The H2/CO ratio of emissions from combustion sources: comparison of top-down with bottom-up measurements in southwest Germany

The hydrogen-to-carbon monoxide (H₂/CO) emission ratio of anthropogenic combustion sources was determined from more than two years of quasi-continuous atmospheric observations in Heidelberg (49°24' N, 8°42' E), located in the polluted Rhein-Neckar region. Evaluating concurrent mixing ratio changes of H₂ and CO during morning rush hours yielded mean molar H₂/CO ratios of 0.40 ± 0.06, while respective results inferred from synoptic pollution events gave a mean value of 0.31 ± 0.05 mole H₂/mole CO. After correction for the influence of the H₂ soil sink on the measured ratios, mean values of 0.46 ± 0.07 resp. 0.48 ± 0.07 mole H₂/mole CO were obtained, which are in excellent agreement with direct source studies of traffic emissions in the Heidelberg/Mannheim region (0.448 ± 0.003 mole H₂/mole CO). Including results from other European studies, our best estimate of the mean H₂/CO emission ratio from anthropogenic combustion sources (mainly traffic) ranges from 0.45 to 0.48 mole H₂/mole CO, which is about 20% smaller than the value of 0.59 mole H₂/mole CO which is frequently used as the basis to calculate global H₂ emissions from anthropogenic combustion sources.     

Climate-driven changes in lake conditions during late MIS 3 and MIS 2: a high-resolution geochemical record from Les Echets, France

A new set of geochemical data obtained from a long sediment sequence from the Les Echets basin provides a new record of palaeoenvironmental change for western Europe. The sequence covers the late part of Marine Isotope Stage (MIS) 3 and MIS 2 ( c . 46.1–15.0 cal. kyr BP) and extends over 30 m of sediment, allowing for high sampling resolution. Distinct cyclic fluctuations in aquatic productivity proxies suggest a tempo of environmental change at Les Echets that resembles the one established for Dansgaard-Oeschger cycles and Heinrich events. Increases in organic carbon are paralleled by high hydrogenous contents and enriched δ¹³C_org and C_org/N_tot ratios, implying a mixture of aquatic and land-derived constituents. The stable isotope values are directly linked to primary aquatic productivity and the input of terrestrial organic matter, enriched during warm, productive, periods, and drastically depleted during cold periods, particularly Heinrich events. Phases of relatively high productivity correlate with Dansgaard-Oeschger interstadials 8–2, while Heinrich events 3 and 2 are also clearly delineated by distinct lithological horizons with very low organic contents, high dry densities and enhanced organic matter oxidation. A large hiatus occurring about the time of Heinrich event 4 suggests that the cold and dry climate reconstructed for this event in the North Atlantic region also greatly affected Les Echets and its catchment.     

Airborne measurements of dust layer properties, particle size distribution and mixing state of Saharan dust during SAMUM 2006

The Saharan Mineral Dust Experiment (SAMUM) was conducted in May/June 2006 in southern Morocco. As part of SAMUM, airborne in situ measurements of the particle size distribution in the diameter range 4 nm < D _p < 100 μm were conducted. The aerosol mixing state was determined below D _p < 2.5 μm. Furthermore, the vertical structure of the dust layers was investigated with a nadir-looking high spectral resolution lidar (HSRL). The desert dust aerosol exhibited two size regimes of different mixing states: below 0.5 μm, the particles had a non-volatile core and a volatile coating; larger particles above 0.5 μm consisted of non-volatile components and contained light absorbing material. In all cases, particles larger than 10 μm were present, and in 80% of the measurements no particles larger than 40 μm were present. The abundance of large particles showed almost no height dependence. The effective diameter D _eff in the dust plumes investigated showed two main ranges: the first range of D _eff peaked around 5 μm and the second range of D _eff around 8 μm. The two ranges of D _eff suggest that it may be inadequate to use one average effective diameter or one parametrization for a typical dust size distribution.     

Vertically resolved dust optical properties during SAMUM: Tinfou compared to Ouarzazate

Vertical profiles of dust key optical properties are presented from measurements during the Saharan Mineral Dust Experiment (SAMUM) by Raman and depolarization lidar at two ground-based sites and by airborne high spectral resolution lidar. One of the sites, Tinfou, is located close to the border of the Sahara in Southern Morocco and was the main in situ site during SAMUM. The other site was Ouarzazate airport, the main lidar site. From the lidar measurements the spatial distribution of the dust between Tinfou and Ouarzazate was derived for 1 d. The retrieved profiles of backscatter and extinction coefficients and particle depolarization ratios show comparable dust optical properties, a similar vertical structure of the dust layer, and a height of about 4 km asl at both sites. The airborne cross-section of the extinction coefficient at the two sites confirms the low variability in dust properties. Although the general picture of the dust layer was similar, the lidar measurements reveal a higher dust load closer to the dust source. Nevertheless, the observed intensive optical properties were the same. These results indicate that the lidar measurements at two sites close to the dust source are both representative for the SAMUM dust conditions.     

