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1.
Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff
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We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AICC] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component. 相似文献
2.
Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro. 相似文献
3.
本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实 相似文献
4.
盘山山前地下水与矿泉水污染成因分析 总被引:4,自引:0,他引:4
文章利用主成分分析方法,结合揭示变量和样品之间在成因或空间上联系的对应分析,通过SPSS统计分析软件,对盘山山前地区地下水和矿泉水污染成因进行分析。研究表明,盘山山前存在地下水和矿泉水污染;局部范围的污染主要是由于食品厂等企业的排污引起的,污染成分主要是Cl-和NO3—N,主要污染地区是塔院地区,其次是西大佛塔至南营,污染程度与至污染源的距离有关;大部分地区存在三氮面状污染,农业氮肥的施用是其主要原因。 相似文献
5.
四川省华蓥市赵子秀山变形体的成因机制研究 总被引:1,自引:0,他引:1
赵子秀山变形体位于华蓥市西北部,变形体一旦失稳将直接对华蓥市造成威胁。本文从斜坡地质结构、变形破裂特征、地貌演化及人类工程活动(采煤)入手,结合数值模拟的方法研究变形体的变形机制。研究表明变形体的形成是下部含煤层的中倾角反向层状结构斜坡在河谷下切过程中发生倾倒-拉裂变形所致,同时,后期的采煤活动对拉裂变形的发展有较大影响。 相似文献
6.
7.
Tetraploid induced by physical and chemical methods in Jinjiang oyster(Crassostrea rivularis) 总被引:1,自引:0,他引:1
Rong Shoubai Shi Shumei Mo Qirong Liu Shaeqiong Liang Ze Zhao Xiuzhu Tong Wangdong Li Shouwu Li Yimin 《海洋学报(英文版)》1994,13(2):275-283
TetraploidinducedbyphysicalandchemicalmethodsinJinjiangoyster(Crassostrearivularis)¥RongShoubai,ShiShumei,McQirong,LiuShaeqio... 相似文献
8.
1 .IntroductionNondestructiveinspection (NDI)isveryimportantforensuringthereliabilityofoffshorestructuresintheirservicelives (Lauraetal.,1 996 ) .Itiswellknownthatdetectionofflawsinvolvesconsider ablestatisticaluncertainties.Asaresult,theprobabilityofdetection (POD)forallflawsofagivensizehasbeenusedintheliteraturetodefinethecapabilityofaparticularNDItechniqueinagivenen vironment.SincethedataofPODusuallyscatterlargely ,itisdifficulttodeterminewhichmodelfitstheavailabledatabest.Thismodelun… 相似文献
9.
本文通过扫描电镜的观察,研究了对虾科中5个属10种虾的雄性交接器联合缘上的小钩,对小钩的形态特征及小钩的机能进行了分析和描述。研究表明,小钩的研究将为对虾形态分类工作提供新的参考依据。 相似文献
10.
A new approach to high-order Boussinesq-type equations with ambient currents is presented. The current velocity is assumed to be uniform over depth and of the same magnitude as the shallow water wave celerity. The wave velocity field is expressed in terms of the horizontal and vertical wave velocity components at an arbitrary water depth level. Linear operators are introduced to improve the accuracy of the kinematic condition at the sea bottom. The dynamic and kinematic conditions at the free surface are expressed in terms of wave velocity variables defined directly on the free surface. The new equations provide high accuracy of linear properties as well as nonlinear properties from shallow to deep water, and extend the applicable range of relative water depth in the case of opposing currents. 相似文献