Quantifying time scales of pedogenic calcrete formation using U-series disequilibria

Time scales of pedogenic calcrete development are quantified by subsampling carbonate from within a mature (stage V) pedogenic calcrete profile from southeast Spain and dating the material by U-series disequilibria. The location of the earliest and latest cements can be estimated by comparing previous studies of calcrete morphological development with micromorphological analysis of the study profile. Carbonate was sampled and dated from three locations within the profile: (1) below the lower surface of clasts within the hardpan (representing the earliest cement present—207±11 ka), (2) from the centre of cement filled pores within the hardpan (reflecting the final plugging of the calcrete hardpan—155±9 ka) and (3) from the laminar calcrete overlying the hardpan (representing the latest cement—112±15 ka). These results show that the hardpan took between 73 and 31 ka to form, whilst the mature stage V profile took between 121 and 69 ka to form. This is the first time that rates of mature calcrete development have been established by direct radiometric dating of the authigenic carbonate. The technique is appropriate for dating mature calcretes in dryland regions worldwide and offers the opportunity of increasing our understanding of the spatial and temporal variability in rates of pedogenic calcrete development.     

Very Low-grade Metamorphism in Basement Greywacke Terranes of the Northern and Central North Island, New Zealand

Metamorphism in the late Permian to early Cretaceous North Island basement greywackes has been investigated using petrography and clay mineral crystallinity. Several terranes are represented in the North Island greywackes and the study area includes Murihiku, Manaia Hill, Bay of Islands and Omahuta terranes and the Mélange Zone. Very low-grade metamorphic events in the greywackes have produced mineral assemblages of zeolite to pumpellyite-actinolite greywacke facies. Zeolite facies greywackes are characterized by the assemblage Zeo (Lmt, Anl, Hul)+Qtz±Ab±Cal± Chl±I±I/S* observed in the entire Murihiku terrane and in the eastern part of the Bay of Islands terrane and the Mélange Zone. The entire Manaia Hill, most of the Bay of Islands, the eastern area of the Omahuta terranes and the central part of the Mélange Zone are at prehnite-pumpellyite facies with mineral assemblages of Prh+Qtz+Chl+Pmp+Ab+± Ill±Cal±Lmt. Pumpellyite-actinolite facies with the mineral assemblage of Pmp±Act+Qtz+Ab+Chl±Ep±Ill±Cal±Chl occurs in the western part of the Mélange Zone and the Omahuta terrane.

Illite (IC) and chlorite (ChC) crystallinity values of greywackes are very similar and range from diagenetic zone to anchizone. Metamorphic conditions indicated by the IC and ChC and mineral facies are in excellent agreement and correlate as follows: crystallinity diagenetic-zone with the zeolite mineral facies, crystallinity lower anchizone with prehnite-pumpellyite mineral facies and crystallinity upper anchizone with pumpellyite-actinolite mineral facies. The general increase in the metamorphic grade from east to west, except in Murihiku terrane, is compatible with the sequence of accretion expected in a subduction environment.     

Coalification and graphitization in high-pressure schists in New Caledonia

The northern portion of the Tertiary high-pressure schist belt in New Caledonia contains, from west to east, a metamorphic progression from lawsonite-albite facies through glaucophanitic greenschists to eclogitic albite-epidote amphibolites. This belt is flanked to the west by Upper Cretaceous-Eocene metasediments, of prehnite-pumpellyite grade. Paraschists throughout this whole sequence contain abundant carbonaceous material which shows a progressive metamorphism from coal to graphite. Structural analysis of lithostatic load and oxygen isotope data have provided a PT profile for the carbon metamorphism. In the prehnite-pumpellyite metasediments, phytoclasts were progressively coalified to anthracite rank under PT conditions which extended up to 3 kb/255 ° C at the lawsonite isograd where graphite first appears. On the high grade side of the lawsonite isograd a transitional mixed zone of continued coalification and graphitization occurred within the PT range 3 kb/255 ° C to 5.5 kb/335 ° C which included the ferroglaucophane isograd. Immediately beyond this zone all phytoclasts were completely graphitized before the epidote isograd was reached at 6.3 kb/ 390 ° C. The prevailing metamorphic environment retarded coalification, but accelerated graphitization, under conditions of high pressure and a low temperature gradient (7 ° C/km) that had been generated within the sedimentary pile by rapid tectonic thickening and consequent deep burial.     

