Monzonitic plutons,California, and a model for generation of alkali-rich,near silica-saturated magmas

Petrochemical data suggest that early Mesozoic alkali-rich monzonite plutons in California were generated by partial melting of a garnet-bearing, virtually feldspar-free source which was rich (compared to abyssal basalt or sub-oceanic mantle peridotites) in LIL elements. These monzonites are characterized by high Na₂O+K₂O (near 10 wt% total) and Sr (1000 to 2000 ppm), moderate SiO₂ (53 to 63 wt%), steep negatively sloping REE patterns (from >100 to <10 × chondritic abundance), and moderate initial ⁸⁷Sr/⁸⁶Sr ratios (0.705 to 0.707). Most are very slightly oversaturated in silica, but one pluton includes both oversaturated and undersaturated units.The simplest petrogenetic model which can account for the compositions of these rocks involves partial melting of quartz eclogite. Any differentiation of the resulting magma must take place under pressures at which plagioclase is unstable. The eclogite could be equivalent to a wide variety of continental or oceanic island basalts.Rocks which are chemically similar to these monzonites, though not extremely abundant, are widespread in both space and time and occur in a wide variety of tectonic settings. These rocks are anomalous in terms of crustal compositions and phase equilibria, but many could be explained as partial melting products of eclogite. Relatively minor thermal events or early stages of major events may tap alkalic intermediate magmas from eclogite pockets as the lowest temperature melting fractions of the upper mantle.     

40Ar39Ar studies of Precambrian cherts; an unsuccessful attempt to measure the time evolution of the atmospheric 40Ar/36Ar ratio

KAr isochron techniques can provide, in principle, an experimental reconstruction of the time evolution of the atmospheric ⁴⁰Ar/³⁶Ar ratio if minerals can be found which contain samples of argon from the ancient atmosphere and which have had a simple geologic history. Authigenic sedimentary minerals with low potassium content appear to be the best candidates. An experimental reconstruction of the evolution of the atmospheric ⁴⁰Ar/³⁶Ar ratio will serve as a test of various models for the chemical and thermal evolution of the Earth.⁴⁰Ar³⁹Ar studies of five chert samples from the Swaziland sequence and the Bulawayan and Gunflint Formations indicate that lower Precambrian cherts do not contain appreciable samples of the ancient atmospheric argon and have experienced complicated geologic histories. The chert sample from the Kromberg Formation contains excess ⁴⁰Ar. The other four samples yield age spectra which are complicated but which are interpretable in terms of geologically reasonable ages.The lack of evidence for argon loss in the chert data suggests that some cherts may prove to be datable sedimentary minerals.     

Surface color variations of the Galilean satellites

Color variations of the four Galilean satellites have been monitored during the summer of 1971 with the McDonald Observatory area-scanning photometer. All were found to vary with orbital phase, with the exception of Europa in B-V. The curves suggest complex variations in surface make-up with some large features, possibly the result of interaction with the Jovian environment.     

Beach erosion under rising sea‐level modulated by coastal geomorphology and sediment availability on carbonate reef‐fringed island coasts

This study addresses gaps in understanding the relative roles of sea‐level change, coastal geomorphology and sediment availability in driving beach erosion at the scale of individual beaches. Patterns of historical shoreline change are examined for spatial relationships to geomorphology and for temporal relationships to late‐Holocene and modern sea‐level change. The study area shoreline on the north‐east coast of Oahu, Hawaii, is characterized by a series of kilometre‐long beaches with repeated headland‐embayed morphology fronted by a carbonate fringing reef. The beaches are the seaward edge of a carbonate sand‐rich coastal strand plain, a common morphological setting in tectonically stable tropical island coasts. Multiple lines of geological evidence indicate that the strand plain prograded atop a fringing reef platform during a period of late‐Holocene sea‐level fall. Analysis of historical shoreline changes indicates an overall trend of erosion (shoreline recession) along headland sections of beach and an overall trend of stable to accreting beaches along adjoining embayed sections. Eighty‐eight per cent of headland beaches eroded over the past century at an average rate of ?0·12 ± 0·03 m yr^?1. In contrast, 56% of embayed beaches accreted at an average rate of 0·04 ± 0·03 m yr^?1. Given over a century of global (and local) sea‐level rise, the data indicate that embayed beaches are showing remarkable resiliency. The pattern of headland beach erosion and stable to accreting embayments suggests a shift from accretion to erosion particular to the headland beaches with the initiation of modern sea‐level rise. These results emphasize the need to account for localized variations in beach erosion related to geomorphology and alongshore sediment transport in attempting to forecast future shoreline change under increasing sea‐level rise.     

