Chlorinated hydrocarbons and hatching success in Baltic herring spring spawners

Eggs from 69 females of spring spawning herring from the German Baltic coast (Travemünde, April 1979) were incubated in clean sea water (20‰ S, temperature 8°C) under standard conditions. Sixty-one trials could be used for the evaluation of hatching success. Viable hatch was taken as a measure to evaluate the effects of chlorinated hydrocarbons accumulated in gonads, liver and muscle of parental fish.PCB levels in running ripe females ranged on a wet weight basis between 19 and 241 ng g^?1 (gonad), 20 and 377 ng g^?1 (liver) and 11 and 1820 ng g^?1 (muscle). Concentrations of other chlorinated hydrocarbons (DDD, DDE, γ-HCH, etc.) were in the same range as reported by other authors for Baltic herring (Huschenbeth, 1973, 1977). Viable hatch was significantly affected at ovary DDE concentrations higher than 18 ng g^?1 (wet wt) and PCB concentrations of more than 120 ng g^?1 (wet wt).Results are compared with data obtained during earlier investigations with flounder eggs.     

Implementation of High Resolution Tidal Current Fields in Electronic Navigational Chart Systems

A system for displaying tidal currents in an electronic chart display and information system (ECDIS) has been developed and implemented in compliance with the standards of the International Hydrographic Organization (IHO). The tidal current fields can be displayed in real time on the electronic navigational chart and several options and functions for updating and zooming have been designed. The current fields are calculated from a data base with the harmonic constants for the four major tidal constituents. The harmonic constants are obtained from a high resolution numerical model with horizontal grid resolution of 100 m. The model is validated by comparing with sea level and current measurements. The depth matrix for the central part of the model domain was calculated from data from multibeam bathymetric surveys. An application example of the implementation is given for Trondheimsleia, a part of the main sailing route along the western coast of Norway.     

Persistent volcanic signature observed around Barren Island, Andaman Sea, India

This study delineates the formation of a warm pool (>34°C) of air to the west (downwind) of the active volcano of the Barren Island during October–November 2005. Barren Island is located in the Sumatra–Andaman region, about 135 km east of Port Blair, and lies within the Burma microplate, the southern tip of which experienced a submarine earthquake (M _w 9.3) causing a tsunami in December 2004. Barren Island is the only volcano, which has shown sustained eruptive activity since shortly after the Great Sumatran Earthquake of December 2004. Our observations require further corroboration to relate how submarine earthquakes activate volcanoes and how far these thermal emissions influence climate changes. Because it links global warming and climate changes to the frequent emissions from a volcano activated by submarine earthquakes, this case study is of special interest to the earth-ocean-atmosphere sciences community.     

Simulation of additive transport from the land surface on the basis of experimental data on heat transfer in the atmospheric surface layer

A method is proposed to study the transport of a passive additive in the atmospheric surface layer with the use of the atmospheric transfer function. This method makes it possible to estimate the spatial distribution of the concentration of a passive additive in the atmospheric surface layer from the additive’s surface source without experimentally determining the vertical profile of the transport coefficient or without resorting to various hypotheses for the character of its behavior. The transfer function, which contains the information on the wind-field structure, can be obtained from simple one-point measurements of surface-and air-temperature fluctuations and from subsequent spectral processing of the data. The effects of the wind-velocity profile and turbulence on the spatial distribution of additive concentration are assessed. This method allows one to simplify experiments during development and verification of the models of atmospheric diffusion. This method may also be useful in emergency situations to predict the propagation of hazardous additives.     

Probing molecular-level transformations of dissolved organic matter: insights on photochemical degradation and protozoan modification of DOM from electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems.     

Salt Diapirs, Salt Brine Seeps, Pockmarks and Surficial Sediment Creep and Slides in the Canary Channel off NW Africa

Circular to elliptical mounds in the Canary Channel with reliefs of 75 to 375 m and diameters of 4 to 8 km partially surrounded by moats with reliefs of 25 to 75 m, were formed by piercement of the seafloor by Mesozoic evaporites. Several long gullies, < 1km wide, with abrupt terminations and pockmarks associated with these mounds were probably eroded by dense brine and hydrocarbon seeps. The salt brines that eroded the gullies were formed where salt diapirs intersect the seafloor, or in the subsurface by circulating ground water heated by igneous activity along the Canary Ridge. If the brines originated in the subsurface they reached the seafloor along faults. Displacement of the surficial sediments by sliding and creep is probably the result of the expulsion of hydrocarbons and/or vertical motion of the Mesozoic evaporites. Microtopographic features along or near the east flank of the Canary Ridge are the creation of uplift of the ridge, hydrothermal activity, mass wasting processes and turbidity currents.     

Stress and deformation of offshore piles under structural and wave loading

Various offshore structures, especially large structures such as Tension Leg Platforms (TLP), are usually supported by concrete piles as the foundation elements. The stress distribution within such a large structure is a dominant factor in the design procedure of an offshore pile. To provide a more accurate and effective design for offshore foundation systems under axial and lateral wave loads, a finite element model is employed herein to determine the stresses and displacements in a concrete pile under similar loading conditions. A parametric study is also performed to examine the effects of the stress distribution due to the changing loading conditions.     

Phototoxicity of pyrene and benzo[a]pyrene to embryo-larval stages of the Pacific oyster Crassostrea gigas

There is a growing body of evidence to suggest that certain polycyclic aromatic hydrocarbons (PAHs) pose a greater hazard to aquatic organisms than previously demonstrated, due to their potential to cause photo-induced toxicity when exposed to ultraviolet (UV) radiation. The consequences of photo-induced toxicity are reported here for embryo-larval stages of the pacific oyster Crassostrea gigas, following exposure to pyrene and benzo[a]pyrene. During laboratory investigations, significant increases in toxicity were observed in the presence of environmentally attainable levels of UV-radiation, compared with embryos exposed to PAH alone, at levels previously deemed to have little acute biological effect. The phototoxicity of pyrene and benzo[a]pyrene completely inhibited the development to the D-shell larval stage when embryos were simultaneously exposed to 5 microg l(-1) PAH and ultraviolet light (UVB = 6.3 +/- 0.1 microW/cm2 and UVA = 456.2 +/- 55 microW/cm2). A linear relationship was also demonstrated for benzo[a]pyrene phototoxicity with decreasing UV light intensity.