyzed. 相似文献
117.
There is a growing scholarship on the role of the amateur, and amateur societies, in the production and circulation of weather and climate knowledge in the past. Yet relatively little attention has been paid to the actual and potential contribution of contemporary amateur meteorologists in this respect. In this paper we first examine the importance of the amateur historically in the production of local weather knowledge and also in the emergence of professional meteorology. Drawing on semi-structured interviews with members of one contemporary UK based amateur meteorological organisation??the Climatological Observers Link (COL)??we then investigate the nature and extent of contemporary amateur meteorologists?? contributions to a wide range of different ??publics?? today, which include both popular and professional communities. Finally, we interrogate our interview data to identify whether COL members themselves recognise a wider role for their expertise at a time of increasing popular and scientific interest in weather and climate and in an era when the inclusion of non-certified experts in policy decision making processes is being advocated. 相似文献
118.
Carol Molinivelsko Toshiko K. Mayeda Robert N. Clayton 《Geochimica et cosmochimica acta》1986,50(12):2719-2726
Samples of bulk meteorites show only mass-dependent fractionation of silicon isotopes. No isotopic anomalies were found. The variation of the ratios 29Si/28Si and 30Si/28Si over the meteorite classes is small; 1%. per mass unit difference. The average Si isotopic composition for each class of meteorites is identical, within analytical uncertainties. This is quite unlike O, whose anomalous isotopic abundances in bulk samples differentiate among the classes of meteorites. The overlapping abundance ranges of Si isotopes among many classes of meteorites suggest closed-system behavior for this element prior to meteorite accretion and allow calculation of an average solar system Si isotope composition. 相似文献
119.
When the earth blisters: Exploring recurrent liquefaction features in the coastal system of Christchurch,New Zealand
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Monica Giona Bucci Peter Almond Pilar Villamor William Ries Carol Smith Martitia Tuttle 《地学学报》2017,29(3):162-172
The 14 February, or Valentine's Day, 2016 earthquake located offshore of Christchurch produced a new generation of liquefaction in the coastal environment of Christchurch, an environment of recurrent liquefaction during the 2010–2011 Canterbury Earthquake Sequence. The Valentine's Day earthquake occurred while trenches were open at a site in the coastal environment for studying the 2010–2011 liquefaction features. Observations in the 2016 trenches provided insights into the formation of a suite of surface and subsurface liquefaction features characteristic of the dune deposits, related to the persistent shallow water table, well‐sorted sands within the liquefiable layer and the soil above. Given these conducive conditions, there is a high potential that all earthquakes capable of inducing liquefaction may have been recorded during formation of the dunes near Christchurch. However, overprinting by subsequent generations of liquefaction features may be common and present challenges in unravelling the event history. 相似文献
120.
A canonical transformation in phase space and a rescaling of time are proposed to reduce a Keplerian system with a time-dependent Gaussian parameter to a perturbed Keplerian system with a constant Gaussian parameter. When the time variation is slow, the perturbation through second order in the reduced problem is conservative, and, as a result, the orbital space of the averaged system is a sphere on which the phase flow causes a differential rotation representing a circulation of the line of apsides. The flow presents two isolated singularities corresponding to circular orbits travelled respectively in the direct and in the retrograde sense, and a degenerate manifold of fixed points corresponding to the collision orbits. Normalization beyond order two does not break the degeneracy. Adiabatic invariants, which are conservative functions, may be computed from the normalized Hamiltonian evaluated here to the fourth order. Nonetheless so high an approximation gives little information because the normalizing Lie transformation depends explicitly on the time through mixed secular-periodic terms. As an application, an estimate is offered for the apsidal rotation that a second order time derivative in the mass of the sun would induce on planetary orbits. This suggests an observational method for determining the latter parameter for the solar wind, but the predicted motions are too slow for the current level of observational precision. 相似文献