Statistical analysis of isotopic ratios in MORB: the mantle blob cluster model and the convective regime of the mantle

A statistical examination of isotopic distributions for MORB from various ocean ridges leads to the “blob cluster model”, in which the oceanic crust accreting at ridges results from the mixing of two components within the ascending mantle. These are (1) upper mantle material and (2) discrete rising blobs of more radiogenic material. The blobs are fractionated to a variable degree and are distributed in the upper mantle circulation in a manner that is related to the spreading rate.(1) Themean values of the isotopic distributions allow us to calculate the probabilities of the two types of material within the mantle. The results show that theproportion of asthenospheric material in the mixtureincreases with the spreading rate, in agreement with the hypothesis of blob dilution within the upper mantle convection.Mass fluxes can be estimated for the rising blobs from these probabilities, which depend on the respective concentrations in the sources of the two types of material. If the blobs originate in the lower mantle, this flux estimation would suggest that a significant part of the lower mantle has been injected into the upper mantle during earth history.(2) Thestandard deviations of the distributions depend on the “efficiency” of the mixing process:the more imbricated are the asthenospheric and blob materials in the mixture,the smaller is theisotopic spread. This efficiency parameter is shown to increase with the spreading rate, as already suggested by previous comparisons between the East Pacific Rise and the Mid-Atlantic Ridge. Moreover, this feature may also be correlated with other data such as ridge bathymetric variations.     

Climatic control on the growth of gigantic gypsum crystals within hypogenic caves (Naica mine,Mexico)?

Three hypogenic caves within the Naica mine of Mexico (Cueva de los Cristales — CLC, Ojo de la Reina — OR, and Cueva de las Velas — CLV) host spectacular gypsum crystals up to 11 m in length. These caves are close to another shallow cave of the area (Cueva de las Espadas — CLE), with which they cover a 160 m-deep vertical section of the local drainage basin. Similar to other hypogenic caves, all these caves lack a direct connection with the land surface and should be unrelated with climate.A record of multi-technique fluid inclusion data and pollen spectra from cave and mine gypsum indicates surprisingly that climatic changes occurring at Naica could have controlled fluid composition in these caves, and hence crystal growth. Microthermometry and LA-ICP-Mass Spectrometry of fluid inclusions indicate that the shallow, chemically peculiar, saline fluid (up to 7.7 eq. wt.%NaCl) of CLE could have formed from evaporation, during a dry and hot climatic period. The fluid of the deep caves was instead of low salinity (～ 3.5 eq. wt.% NaCl) and chemically homogeneous, and was poorly affected by evaporation. We propose that mixing of these two fluids, generated at different depths of the Naica drainage basin, determined the stable supersaturation conditions for the gigantic gypsum crystals to grow. Fluid mixing was controlled by the hydraulic communication between CLE and the other deep caves, and must have taken place during cycles of warm-dry and fresh-wet climatic periods, which are known to have occurred in the region. Pollen grains from a 35 ka-old gypsum crystal of CLC corresponds to a fairly homogenous catchment basin made of a mixed broadleaf wet forest, which suggests precipitation during a fresh-wet climatic period and confirms our interpretation of the fluid inclusion data.The unusual combination of geological and geochemical factors of Naica suggests that other hypogenic caves found elsewhere may not host similar crystals. However, this work shows that fluid inclusions and pollen spectra represent a useful tool for cave studies in general, and if used in future studies might be essential to unravel the mechanisms of hypogenic deposition.     

