Trace element distribution in mineral separates of the Allende inclusions and their genetic implications

Concentrations of the REE, Sc, Co, Fe, Zn, Ir, Na and Cr were determined by instrumental neutron activation and mass spectrometric isotope dilution analysis for mineral separates of the coarseand fine-grained types (group I and II of Martin and Mason's classification) of the Allende inclusions.These data, combined with data on mineral/liquid partition coefficients, oxygen isotope distributions and diffusion calculations, suggest the following: (1) Minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements. On the other hand, differences in oxygen isotope distributions among minerals preclude a totally molten stage in the history of the inclusion. Group I inclusions were formed by rapid condensation (either to liquid or solid) in a supercooled solar nebula; extrasolar pyroxene and spinel dust were included but not melted in the condensing inclusions, thus preserving their extrasolar oxygen isotope composition. REE were distributed by diffusion during the subsequent heating at subsolidus temperatures; because oxygen diffuses much more slowly at these temperatures, the oxygen isotope anomalies were preserved. (2) The fine-grained (group II) inclusions were also formed by condensation from a super-cooled nebular gas; however, REE-rich clinopyroxene and spinel were formed early and REE-poor sodalite and nepheline were formed later and mechanically mixed with clinopyroxene and spinel to form the inclusions. The REE patterns of the bulk inclusions and the mineral separates are fractionated, indicating that REE abundances in the gaseous phase were already fractionated at the time of condensation of the minerals. (3) Pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage thus resetting the ²⁶Al-²⁶Mg chronometer.     

Zur permischen Vereisung der Salt Range (W.-Pakistan)

Zusammenfassung Die unterpermischen Geröll-Packungen der östlichen Salt Range führen fazettierte und geschrammte Geschiebe unzweifelhaft glazialer Entstehung, die zusammen mit anderen Hinweisen eine Deutung der Boulder Beds als fluviatile Konglomerate (nachLotze) nicht überzeugend erscheinen lassen. Die ausgezeichnete Erhaltung der Schrammung schließt zum mindesten einen längeren Flußtransport aus. Das vereiste Gebiet muß sich daher in der Salt Range selbst oder in seiner unmittelbaren Nachbarschaft befunden haben.

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The Lower Permian boulder beds of the eastern Salt Range contain facetted and scratched boulders of unquestionably glacial origin. Their excellent preservation seems to tell in favour of a glacial tillite rather than of a fluviatile conglomerate, as supposed by F.Lotze. At least a fluvial transport of the glacial boulders over a longer distance is to be excluded. The Salt Range itself or its immediate surroundings must have been covered by the Permian glaciers.

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Résumé Les boulder beds du Permien inférieur de la Salt Range orientale contiennent des galets nettement facettés et striés d'origine glaciale. Leur préservation excellente exclut un long transport fluviatile. Par conséquent la Salt Range elle-même ou ses environs immédiats doivent avoir été couverts de glaciers permiens.

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Die vorstehenden Zeilen sind nicht als Selbstverteidigung, sondern in dem Wunsche geschrieben, den von Tübingen ausgegangenen Arbeiten E.Kokens und denen F.Noetlings, der in seinen späteren Jahren gleichfalls in Tübingen wirkte, zur Anerkennung zu verhelfen. Herrn Koll. G.Einsele danke ich verbindlichst für die Durchmusterung der von den abgebildeten Geschieben angefertigten Dünnschliffe. Unsere Bild-Erläuterungen beruhen auf seinen Bestimmungen.     

UBV photometry of the WR binary CQ Cephei

Photoelectric observations of the WR binary CQ Cephei (WN6+O9) are presented. the depths of the eclipses in the light curves are best represented by an inclination of the orbit i = (68°.8±0.6) and the width of the very asymmetric eclipse curves can be represented by only an overcontact configuration (Ω₁ = Ω₂ = 3.65 ± 0.05, and f = 27%). Simultaneous solution of the light and radial velocity curves strongly supports CQ Cep's membership of the Cep OB1 association. By considering this membership we obtained absolute dimensions of the system, which lead to a consistent physical model for CQ Cephei. The more luminous WR primary turns out to be the hotter but slightly less massive component: M_WR = 20.8 M⊙, R_WR = 8.2R⊙, T_eff(WR) = 43600 K, and M_o = 21.4 M⊙, R_o = 8.3 R⊙, T_eff(O) = 37000 K.     

