海水中溶解态铵盐氮同位素分析的预处理方法

以蒸馏法为基础, 研究了适合海水中铵盐稳定氮同位素分析的预处理方法。对蒸馏法预处理过程中的最佳蒸馏时间、沸石的选取、铵盐最适浓度范围等分别进行改进和优化, 获得稳定、高效的海水中铵盐氮稳定同位素分析预处理方法。结果表明: 最佳蒸馏时间为50 min, 铵盐的回收率为(97±5.8)%。测定了不同沸石对不同浓度氨氮的吸附率, 筛选出酸性条件下铵氮吸附效率较高且稳定的康华科技沸石; 确定铵盐的最佳适用浓度范围为2～10 μmol/L, 在该浓度范围内氮回收率94%～99%,氮分馏系数为0.1‰～0.8‰。将此方法应用于长江口海域水样分析, 结果表明, 这一方法可以应用于河口中铵盐的氮同位素分析, 能够为河口中溶解态氮的来源及循环机理等研究提供有效信息。     

A bio-optical inversion model to retrieve absorption contributions and phytoplankton size structure from total minus water spectral absorption using genetic algorithm

We propose a bio-optical inversion model that retrieves the absorption contributions of phytoplankton and colored detrital matter(CDM),as well as the phytoplankton size classes(PSCs),from total minus water absorption spectra.The model is based on three-component separation of phytoplankton size structure and a genetic algorithm.The model performance was tested on two independent datasets(the NASA bio-Optical Marine Algorithm Dataset(NOMAD) and the northern South China Sea(NSCS) dataset).The relationships between the estimated and measured values were strongly linear,especially for aCDM(412),and the Root Mean Square Error(RMSE) of the CDM exponential slope(SCDM) was relatively low.Next,the inversion model was directly applied to in-situ total minus water absorption spectra determined by an underwater meter during a cruise in September 2008,to retrieve the phytoplankton size structure in the seawater.By comparing the measured and retrieved chlorophyll a concentrations,we demonstrated that total and size-specific chlorophyll a concentrations could be retrieved by the model with relatively high accuracy.Finally,we applied the bio-optical inversion model to investigate changes in phytoplankton size structure induced by an anti-cyclonic eddy in the NSCS.     

Spatial pattern and regional types of rural settlements in Xuzhou City, Jiangsu Province, China

This paper principally focuses on the morphological differences,spatial pattern and regional types of rural settlements in Xuzhou City of Jiangsu Province in China.Using satellite images of Xuzhou City taken in 2007 and 2008 and models of exploratory spatial data analysis(ESDA) and spatial metrics,the paper conducts a quantitative analysis of the morphological pattern of rural settlements,and finds significant characteristics.First,rural settlements in Xuzhou City are significantly agglomerated in terms of their spatial distribution;meanwhile,there is significant variation in the geographical density distribution.Second,the scale of rural settlements in Xuzhou City is larger than the average in Jiangsu Province,and the histogram of the scale data is more even and more like a gamma distribution.There are a significant high-value cluster in the scale distribution,and local negative correlation between the scale and density distribution of rural settlements in Xuzhou City.Third,the morphology of rural settlements in Xuzhou City shows relative regularity with good connection and integrity,but the spatial variation of the morphology is anisotropic.Finally,according to the characteristics of density,scale,and form of rural settlements,the rural settlements of Xuzhou City are divided into three types:A high-density and point-scattered type,a low-density and cluster-like type and a mass-like and sparse type.The research findings could be used as the scientific foundation for rural planning and community rebuilding,particularly in less-developed areas.     

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1597年10月6日ldquo;珲春-汪清深震区rdquo;Mge;8地震触发的湖震和火山喷发

探讨了1597年10月6日（明万历二十五年八月二十六日）地震的烈度特征,地震伴随的湖震和火山喷发,以及地震类型与规模．结果表明, 1597年10月6日地震为可能发生在ldquo;珲春——汪清深震区rdquo;的一次Mge;8深源地震;地震在中国东部地区产生了广泛的湖震,其多种形态可与1775年葡萄牙里斯本地震产生的湖震比拟;地震触发了望天鹅火山的一次中小规模爆发式喷发,其地点在中国吉林省长白县境内．      

Energy dissipation through wind-generated breaking waves

Wave breaking is an important process that controls turbulence properties and fluxes of heat and mass in the upper oceanic layer.A model is described for energy dissipation per unit area at the ocean surface attributed to wind-generated breaking waves,in terms of ratio of energy dissipation to energy input,windgenerated wave spectrum,and wave growth rate.Also advanced is a vertical distribution model of turbulent kinetic energy,based on an exponential distribution method.The result shows that energy dissipation rate depends heavily on wind speed and sea state.Our results agree well with predictions of previous works.     