Periglacial features indicative of permafrost: Ice and soil wedges

Ice wedges are wedge-shaped masses of ice, oriented vertically with their apices downward, a few millimeters to many meters wide at the top, and generally less than 10 m vertically. Ice wedges grow in and are confined to humid permafrost regions. Snow, hoar frost, or freezing water partly fill winter contraction cracks outlining polygons, commonly 5–20 m in diameter, on the surface of the ground. Moisture comes from the atmosphere. Increments of ice, generally 0.1–2.0 mm, are added annually to wedges which squeeze enclosing permafrost aside and to the surface to produce striking surface patterns. Soil wedges are not confined to permafrost. One type, sand wedges, now grows in arid permafrost regions. Sand wedges are similar in dimensions, patterns, and growth rates to ice wedges. Drifting sand enters winter contraction cracks instead of ice. Fossil ice and sand wedges are the most diagnostic and widespread indicators of former permafrost, but identification is difficult. Any single wedge is untrustworthy. Evidence of fossil ice wedges includes: wedge forms with collapse structures from replacement of ice; polygonal patterns with dimensions comparable to active forms having similar coefficients of thermal expansion; fabrics in the host showing pressure effects; secondary deposits and fabric indicative of a permafrost table; and other evidence of former permafrost. Sand wedges lack open-wedge, collapse structures, but have complex, nearly vertical, crisscrossing narrow dikelets and fabric. Similar soil wedges are produced by wetting and drying, freezing and thawing, solution, faulting, and other mechanisms. Many forms are multigenetic. Many socalled ice-wedge casts are misidentified, and hence, permafrost along the late-Wisconsinan border in the United States was less extensive than has been proposed.     

Geochemistry of Precambrian gneisses: relevance for the evolution of the East Antarctic Shield

Archaean granulite-facies orthogneisses of the Napier Complex in Enderby Land, metamorphosed 3070 Maago, comprise two chemically distinct suites. The more abundant, mainly of tonalitic to granodioritic composition, shows strong Y depletion, explicable by hydrous partial melting of a garnet-bearing source (garnet amphibolite or possibly eclogite); it apparently represents new continental crust. Other gneisses (predominantly of trondhjemitic to granitic (s.s) composition) do not show Y depletion, and have higher TiO₂, Zr, Nb, La, Ce and Ga/Al, and lower CaO, Sr and Mg/(Mg + total Fe); they probably originated by relatively dry melting of predominantly felsic crystal rocks. Both suites show evidence for loss of Rb (relative to K), Th, and U during metamorphism. Late Archaean (−2800 Ma) amphibolite-facies gneisses of MacRobertson Land are of ‘undepleted’ type and may be representative of a higher crustal level than those of Enderby land. Late Proterozoic (1000 Ma) granulite-facies gneisses of Enderby Land (Rayner Complex) are to a large extent remetamorphosed Napier Complex rocks of igneous derivation; in contrast, gneisses of similar age in MacRobertson Land include a much higher proportion derived, either directly or by partial melting, from sedimentary protoliths.     

Tadhak alkaline ring-complex (Mali): existence of UPb isochrons and “Dupal” signature 270 Ma ago

The Tadhak alkaline ring-complex of Permian age provides two whole rock UPb isochrons giving concordant ages in agreement within relative errors with the RbSr isochron age:²³⁵U²⁰⁷Pb isochron: 271 ± 32Ma(MSWD= 0.3);²³⁸U²⁰⁶Pb isochron: 254 ± 18Ma(MSWD= 7.8), both on 8 whole-rock samples. The existence of these isochrons indicates that in favorable conditions U (and Pb) can be immobile. This can be due either to the lack of hard oxidizing conditions and/or to the location of U, in very low concentrations, in weathering-resistant minerals. The initial ratios (²⁰⁶Pb/²⁰⁴Pb = 18.714 ± 70and²⁰⁷Pb/²⁰⁴Pb = 15.589 ± 16), corrected for their Permian age, lie in the range observed for oceanic island basalts or continental alkali basalts and indicate an origin in a similar mantle, without any significant crustal contamination. This was also suggested by the initial⁸⁷Sr/⁸⁶Sr ratio of 0.70457 ± 4. Moreover, these Sr and Pb isotopic characteristics belong to the field of the so-called “Dupal” anomaly and indicate that it existed already 270 Ma ago. This study shows the potential interest of isotopic investigations of within-plate alkaline ring-complexes to characterize subcontinental mantle compositions, particularly in the past.     