Geology,petrography, shock petrography,and geochemistry of impactites and target rocks from the Kärdla crater,Estonia

Abstract— The Kärdla crater is a 4 km‐wide impact structure of Late Ordovician age located on Hiiumaa Island, Estonia. The 455 Ma‐old buried crater was formed in shallow seawater in Precambrian crystalline target rocks that were covered with sedimentary rocks. Basement and breccia samples from 13 drill cores were studied mineralogically, petrographically, and geochemically. Geochemical analyses of major and trace elements were performed on 90 samples from allochthonous breccias, sub‐crater and surrounding basement rocks. The breccia units do not include any melt rocks or suevites. The remarkably poorly mixed sedimentary and crystalline rocks were deposited separately within the allochthonous breccia suites of the crater. The most intensely shockmetamorphosed allochthonous granitoid crystalline‐derived breccia layers contain planar deformation features (PDFs) in quartz, indicating shock pressures of 20–35 GPa. An apparent K‐enrichment and Ca‐Na‐depletion of feldspar‐ and hornblende‐bearing rocks in the allochthonous breccia units and sub‐crater basement is interpreted to be the result of early stage alteration in an impact‐induced hydrothermal system. The chemical composition of the breccias shows no definite sign of an extraterrestrial contamination. By modeling of the different breccia units with HMX‐mixing, the indigenous component was determined. From the abundances of the siderophile elements (Cr, Co, Ni, Ir, and Au) in the breccia samples, no unambiguous evidence for the incorporation of a meteoritic component above about 0.1 wt% chondrite‐equivalent was found.     

CCD‐Δa and BV R photometry of NGC 7296

The first CCD photometric investigation of the open cluster NGC 7296 up to now was performed within the narrow band Δa photometric system, which enables us to detect peculiar objects. A deeper investigation of that cluster followed, using the standard BV R ‐Bessel filter set. The age and E (B – V ) was determined independently to log t = 8.0 ± 0.1 and 0.15 ± 0.02, respectively by using Δa and broadband photometry. In total five Be/Ae objects and two metal‐weak stars showing significant negative Δa ‐values as well as one classical chemically peculiar star could be identified within that intermediate age open cluster. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Upper limit concentrations of trapped xenon in individual interplanetary dust particles from the stratosphere

Abstract— The Xe contents in 25 individual stratospheric interplanetary dust particles were measured in two different laboratories using focused laser micro‐gas extraction and (1) a conventional low‐blank magnetic sector mass spectrometer (Washington University), and (2) a resonance ionization time of flight mass spectrometer (RELAX‐University of Manchester). Data from both laboratories yielded a remarkably similar upper‐limit ¹³²Xe concentration in the IDPs (>2.7, 6.8 and 2.2 × 10^?8ccSTP/g for Washington University Run 1, Washington University Run 2 and University of Manchester analyses, respectively), which is up to a factor of five smaller than previous estimates. The upper‐limit ¹³²Xe/³⁶Ar ratio in the IDPs (¹³²Xe/³⁶Ar > ?8 × 10^?4for Run 1 and ¹³²Xe/³⁶Ar > ?19 × 10^?4for Run 2), computed using ³⁶Ar concentration data reported elsewhere is consistent with a mixture between implanted solar wind, primordial, and atmospheric noble gases. Most significantly, there is no evidence that IDPs are particularly enriched in primordial noble gases compared to chondritic meteorites, as implied by previous work.     

The quasar population density as a result of the formation rate and the evolutionary pathes II. Adaption to the observation

The continuity equation of CAVALIERE et al. (1971) generalized to age-dependent luminosity evolution (BOLLER and LIEBSCHER 1989) is used to calculate quasar luminosity functions. For some combinations of source functions S(L, t) and evolutionary pathes M(L) we discuss the resulting N — m relations and the amount of the X-ray background and compare them with actual results of observation. We can exclude certain models, (S(L, t), M(L)). We cannot yet decide what the actual source function and the actual evolutionary path are.     

Detection and temporal coherence of p‐modes below 1.4 mHz

Data collected recently by the helioseismic experiments aboard the SOHO spacecraft have allowed the detection of low degree p‐modes with increasingly lower order n. In particular, the GOLF experiment is currently able to unambiguously identify low degree modes with frequencies as low as 1.3 mHz. The detection of p‐modes with very low frequency (i.e., low n), is difficult due to the low signal‐to‐noise ratio in this spectral region and its contamination by solar signals that are not of acoustic origin. To address this problem without using any theoretical a priory, we propose a methodology that relies only on the inversion of observed values to define a spectral window for the expected locations of these low frequency modes. The application of this method to 2920‐day‐long GOLF observations is presented and its results discussed. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The OSO-1 solar neutron experiment

BF₃ counters on OSO-1 were used to look for solar neutrons by trying to observe a diurnal variation in count rate. No effect was observed and an upper limit was placed on the solar neutron flux at the earth of J _n < 2 × 10^–3 neut/cm²/sec of 10 keV < E _n < 10 meV for the period March to May 1962. No proton-producing flares occurred during this time, so the most obvious source of solar neutrons could not be studied. The emulsion experiment of Apparao et al., flown during this period, which seemed to indicate solar neutrons has probably been misinterpreted.