Inversion of two-dimensional tidal open boundary conditions of M<Subscript>2</Subscript> constituent in the Bohai and Yellow Seas

Two-dimensional tidal open boundary conditions of the M2 constituent in the Bohai and Yellow Seas(BYS) have been estimated by assimilating T/P altimeter data.During inversion,independent point(IP) strategy was used,in which several IPs on the open boundary is assumed,values at these IPs can be optimized with an adjoint method,and those at other grid points are determined by linearly interpolating the values at IPs.The reasonability and feasibility of the model are tested by ideal twin experiments.In the practical experiment(PE) after assimilation,the cost function may reach 1% or less of its initial value.Mean absolute errors in amplitude and phase can be less than 5 cm and 5°,respectively,and the obtained co-chart can show the character of the M2 constituent in the BYS.The results of the PE indicate that using only two IPs on the open boundary can yield better simulated results.     

Changing spatial and structural patterns of non-agricultural activities in outward-moving Beijing urban fringe

As responses to metropolitan suburbanization and rural urbanization,the formation and evolution of urban fringes should be understood against the background of overall economic development and spatial reconstruction of entire metropolises.At the same time,however,endogenous interactions between industrial structure and spatial patterns of non-agricultural activities are also worthy of scholarly attention.Since the 1980s,studies on urban fringes in China have been restricted by the lack of micro-level data.This paper investigates the spatial expansion and structural evolution of the urban fringe by taking the case of Beijing and uses systematic firm-level data in 1996 and 2001 from the National Census of Basic Units.The diversity of distribution patterns across industrial sectors brings about two interrelated results.On the one hand,structural adjustment of non-agricultural industries promotes the expansion and spatial evolution of the urban fringe.On the other hand,the stability and dynamics of industrial structure coexist in the moving urban fringe.This study also reveals that the outward-moving urban fringe is the optimal location for manufacturing,especially heavy manufacturing,as well as traditional producer and consumer services.However,industries with spatial stickiness such as tourism and sports have not moved with the fringe.Most advanced services remain concentrated in the city center.The authors argue that it is essential for understanding and managing urban fringes to take into account spatial evolution and industrial structural adjustment together with their interaction with each other.     

南昌地震台钻孔应变同震响应分析

通过总结2007年5月以来南昌地震台TJ-2钻孔应变仪的同震效应,并与同期中国地震台网(CSN)提供的全球大震目录中的数据进行对比分析,绘出了震级与震中距的对数关系图,得出南昌地震台体应变仪的映震能力的表达式近似为Ms=1.381gD+ 1.1.     

Chitosan extends the shelf-life of filleted tilapia (Oreochromis niloticus) during refrigerated storage

Shelf-life extension of aquatic products is of significant economical importance. To determine the potential effect of chitosan on the shelf-life of filleted tilapia, this study analyzed the bacterial community diversity in fresh and spoiled tilapia fillets stored at (4 ± 1)℃ and examined the antimicrobial activity of chitosan against relevant bacteria isolates. Results showed that Pseudomonas (20%) and Aeromonas (16%) were abundant in fresh tilapia fillets, whereas Pseudomonas (52%), Aeromonas (32%) and Staphylococcus (12%) were dominant in the spoiled samples. Chitosan showed wide-spectrum antibacterial activity against bacteria isolated from tilapia and 5.0 g L-1 chitosan was selected for application in preservation. We further determined the shelf-life of chitosan-treated, filleted tilapia stored at (4 ± 1)℃ based on microbiological, biochemical and sensory analyses. Results showed that the shelf-life of chitosan-treated, filleted tilapia was extended to 12 d, whereas that of untreated, control samples was 6 d. These indicate that chitosan, as a natural preservative, has great application potential in the shelf-life extension of tilapia fillets.