Chromium speciation and mobility in a high level nuclear waste vadose zone plume

Radioactive core samples containing elevated concentrations of Cr from a high level nuclear waste plume in the Hanford vadose zone were studied to asses the future mobility of Cr. Cr(VI) is an important subsurface contaminant at the Hanford Site. The plume originated in 1969 by leakage of self-boiling supernate from a tank containing REDOX process waste. The supernate contained high concentrations of alkali (NaOH ≈ 5.25 mol/L), salt (NaNO₃/NaNO₂ >10 mol/L), aluminate [Al(OH)₄⁻ = 3.36 mol/L], Cr(VI) (0.413 mol/L), and ¹³⁷Cs⁺ (6.51 × 10⁻⁵ mol/L). Water and acid extraction of the oxidized subsurface sediments indicated that a significant portion of the total Cr was associated with the solid phase. Mineralogic analyses, Cr valence speciation measurements by X-ray adsorption near edge structure (XANES) spectroscopy, and small column leaching studies were performed to identify the chemical retardation mechanism and leachability of Cr. While X-ray diffraction detected little mineralogic change to the sediments from waste reaction, scanning electron microscopy (SEM) showed that mineral particles within 5 m of the point of tank failure were coated with secondary, sodium aluminosilicate precipitates. The density of these precipitates decreased with distance from the source (e.g., beyond 10 m). The XANES and column studies demonstrated the reduction of 29-75% of the total Cr to insoluble Cr(III), and the apparent precipitation of up to 43% of the Cr(VI) as an unidentified, non-leachable phase. Both Cr(VI) reduction and Cr(VI) precipitation were greater in sediments closer to the leak source where significant mineral alteration was noted by SEM. These and other observations imply that basic mineral hydrolysis driven by large concentrations of OH⁻ in the waste stream liberated Fe(II) from the otherwise oxidizing sediments that served as a reductant for CrO₄²⁻. The coarse-textured Hanford sediments contain silt-sized mineral phases (biotite, clinochlore, magnetite, and ilmenite) that are sources of Fe(II). Other dissolution products (e.g., Ba²⁺) or Al(OH)₄⁻ present in the waste stream may have induced Cr(VI) precipitation as pH moderated through mineral reaction. The results demonstrate that a minimum of 42% of the total Cr inventory in all of the samples was immobilized as Cr(III) and Cr(VI) precipitates that are unlikely to dissolve and migrate to groundwater under the low recharge conditions of the Hanford vadose zone.     

Transport-controlled kinetics of dissolution and precipitation in the sediments under alkaline and saline conditions

Over 1.6 million liters of radioactive, high-temperature, Al-rich, alkaline and saline high-level waste (HLW) fluids were accidentally discharged from tank leaks onto the sediments at the Hanford Site, Washington. In order to better understand processes that might occur during the migration of HLW through sediments and to estimate their extents, we studied the effects of Al-rich, alkaline and saline solutions on soil mineral dissolution and precipitation during reactive transport. Metal- and glass-free systems were used to conduct miscible-displacement experiments at 50 °C under CO₂ and O₂ free conditions. Results showed significant release of Si, K, Al, Fe, Ca, Mg, and Ba into the aqueous phase. The transport-controlled release of these elements was time dependent as evidenced by its extent varying with the fluid residence time. Silica initial dissolution rates (6.08 × 10^-11 and 5.38 × 10^-13 mol m^-2 s^-1) increased with base concentration, decreased with Al concentration, and decreased with fluid residence time. Aluminum precipitation rates varied in the range from 0.44 to 1.07 × 10^-6 mol s^-1 and were faster in these column experiments than in previous batch studies. The initial rate constant of Al precipitation reaction was 0.07 h^-1 (half-life of 9.9 h at about 3 PV); it increased up to 0.137 h^-1 (half-life of 5.1 h at about 20 PV). The precipitates identified with SEM and suggested from the modeling results were mainly NO₃-cancrinite. SEM analyses also indicated the formation of sodalite when Al was not present in the leaching solution. In addition, results from modeling suggested the precipitation of brucite, goethite and gibbsite; the latter may precipitate in the presence of high Al concentrations. Aqueous and solid phase transformations caused by base-induced dissolution and subsequent secondary phases precipitation should be important determinants of the fate of contaminants and radionuclides in the vadose zone under alkaline and saline conditions.     

Identifying American Beer Geographies: A Multiscale Core-Cluster Analysis of U.S. Breweries

The recent growth in the U.S. brewing industry is remarkable, and the prevailing number of breweries has not been seen since the late nineteenth century. Several studies have shown that beer-producing facilities are spatially uneven across the United States. These previous studies used spatial units, however, such as metropolitan statistical areas, that might bias conclusions. Using a multiscale core-cluster approach, we explicitly identify where significant agglomerations of brewers are located. Our approach offers two refinements to standard cluster detection methods. First, instead of using fixed spatial boundaries, our method allows us to measure the concentration of brewery point locations across a spectrum of spatial scales. Additionally, our approach enables us to account for important underlying factors that influence the location of beer production. We use point data for all U.S. breweries in 2014. Our results show that the localization of beer production is significant and strongest at small spatial scales and diminishes rapidly with increasing distance, after controlling for population. We map the results to show the spatial variation in brewery agglomeration across the United States.     

Self-governance within a QMS framework—The evolution of self-governance in the New Zealand Bluff oyster fishery

This paper examines efforts to develop stakeholder led self-governance in the Bluff oyster fishery. The paper focuses on collaborative management and its ability to address some of the unintended consequences of management. The Bluff oyster fishery's administrative, biological, and economic performances are analysed to assess whether or not the participatory management model, in this case fisheries self-governance, complements individual transferable quota (ITQ) for this inshore shellfish fishery.The paper argues that the Bluff oyster fishery's current self-governance model, based on a fishery plan, aids in improving the performance of the fishery, and that the Bluff oyster fishery has the capacity to shift further towards a stakeholder led self-regulated fishery.