遗传算法在上地幔速度结构研究中的应用

遗传算法是近年来发展较快的一种求解非线性优化问题的有效方法。本文通过对遗传算法基本原理的介绍，对该方法的特点进行了分析。我们采用ＷＫＢＪ理论地震图作正演，遗传算法作反演，对用体波波形反演上地幔速度结构的方法进行了研究。在ＷＫＢＪ理论地震图的计算中，通过计算主要射线的平均吸收特征时间，考虑了衰减随距离的变化，通过对不同震源引入不同的虚拟界面，同时对多个地震的波形记录进行反演。探讨了观测误差对反演结果的影响。对理论记录的反演表明，用遗传算法研究上地幔速度结构具有较好的效果。     

ELNES spectroscopy of mixed Si coordination minerals

 Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds varying in Si^VI:Si^IV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of Si^VI/(Si^VI+Si^IV): (1) A linear relationship between the L_2,3-L₁ splitting and Si^VI/(Si^VI+Si^IV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied to both Si K- and L-edge ELNES spectra. Received: February 10, 1997 / Revised, accepted: May 23, 1997     

The local structure of Ca-Na pyroxenes. I. XANES study at the Na K-edge

 X-ray absorption Na K-edge spectra have been recorded on synthetic endmember jadeite and on a series of natural Ca-Na pyroxenes compositionally straddling the Jd-Di join. The C2/c members of the series are systematically different from the P2/n members. Differences can be interpreted and explained by comparing the experimental spectra with theoretical spectra. These have been calculated by the multiple-scattering formalism from the atomic positional parameters determined by single-crystal X-ray diffraction structure refinement on the same samples. In the full multiple scattering region of the spectra (1075 to 1090 eV) C-pyroxenes exhibit three features which reflect the 6-2 configuration of the O back-scattering atoms around the Na absorber located at the center of the cluster (site M2 of the jadeite structure). P-pyroxenes show more complicated spectra in which at least four (possibly five) features can be recognized; they reflect the two types of configuration (6-2 and 4-2-2) of O around Na in the two independent M2 and M21 eight-fold coordinated sites of the omphacite structure. A weak, sometimes poorly resolved peak at 1079 eV is diagnostic and discriminates C- from P-pyroxenes. The Garnet Ridge C2/c impure jadeite exhibits a spectrum which is intermediate between those of jadeite and omphacite. The Hedin-Lundqvist potential proves best for these insulating materials and allows multiple-scattering calculations agreeing well with experiments. Received: July 11, 1996/Revised, accepted: October 21, 1996     

柱撑蒙脱石制备与表征

本文采用多种方法制备keggin离子，并探索出制备稳定keggin离子的适宜酸碱度，用此柱化剂制备出层间距为2．4～2．5nm的柱撑蒙脱石。应用X射线走向衍射技术、红外光谱、差热分析对往撑蒙脱石进行表征，用BET、吡啶吸附考察了其表面物理化学性质。结果表明，用Keggin离子制备出的柱撑蒙脱石其层间距在自然状态下为2．4～2．5nm，350C灼烧，层间距稳℃定在1．8nm，且具有耐热性能好、较大的比表面积和较强的Lewis酸位中心等特点．     

法国GUERET花岗岩内黑云母的结构特征研究

应用形态数学、图象分析及立体学原理，通过岩石薄片研究，对Gueret花岗岩内黑云母的结构特征进行了定量分析，揭示了黑云母矿物粒子在花岗岩中的密度、粒径、形状及空间分布的规律。根据岩石薄片上黑云母的灰度特征，应用直接成象方法获得其灰度图象，用自动阈值方法可用来提取黑云母粒子从而构成二值图象。借助MIPS图象分析系统，可以评价花岗岩薄片样本图象中所有黑云母粒子的参数，包括面积、周长等。花岗岩内黑云母矿物的密度、粒径 形状及空间分布的分析，揭示了其各向异性特征；同时，威布尔、正态及泊橙模型可分别用来描述黑云母矿物的粒径、形状及空间分布特征。     

黑龙江省土壤元素有效量及其与农作物的关系初探

将区域地球化学资料应用于农业问题的研究，是扩大区域地球化学资料应用领域的重要方面之一。通过土壤中Ｃｕ、Ｚｎ、Ｆｅ、Ｍｎ、Ｃｏ元素的全量、有效量、ｐＨ值、有机质与作物产量之间关系的研究，发现元素有效量与土壤中元素全量呈正相关，与ｐＨ值呈负相关，与有机质呈正相关，而作物产量与元素有效量呈正相关     

极谱催化波测定天然水中微量锗的研究

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。     

生物礁岩分类方案

本文系统地提出了一个生物礁岩分类的新方案。生物礁岩首先根据次生组分的有无分为原生礁岩和次生礁岩。次生礁岩根据次生组分来源分为骨源次生礁岩和礁源次生礁岩。次生礁岩的二级分类根据次生组分的含量进行。骨源次生礁岩分为骨屑岩和含骨屑礁（灰）岩、倒骨央和含倒骨礁（灰）岩；礁源次生礁岩分为礁屑岩和含礁屑礁（灰）岩。骨屑岩根据次生组分的粒度分为巨骨砾（屑灰）岩、骨砾（屑灰）岩、细骨砾（屑灰）岩、骨砂（屑灰）岩；