Thallium isotope variations in an ore-bearing continental igneous setting: Collahuasi Formation, northern Chile

Thallium is a highly incompatible element and a large fraction of the bulk silicate Earth Tl budget is, therefore, expected to reside in the continental crust. Nonetheless, the Tl isotope systematics of continental rocks are essentially unexplored at present. Here, we present new Tl isotope composition and concentration data for a suite of 36 intrusive and extrusive igneous rocks from the vicinity of porphyry Cu deposits in the Collahuasi Formation of the Central Andes in northern Chile. The igneous lithologies of the rocks are variably affected by the hydrothermal alteration that accompanied the formation of the Cu deposits.The samples display Tl concentrations that vary by more than an order of magnitude, from 0.1 to 3.2 μg/g, whilst ε²⁰⁵Tl ranges between −5.1 and +0.1 (ε²⁰⁵Tl is the deviation of the ²⁰⁵Tl/²⁰³Tl isotope ratio of a sample from a standard in parts per 10⁴). These variations are primarily thought to be a consequence of hydrothermal alteration processes, including metasomatic transport of Tl, and formation/breakdown of Tl-bearing minerals, which are associated with small but significant Tl isotope effects. The Tl abundances show excellent correlations with both K and Rb concentrations but no co-variation with Cu. This demonstrates that Tl displays only limited chalcophile affinity in the continental crust of the Collahuasi Formation, but behaves as a lithophile element with a distribution that is primarily governed by partitioning of Tl⁺ into K⁺-bearing phases. Collahuasi samples with propylitic alteration features, which are derived from the marginal parts of the hydrothermal systems, have, on average, slightly lighter Tl isotope compositions than rocks from the more central sericitic and argillic alteration zones. This small but statistically significant difference most likely reflects preferential retention of isotopically heavy Tl in alteration phases, such as white micas and clays, which formed during sericitic and argillic alteration.     

Anthropogenic effects on the smalltooth sawfish (Pristis pectinata) in the United States

Bycatch mortality in net fisheries was the major reason for the decline of the endangered smalltooth sawfish, Pristis pectinata, in the United States. These fisheries have been reduced or eliminated in some states including Florida--where most smalltooth sawfish are currently found in the United States. To determine whether other factors are still affecting this species, we obtained non-net fishery entanglement, injury, and mortality data by soliciting information from anyone who may have encountered this species. Smalltooth sawfish were damaged by marine pollution (e.g., polyvinyl chloride pipe, monofilament line, non-monofilament line) and injured by humans. Examples of injuries caused directly by humans include removal of rostra, shooting an individual with a powerhead, and shooting another with arrows. Many people are aware that the smalltooth sawfish is protected by state and federal laws, but some are still not aware of (or willing to accept) this status. The impacts of marine pollution and injuries directly caused by humans on this endangered species can be ameliorated by incorporating fisher education into the conservation and management processes.     

Use of Recycled Polyethylene Terephthalate Strips in Soil Improvement

Geotechnical and Geological Engineering - Many studies have investigated polyethylene terephthalate (PET) and polypropylene fibers in soil improvement. However, there is a lack of research using...     

The unusual X-ray light curve of GRB 080307: the onset of the afterglow?

Swift -detected GRB 080307 showed an unusual smooth rise in its X-ray light curve around 100 s after the burst, at the start of which the emission briefly softened. This 'hump' has a longer duration than is normal for a flare at early times and does not demonstrate a typical flare profile. Using a two-component power-law-to-exponential model, the rising emission can be modelled as the onset of the afterglow, something which is very rarely seen in Swift -X-ray light curves. We cannot, however, rule out that the hump is a particularly slow early-time flare, or that it is caused by upscattered reverse shock electrons.     

Dust processing in nova winds

We have radically re-assessed the conditions required for the formation and growth of carbon grains in the ejecta of novae. The stability and hence the ultimate fate of the grains is primarily determined by the degree to which they are annealed by the nova's ultraviolet radiation field.     