Der Einfluß der Vegetation auf die Schwankungen des CO2-Gehaltes der Atmosphäre

Zusammenfassung Mit Hilfe des Ultrarot-Absorptionsschreibers wurden Tagesgänge des CO₂-Gehaltes in verschiedenen Höhen über einem Weizenfeld registriert. Während sich nachts durch die Atmung der Vegetation CO₂ am Boden anreichert, verarmt die bodennahe Luftschicht tagsüber infolge der Assimilation an CO₂. Das CO₂-Gefälle wechselt demnach zweimal täglich (morgens und abends) sein Vorzeichen. Infolge größerer Turbulenz ist das Gefälle bei Tag kleiner als bei Nacht; nach Multiplikation mit der Windgeschwindigkeit als Relativmaß des Austausches ergeben sich aber glaubhafte Relativwerte für den vertikalen CO₂-Strom und damit für die Kohlenstoffbindung und-entbindung durch die Pflanzendecke.

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Summary With the help of an infrared absorption-recorder the daily variation of CO₂ content in different heights above a wheat field has been recorded. During the night the CO₂ content is accumulated at the plant level by respiration, during the day diminished by photosynthesis. The CO₂ gradient thus changes its sign (+ or –) twice a day in the morning and evening. The CO₂ gradient is smaller during the day than in the night due to the stronger turbulence of the air. In multiplying gradients with wind velocities (used as a measure for the eddy exchange) one gets reasonable relative values for the vertical CO₂-stream, and thus also for photosynthesis and respiration of vegetation.

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Résumé La variation diurne de la teneur de l'air en CO₂ a été mesurée à différentes hauteurs au-dessus d'un champ de froment à l'aide d'un appareil enregistreur de l'absorption à l'infra-rouge. Tandis que cette teneur augmente de nuit au voisinage du sol par la respiration végétale, elle diminue au cours du jour par suite de l'assimilation. Le gradient vertical de la teneur en CO₂ change par conséquent de signe deux fois par jour, le matin et le soir; il est plus faible de jour à cause de la turbulence accrue que de nuit. Après multiplication par la vitesse du vent, mesure relative de l'échange turbulent, on obtient des valeurs relatives mais vraisemblables du courant vertical de CO₂ et par conséquent de la fixation et de la libération du carbone par la végétation.

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Mit 7 Textabbildungen.

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Nach einem am 15. Oktober 1951 auf der Meteorologentagung in Bad Kissingen gehaltenen Vortrag.     

Solution of rare earth elements in silicate solid phases; henry's law revisited in light of defect chemistry

It is shown that experimentally observed departures from Henry's law at high dilution conditions for rare earth elements (REE) in garnet, clinopyroxene and plagioclase can be referred to stabilization in the lattice point defects. The solution process involves negative interaction parameters (?500/?3,000 cal for garnet). On the basis of the experimental data, the activity coefficients of the trace REE can be approximated by a model based on trace cation/cationic vacancy binary solid solution, taking into account association phenomena between them as well.     

Dendrochronologie

Zusammenfassung Die Dendrochronologie arbeitet mit der Jahresschichtung des Holzes. Der Zuwachs gleichzeitig wachsender Hölzer ist ähnlich. Diese Forschungsrichtung braucht viel Material zur Herstellung typischer Mittelkurven. Mit Hilfe der Überbrückungsmethode kommt man örtlich sehr weit zurück. Schwierigkeiten liegen in der gesetzmäßigen Abnahme der Ähnlichkeit von Jahresringkurven mit der Entfernung voneinander. Neben einer absoluten Chronologie sind in Deutschland relative Chronologien aus Jungsteinzeit und Bronzezeit erarbeitet worden. Die Dendrochronologie kann gewisse Aussagen über Klimaschwankungen machen.     

Solar Coronal Plasma in Doppler Measurements

Doppler tracking of an interplanetary spacecraft near solar conjunction is strongly affected by the plasma in the solar corona, the main competitive contribution in measurements of the gravitational deflection of light rays. With the simultaneous availability of carriers in X band and K_a band for interplanetary communications, the plasma contribution to the corona can be accurately eliminated and measured. If, as in the Cassini mission, three different observables are available, this can be done in two ways: one deals with the total plasma content in the electric approximation, even in the ionosphere and interplanetary space; another is limited to the corona, but has access to subtler effects, like the magnetic correction to the refractive index. This technique will allow important progress in the radio investigation of the solar corona.     