The 30–60-day oscillation in the East Asian summer monsoon and its time-dependent association with the ENSO

Based on 30–60-day oscillation in the East Asian summer monsoon (EASM), the relationship between its northward propagation and ENSO (El Niño and Southern Oscillation) was investigated. To explicitly describe the 30–60-day monsoonal evolution, an empirical orthogonal function (EOF) analysis was carried out on the temporal-latitude section of the longitudinal average for 115°E–120°E. The principal 30–60-day EASM mode captures a northward propagation of well-organized intraseasonal oscillation (NISO). Using the associated time series of the first mode, we found a significant lagged correlation between interannual variability of the NISO and ENSO. Its lagged correlations with NINO indices have a quasi-biennial (QB) characteristic through the preceding summer and the concurrent summer. Their relationship was found by the regression analysis relating the low-level circulation to the ocean temperature. The western North Pacific anticyclone and the anticyclone-induced easterly vertical wind shear anomalies induce the dynamical linkage between the NISO and QB-type ENSO. It is shown that the NISO is more closely tied with QB-type ENSO in its phase than in its amplitude, and may be connected to the anomalous easterly wind and the eastward evolution of an oceanic Kelvin wave, which is associated with abrupt ENSO transition. The predictability on ENSO and NISO is examined through the canonical correlation analysis.     

Heavy metals and macroelements in the tundra of southern Spitsbergen: the effect of little auk Alle alle (L.) colonies

Samples of two species of widely distributed mosses (Sanionia uncinata and Hylocomium splendens) were collected in the Ariekammen-Fuglebergct catchment area (Hornsund. Spitsbergen) within and outside little auk Alle alle (L.) colonies. The concentrations of Cd. Pb, Ni, Zn, Cu, Mn. Fe. N, P, and S in the moss samples were found to be 1.5-2 times higher within than outside the colonics. Significant differences were found for Cd, Pb, Zn, Cu, and Fe, but not for Ni, Mn, N, P, and S. Sanionia uncinata accumulates up to 8 ug g⁻¹ d. wt Cd, 14-Pb, 8-Ni, 47-Zn, 9-Cu, 90-Mn, and 1920 u, g g⁻¹ d. wt Fe, while Hylocomium splendens accumulates up to 4 μg g⁻¹ d. wt Cd, 12-Pb, 3-Ni, 31-Zn, 5-Cu, fiO-Mn, and 840 μg g⁻¹ d. wt Fc. The colonics of seabirds contribute greatly to the supply of elements in the tundra ecosystems of southern Spitsbergen. The effect seems, however, to be limited to rather small areas.     

Soil investigations, offshore mid Norway: A case study of glacial influence on geotechnical properties

Fine-grained glaciomarine and glacial deposits on the outer Mid Norwegian continental shelf show complex variations in shear strength and degree of consolidation. At the Smørbukk Sør field (approx. 65°N, 7°E) about 80 m of variably overconsolidated clayey till is found on top of normally- or possibly underconsolidated glaciomarine and marine sediments. A high gas content is found below 60 m, and the porewater in the rather soft sediments in the lower part of the borehole may have been partly trapped by gas hydrates when the overlying hard till was deposited. The variations in geotechnical properties of the 80 m thick till section are suggested to result mainly from compaction below grounded ice during the last glaciation, and we interpret the strength variations in the till to reflect shifts between freeze of sediment porewater onto the base of the ice causing highly overconsolidated intervals, and thermal equilibrium or melting at the ice sole resulting in intervals of softer till.A large ridge northwest of Smørbukk (Skjoldryggen) is probably partly formed by ice push during ice flow oscillations at the same time as the described till at Smørbukk was deposited. This ridge retarded the ice flow and hence the frictional heating at the end of surges, creating pulses of net freezing base ice and consolidation of the substratum. The described process has possibly affected a wide area up-ice of Skjoldryggen, and may be common in areas with a complex glacial history and a fine-grained substratum.