Short-term environmental variability in cold-water coral habitat at Viosca Knoll,Gulf of Mexico

The Lophelia pertusa community at Viosca Knoll (VK826) is the most extensive found to date in the Gulf of Mexico. As part of a multi-disciplinary study, the physical setting of this area was described using benthic landers, CTD transects and remotely operated vehicle observations. The site was broadly characterised into three main habitats: (1) dense coral cover that resembles biogenic reef complexes, (2) areas of sediment, and (3) authigenic carbonate blocks with sparse coral and chemosynthetic communities. The coral communities were dominated by L. pertusa but also contained numerous solitary coral species. Over areas that contained L. pertusa, the environmental conditions recorded were similar to those associated with communities in the north-eastern Atlantic, with temperature (8.5–10.6 °C) and salinity (～35) falling within the known species niche for L. pertusa. However, dissolved oxygen concentrations (2.7–2.8 ml l^?1) and density (σ_Θ, 27.1–27.2 kg m^?3) were lower and mass fluxes from sediment trap data appeared much higher (4002–4192 mg m^?2 d^?1). Yet, this species still appears to thrive in this region, suggesting that L. pertusa may not be as limited by lower dissolved oxygen concentrations as previously thought. The VK826 site experienced sustained eastward water flow of 10–30 cm s^?1 over the 5-day measurement period but was also subjected to significant short-term variability in current velocity and direction. In addition, two processes were observed that caused variability in salinity and temperature; the first was consistent with internal waves that caused temperature variations of 0.8 °C over 5–11 h periods. The second was high-frequency variability (20–30 min periods) in temperature recorded only at the ALBEX site. A further pattern observed over the coral habitat was the presence of a 24 h diel vertical migration of zooplankton that may form part of a food chain that eventually reaches the corals. The majority of detailed studies concerning local environmental conditions in L. pertusa habitats have been conducted within the north-eastern Atlantic, limiting most knowledge of the niche of this species to a single part of an ocean basin. Data presented here show that the corals at VK826 are subjected to similar conditions in temperature, salinity, and flow velocity as their counterparts in the north-east Atlantic, although values for dissolved oxygen and density (sigma-theta: σ_Θ) are different. Our data also highlight novel observations of short-term environmental variability in cold-water coral habitat.     

A comparison of single‐run pushover analysis techniques for seismic assessment of bridges

Traditional pushover analysis is performed subjecting the structure to monotonically increasing lateral forces with invariant distribution until a target displacement is reached; both the force distribution and target displacement are hence based on the assumption that the response is controlled by a fundamental mode, that remains unchanged throughout. However, such invariant force distributions cannot account for the redistribution of inertia forces caused by structural yielding and the associated changes in the vibration properties, including the increase of higher‐mode participation. In order to overcome such drawbacks, but still keep the simplicity of using single‐run pushover analysis, as opposed to multiple‐analyses schemes, adaptive pushover techniques have recently been proposed. In order to investigate the effectiveness of such new pushover schemes in assessing bridges subjected to seismic action, so far object of only limited scrutiny, an analytical parametric study, conducted on a suite of continuous multi‐span bridges, is carried out. The study seems to show that, with respect to conventional pushover methods, these novel single‐run approaches can lead to the attainment of improved predictions. Copyright © 2007 John Wiley & Sons, Ltd.     

Measurements of the direction of the solar wind using interplanetary scintillation

EISCAT observations of the interplanetary scintillation of a single source were made over an extended period of time, during which the orientation of the baselines between the two observing sites changed significantly. Assuming that maximum correlation between the scintillations observed at the two sites occurs when the projected baseline is parallel to the direction of plasma flow, this technique can be used to make a unique determination of the direction of the solar wind. In the past it has usually been assumed that the plasma flow is radial, but measurements of eleven sources using this technique have indicated conclusively that in at least six cases observed at mid or high heliocentric latitude there is a significant non-radial component directed in four cases towards the heliocentric equator and in two cases towards the pole.     

