The importance of oxygen isotope provenance in relation to solute content of bulk meltwaters at Imersuaq Glacier,West Greenland

Stable oxygen isotope analysis and measurement of several dissolved cations and anions of bulk meltwater samples have provided information about the hydrochemical environment of the glacial hydrological system at Imersuaq Glacier, an outlet tongue from the Greenland ice‐sheet, West Greenland. The samples were collected at frequent intervals during the period 20–28 July 2000 in a small (<20 L s^?1) englacial meltwater outlet at the glacier margin. The results document the following findings: (i) a marked diurnal variation of δ¹⁸O is related to the composition of oxygen isotope provenances, mainly near‐marginal local superimposed ice and basal up‐sheared ice further up‐glacier; (ii) a relationship is seen between all base cations (Na⁺, K⁺, Ca²⁺, Mg²⁺), SO₄^2? and δ¹⁸O, indicating that solute acquisition is provided by solid–solution contact with the up‐sheared ice—as the relationship with Cl^? is weak the influence of seasalt‐derived solutes is small in the area; (iii) when the melt rate is high, two diurnal maxima of δ¹⁸O values and solute concentrations are measured, and it is suggested that a snow meltwater component is responsible for the second maximum of δ¹⁸O—a short residence time leads to a delayed decrease in ion concentrations. Copyright © 2003 John Wiley & Sons, Ltd.     

The development of three-dimensional current system during a magnetospheric substorm

It is suggested that the pattern of three-dimensional substorm current circuit varies significantly even during the lifetime of a single substorm. This gives rise to quite complex time variations of the magnetic field at low latitude stations even for relatively isolated substorms. To verify this, three-dimensional current models with time dependent spatial variations are used to simulate one type of complex low-latitude “substorm signature”. It is shown that the utmost care should be exercised in determining different substorm phases on the basis of such a signature. The results indicate also that, in certain longitudes in the evening sector, one should expect distinct differences in characteristics between positive bays observed on the ground and at the synchronous distance.     

Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

Multi‐sensor Image Maps from SPOT,ERS and JERS

Abstract

Image mapping using data from visible and infrared sensors has, as a major drawback, the frequent cloud cover experienced in many countries. This is one of the main reasons why topographic maps at 1:100,000 scale and larger are often outdated. The results of a study which investigated the possibilities of fusing up‐to‐date spaceborne microwave data with existing images from optical sensors for topographic map updating at a scale of 1:100, 000 are presented in this paper. A key issue researched was the influence of geometric distortions and corrections of remote sensing data on the results of pixel based digital image fusion. After having terrain‐geocoded and radiometrically enhanced imagery from the Landsat, SPOT, ERS‐1 and JERS‐1 satellites, the data were fused applying a variety of colour transformation techniques as well as statistical or arithmetic methods. Initially, the image fusion was implemented using images covering a test site in the north of The Netherlands in order to calibrate specified combinations and techniques in a rather flat area. With the experience gained, the remote sensing data acquired over the research site were processed. The research test site is located in a typical Developing Country in the humid Tropics, on the mountainous south‐west coast of Sumatra in Indonesia. The results of the various applied techniques and image combinations were evaluated with reference to their capability to overcome the cloud cover problem. New combinations of techniques and images were developed as result of an optimisation process. The research produced two prototypes of annotated 1:100,000 scale image maps containing fused, cloud‐free optical/microwave imagery.     

Thermodynamic controls on element partitioning between titanomagnetite and andesitic–dacitic silicate melts

Titanomagnetite–melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity (fO₂) and temperature (T) in an andesitic–dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite–melt partitioning of the divalent cations (Mg²⁺, Mn²⁺, Co²⁺, Ni²⁺, Zn²⁺) and Cu²⁺/Cu⁺ with increasing fO₂ between 0.2 and 3.7 log units above the fayalite–magnetite–quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral–melt partitioning of divalent cations, a more rigorous justification of magnetite–melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO₂ implies a reciprocal relationship between a(Fe²⁺O) and a(Fe³⁺O_1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite–melt partitioning of divalent cations with fO₂ in magnetite-rich spinel. As a result of this, titanomagnetite–melt partitioning of divalent cations is indirectly sensitive to changes in fO₂ in silicic, but less so in mafic bulk systems.     

Stratospheric methane and nitrogen dioxide from infrared spectra

Values of the mixing ratio by volume of stratospheric NO₂ and CH₄ deduced from infrared spectra taken by means of balloon-borne spectrometers are presented. Possible evidence for the presence of formaldehyde in the stratosphere is also given.     

Local hydraulic gradient estimator analysis of long-term monitoring networks

Three measurements of head at unique locations form a three-point estimator of the local magnitude and orientation of the hydraulic gradient. The relative head measurement error (RHME) is defined here as the measurement error normalized by the head drop across the three-point estimator. Monte Carlo simulation results show that estimators with base to height ratios between 0.5 and 5.0 and that are large enough to keep the RHME below 0.05 create the most accurate gradient estimates and provide criteria for identifying good estimators. These criteria are applied to an example ground water monitoring network design problem in the Culebra dolomite near the Waste Isolation Pilot Plant repository to both analyze temporal changes and modify and expand the current monitoring network. Limiting the three-point estimators to those that meet the shape and RHME criteria reduces the number of possible estimators by >50% and leads to approximately 1 order of magnitude decrease in the average estimated magnitude of the gradient relative to using all estimators. Application of these criteria also reduces the variability in estimated gradient magnitude and orientation between the two time periods of measurements. Redundant wells in the network are identified by removing each existing well in turn and determining which removals yield the smallest decrease in the number of acceptable estimators. Optimal new well locations are identified by mapping the increase in total number of acceptable estimators for a single new well placed in the study domain.