Multi-criteria Evaluation of Bran Use to Promote Circularity in the Cereal Production Chain

Natural Resources Research - A reliable and realistic subsurface resource spatial modeling is a common and critical task for geosciences projects (mining, petroleum and environmental) because the...     

Garnet reequilibration and growth in the eclogite facies and geodynamical evolution near peak metamorphic conditions

Caledonian eclogite-facies metamorphism partially reworking Grenvillian granulite-facies anorthosite allows us to study the processes of garnet reequilibration at high pressure and to reconstruct the evolution of the unit near metamorphic peak conditions. Our results indicate that eclogite-facies metamorphism happened in two successive phases: first, inherited granulitic garnet was fractured and reequilibrated from their boundaries (crystal or fracture rims); then eclogite-facies minerals were crystallised in the fractures as overgrowths on inherited garnets. The reequilibration of inherited garnets is achieved through Fe²⁺Mg⁻¹ exchange, whereas eclogite-facies garnets crystallised during the subsequent phase are notably richer in Ca than un- and re-equilibrated granulitic garnet. Pseudosection construction shows that this lack in Ca reequilibration cannot be related to variations in thermodynamic conditions (a _H2O, reacting system composition) between the two phases. From the compilation of the available data, the reequilibration of granulitic garnet seems to be controlled by the inefficient intra- and inter-granular transport properties of Ca compared to Fe²⁺ and Mg. While these kinetic factors confine garnet reequilibration to Fe²⁺Mg⁻¹ exchange, the extent of reequilibration along this exchange vector is controlled by partitioning with adjacent omphacite. On the contrary to the diffusional reequilibration of granulitic garnet that lasted for several My according to our modelling of the diffusional relaxation, the strong compositional gradients between eclogite-facies and reequilibrated garnets, which are almost unaffected by diffusional reequilibration, provide evidence that rapid exhumation followed the crystallisation of eclogite-facies minerals. We propose that the movement reversal itself, from burial to exhumation, and associated deformation and fluid flow, triggered this crystallisation event. The resulting evolution near metamorphic peak conditions is therefore strongly asymmetrical: on the one hand, the prograde diffusional relaxation profiles indicate slow movement during the last stages of burial, whereas the unaffected retrograde overgrowth indicates fast exhumation rates.     

Changes in Nutrient Biogeochemistry in Response to the Regression of Zostera noltii Meadows in the Arcachon Bay (France)

From 1989 to 2007, a severe decline in Zostera noltii meadows was reported in the Arcachon Bay, with an accelerated regression after 2005. We investigated the inter-annual variability of the biogeochemistry of the sediment in an area affected by seagrass decline. In late summer and in winter of the years 2006, 2010, and 2011, sediment cores were collected at low tide on vegetated and adjacent non-vegetated sediments located in the eastern part of the Arcachon Bay. The geochemical analyses of sediment solid-phase organic carbon, reactive P and Fe, and the pore water concentrations of Fe²⁺, DIP, and NH₄ ⁺ are presented. The changes in the chemistry of sediment and pore water between 2006 and 2010 are interpreted as a consequence of the decrease in the Z. noltii biomass between 2006 and 2010. The absence of significant seasonal variations in biomass throughout the growth period (March–September) in 2011 is most likely related to the regression of Z. noltii meadow that strongly affects the study area. In contrast to the healthy meadow in 2006, the declining meadow favored the dissolution of sedimentary particulate phosphorus in winter. In late summer, the low biomass of seagrass resulted in a net release of ammonium in the pore water of the upper 20 cm of sediment. This study clearly shows that seagrass decay may enhance nutrient release in sediments, resulting in a significant supply of phosphorus to the water column of a magnitude comparable to annual inputs to the lagoon from the rivers and the tidal pump.