Unsupported radiogenic Pb in zircon: a cause of anomalously high Pb-Pb,U-Pb and Th-Pb ages

Ion microprobe U-Th-Pb isotopic analyses of zircons from a granodioritic orthogneiss from the Napier Complex, Mount Sones, Enderby Land, Antarctica, have identified an unambiguous example of unsupported radiogenic Pb in a 3,950 Ma-old crystal. At one 40 m spot on the crystal an unusually large heterogeneity in Pb content was found, the concentration of radiogenic Pb ranging from 5 to 50 percent higher than could have been generated in 3,950 Ma by radioactive decay of the co-existing U and Th. This relative excess of radiogenic Pb is attributed to Pb gain rather than to U and Th loss because first, the Pb content varied by more than the U or Th contents and secondly, changes in the Pb/U, Pb/Th and Pb isotopic composition correlated directly with changes in the Pb concentration. The individual ²⁰⁷Pb/²⁰⁶Pb apparent ages ranged from 4,000 Ma to 4,145 Ma, all greater than the inferred age of the crystal. A correlation between ²⁰⁷Pb/²⁰⁶Pb and Pb/U shows that the Pb excess has not resulted from recent Pb movement. The spot apparently gained radiogenic Pb about 2,500 Ma ago, at the same time as the majority of the other zircons in the rock suffered substantial Pb loss. The Pb movement occurred in response to a discrete geologic event. Reverse discordance is a phenomenon that must be considered when interpreting zircon U-Pb ages, especially ²⁰⁷Pb/²⁰⁶Pb ages of single crystals or portions of crystals. Decay constants. Ages in this paper are calculated using the decay constant convention recommended by the Subcommission on Geochronology (Steiger and Jaeger 1977).     

Enhanced boulder weathering under late-lying snowpatches

A Schmidt test hammer was employed to assess the aggregate surface hardness of samples of boulders dug out from under late-lying snowpatches at sites in Switzerland, Scotland and Norway. The results were compared with an equivalent set of readings made on boulders at nearby snow-free control sites. The results in every case reveal that the aggregate surface hardness of boulders buried by late-lying snow is significantly less (at the 0·001 level) than that of boulders at the corresponding control sites. This result indicates that late-lying snow significantly enhances rock weathering, probably because boulder and rock surfaces are exposed to prolonged wetting by percolating meltwater under late-lying snowbeds.     

The petrogenesis of an I-type volcanic-plutonic suite: The St. Marys Porphyrite,Tasmania

The Devonian I-type St. Marys Porphyrite (388±1Ma) comprises two petrographically similar units, an 800 m thick pyroclastic sheet (compositionally dacite and rhyolite) and a subvolcanic feeder dyke. The pyroclastics are crystal-rich and contain (in order of decreasing abundance) plagioclase, quartz, biotite, augite, hypersthene and sanidine phenocrysts in an aphanitic groundmass.The early phenocryst assemblage clinopyroxene+orthopyroxene+plagioclase was followed by crystallisation of less magnesian pyroxene, more sodic plagioclase and biotite, quartz and K-feldspar. The phenocrysts crystallised at high temperature, between 1,000°-850° C, and at a pressure of 2.5±1 kb from a water undersaturated (<2.5 wt.%) magma in a chamber underlying the intrusive centre.At least two eruptive phases are present in the pyroclastic pile, each commencing with rhyolite. Bulk chemical variation probably reflects a zonation in the magma chamber prior to eruption. The low pressure phenocryst crystallisation conditions and the pyroxene Fe-enrichment trend with falling temperature support a fractional crystallisation model. The chemical variation can be explained by 20% fractional crystallisation involving plagioclase, quartz, biotite and pyroxene in proportions similar to modal phenocryst abundances.Volcanics like the St. Marys Porphyrite preserve evidence of their early magmatic history by quenching of mineral phases. Textural relationships and physico-chemical parameters deduced from the St. Marys Porphyrite are applicable to the interpretation of I-type granitoids in eastern Australia and elsewhere and constrain petrogenetic models for their genesis. Pyroxene cores of hornblende grains, pyroxene inclusions in plagioclase and corroded cores of plagioclase crystals may be formed through magmatic crystallisation and need not represent restite.