Form, function and feedbacks in a tidally dominated ooid shoal, Bahamas

Although the general aspects of oolitic depositional systems are well documented, seascape‐scale (≈10³–10⁶ m²) patterns of oolitic shoals and the details of processes acting on them are not well understood or quantified. To begin to fill this basic gap in understanding, this paper describes the morphology and hydrodynamics of Lily Bank, a Modern tidally dominated Bahamian ooid shoal. In this study, integrating remote sensing imagery with quantitative, geo‐located bathymetrical, hydrological and granulometric data in a Geographic Information System documents geomorphic and sedimentological patterns and facilitates interpreting these patterns in the context of the processes operating in this system. The results of these analyses reveal that parabolic bars up to several kilometres in wavelength and several metres in height form a common morphologic motif, although there is considerable variation on that general theme. The seascape‐scale configuration of bars and superimposed sedimentary structures is closely linked to spatial patterns of tidal movements, and includes the presence of mutually evasive flood and ebb channels. Sedimentologically, bars are neither homogenous nor random bodies; instead, granulometric parameters such as sorting and percentage mud vary systematically, as shaped by hydro‐geomorphic controls. The best sorted, coarsest ooids are on bar crests, whereas the finest grains are found in the lower energy, deeper interior and flanking regions. In short, results clearly document hydrodynamic‐bathymetrical influences on these ooid shoals and their granulometry, linkages akin to siliciclastic analogues. Sedimentological, hydrodynamic and geomorphic observations are consistent with a conceptual model for the formation of parabolic bars in which initial irregularities in non‐parabolic bars are enhanced through their effect of focusing flow. Constricted flow leads to higher flow velocities, tidal flow velocity asymmetries, differential net sediment transport and growth of bathymetrical highs. This bathymetrical divergence creates separate paths for flood‐ and ebb‐tides, facilitating emergence of better‐developed parabolic forms. The resultant parabolic geometries and component bedforms appear to be either in dynamic equilibrium with both ebb‐ and flood‐tide flows, or evolving toward that state. In exploring patterns and processes within carbonate shoals, this study illustrates some of the first documented insights on quantitative details of morphology and dynamics and in the links between geomorphic framework and grain‐size and sorting in an oolitic carbonate system. Assuming a continuity of processes between ancient and modern, the insights from this shoal provide information on possible facies geometries and on the characteristics of grains and depositional porosity of analogous facies within ancient ooid shoals.     

Fluvial channel and overbank deposits from the Westphalian of the Durham coalfield, NE England

The Westphalian (Upper Carboniferous) Coal Measures of the Durham coalfield in NE England were deposited in lower and upper delta plain environments. Distributary channels crossed the plain and were separated by shallow, interdistributary lakes and bays. Detailed observation of three-dimensional (3-D) opencast (surface) mine exposures, in collaboration with subsurface borehole analysis, has revealed the existence of five varieties of channel deposits and two associated overbank facies within the Durham Coal Measures. Major distributary channels were the major avenues of sediment transport across the Coal Measures plain, were variably sinuous, mostly 1–2 km wide and deposited elongate belts of sand mostly up to 5 km wide. Proximal, major crevasse splay channels formed by the breaching of major channel banks during flood events, were straight, sand-filled and up to 400 m wide. Minor distributary channels formed by the sustained operation of such crevasses, varied from straight to highly sinuous, and deposited ‘shoestring’ sand/mud belts up to a few hundred metres wide. Minor crevasse channels, generally straight and up to 50 m wide, were formed through bank breaching of minor, and in a few cases major, distributaries. Distal feeder channels formed down-palaeocurrent extensions of minor distributaries which supplied interdistributary minor delta subsystems, were generally straight and up to 200 m wide. Of the two types of channel overbank (levee) deposits recognized, one, comprising thinly interbedded fine-grained sandstone and siltstone/claystone, is mostly, though not exclusively, associated with major distributary channels. The other, consisting of ‘massive’ siltstones with regularly spaced, thin claystone bands, is uniquely developed at the margins of minor distributary channels. The lower part of the Westphalian A succession in the northern Pennines records a change in the depositional environment upwards from a lower to upper delta plain. Through this transition, major channel deposits show evidence of having evolved from being of dominantly low sinuosity to being more variable in morphology. Channel sedimentation was profoundly influenced by regular, possibly seasonal, variations in flow stage and sediment load.