Influence of anthropogenic pressure and seasonal upwelling on coral reefs in Nha Trang Bay (Central Vietnam)

The growing coastal development, dredging and dumping activities, overfishing and expansion of marine cage culture in Nha Trang Bay (NTB) of Central Vietnam since the beginning of the 2000s have resulted in a dramatic decrease of live coral cover. Surveys conducted in April–May 2013 and the same period in 2014 revealed that with an increase in distance from the outer part of the bay towards the mainland, the rivers’ influxes and dredged areas, coral cover decreased from 75% to 0.6% and species richness from 63 to 5, while the abundance of macroalgae increased from 0% to 56%. These changes correlate with differences in the concentration of suspended sediments on the same gradient. The abundance of the crown‐of‐thorns starfish Acanthaster planci and of the echinoid Diadema setosum significantly increased between the first estimation in 1998 and the survey in 2014, from 0 to 1.7 individuals (ind.) per 100 m^?2 and from 50.8 to 94.5 ind. per 100 m^?2, respectively, contributing to coral loss and intensive bioerosion of the reef framework in the bay. The large sizes of adult colonies of tabulate Acropora on the remote stations with negligible sedimentation and eutrophication loads were inconsistent with the assumptions that temperature‐induced coral bleaching or cyclones could be the major impacts in Nha Trang Bay. Analysis of the 16‐year thermal history of the bay did not reveal any instances in which the coral thermal bleaching threshold had been exceeded up to the present study. Seasonal upwelling, which occurs annually in the vicinity of Central Vietnam, may contribute to mitigation of thermal anomalies within NTB and to the maintenance of healthy coral communities on the remote reefs with relatively low anthropogenic impact.     

Improved regional groundwater flow modeling using drainage features: a case study of the central northern karst aquifer system of Puerto Rico (USA)

In northern Puerto Rico (USA), subsurface conduit networks with unknown characteristics, and surface features such as springs, rivers, lagoons and wetlands, drain the coastal karst aquifers. In this study, drain lines connecting sinkholes and springs are used to improve the developed regional model by simulating the drainage effects of conduit networks. Implemented in an equivalent porous media (EPM) approach, the model with drains is able to roughly reproduce the spring discharge hydrographs in response to rainfall. Hydraulic conductivities are found to be scale dependent and significantly increase with higher test radius, indicating scale dependency of the EPM approach. Similar to other karst regions in the world, hydraulic gradients are steeper where the transmissivity is lower approaching the coastline. This study enhances current understanding of the complex flow patterns in karst aquifers and suggests that using a drainage feature improves modeling results where available data on conduit characteristics are minimal.     

河北围场早中新世藓类化石的植物地理学意义

对河北省围场地区广发永剖面藓类植物薄网藓Leptodictyum riparium、似叶镰刀藓Drepanocladus trichophyllus和多姿柳叶藓Amblystegium varium的古地理及其对应的现代植物地理分布研究显示,这些植物最早出现于早中新世的围场地区,可能起源于该时期的古北大陆,东亚为起源中心。之后向东通过白令陆桥扩散到北美,向西沿欧亚大陆扩散至欧洲西部,至全新世时主要分布在北半球。全新世后,薄网藓与多姿柳叶藓进一步向南扩散,分别由北美及亚洲东部扩散到南美洲及澳大利亚地区,逐步形成现在的分布格局;毛叶镰刀藓则在更新世就已形成与现代相近的分布格局。该研究确立了3种藓类植物的地理起源、地史分布及迁移路线。     

Effects of key components of <Emphasis Type="Italic">S. triqueter</Emphasis> root exudates on fractions and bioavailability of pyrene–lead co-contaminated soils

The key components of S. triqueter root exudates involved 4-oxo-pentanoic acid, succinic acid, glutaric acid, phthalate acid, citric acid, vanillic acid, myristic acid, pentadecanoic acid, decanoic acid, 14-methyl-pentadecanoic acid, hexadecanoic acid, octadecanoic acid and oleic acid, and the content of the water-soluble organic acids (citric acid, succinic acid and glutaric acid) significantly increased in pyrene and lead co-contaminated rhizosphere soil. These three water-soluble organic acids including citric acid, succinic acid and glutaric acid were detected as the specific root exudates of S. triqueter under stress of pollutants for pyrene and lead, so they were chosen as the research objects, and they were added into the bioremediation systems of pyrene and lead co-contaminated wetland soils. Compared with the control, the treatments added the three organic acids always improved the quantity of the bioavailable fraction of pyrene and lead in wetland soils and greatly influenced other chemical states of pyrene and lead fractions in the test concentration range. Under the 50 g kg^?1 of organic acids concentration, the amount of the bioavailable fraction of pyrene and lead increased 41.0 and 872.7 % by citric acid, respectively. The enhancement of bioavailability of pyrene and lead in the wetland soil by adding organic acids generally decreased in the following order: citric acid > succinic acid > glutaric acid. Enhancing effects of organic acids on the bioavailability improvement of pyrene and lead is remarkable.     

Role of bentonite adsorbent sub-layer in the photocatalytic-adsorptive removal of methylene blue by the immobilized TiO<Subscript>2</Subscript>/bentonite system

An immobilized clay composite (BEN–PVAG) on a glass plate (GP) was fabricated using bentonite powder (BEN) and glutaraldehyde cross-linked polyvinyl alcohol (PVAG) as the adsorbent and adhesive, respectively. The immobilized bentonite composite (BEN–PVAG) was characterized using SEM, EDX, FTIR, and BET analysis. The adsorption capacity of BEN–PVAG was examined using methylene blue (MB) as the model pollutant. The results indicated that the adsorption of MB onto BEN–PVAG obeyed pseudo-second-order kinetics. In addition, the adsorption of MB by the immobilized BEN–PVAG was controlled by intra-particle diffusion. In contrast, the adsorption of MB by the suspended BEN–PVAG composite was dominated by film diffusion. The immobilized BEN–PVAG was then applied as the adsorbent sub-layer for the fabrication of P-25TiO₂/BEN–PVAG/GP bilayer system where P-25TiO₂ was deposited as the top layer. The fabricated bilayer system exhibited synergistic photocatalytic-adsorptive removal of MB upon irradiation with a light source, while experiment in the dark yielded only adsorption process. The rate of the synergistic photocatalytic-adsorptive removal of MB by the P-25TiO₂/BEN–PVAG/GP was 5.3 times faster than the suspended P-25TiO₂. The result implied the positive impact of the BEN–PVAG adsorbent sub-layer on the immobilized P-25TiO₂ photocatalyst. Most important, the immobilized P-25TiO₂/BEN–PVAG/GP provided a convenient reuse of the catalyst over time where the treated water could be directly discharged without the need of filtration.     

Testing and modeling of the mechanical behavior of dolomite in the Wudongde hydropower plant

In order to understand the mechanical behaviours of the surrounding rocks in the underground caverns of the Wudongde hydropower plant, triaxial tests are performed on a type of dolomite. It is revealed that damage induced by crack development is the main factor controlling the nonlinear plastic deformation and failure behaviour of the dolomite in both pre- and post-peak regimes. Based on this understanding, a coupled elastoplastic damage model is developed for capturing the dolomite’s mechanical behaviours. In the model, the effects of plasticity and damage on rocks is described by introducing plastic hardening and damage softening commonly in the plastic yield surface. Which are both derived from a suitable Helmholtz free energy function. The model is used to simulate the triaxial tests. Comparisons between test results and the numerical modelling show that the developed model is capable of describing the macro mechanical behaviours of the Wudongde dolomite.