Structural changes and valence states in the MgCr<Subscript>2</Subscript>O<Subscript>4</Subscript>–FeCr<Subscript>2</Subscript>O<Subscript>4</Subscript> solid solution series

The influence on the structure of Fe²⁺ Mg substitution was studied in synthetic single crystals belonging to the MgCr₂O₄–FeCr₂O₄ series produced by flux growth at 900–1200 °C in controlled atmosphere. Samples were analyzed by single-crystal X-ray diffraction, electron microprobe analyses, optical absorption-, infrared- and Mössbauer spectroscopy. The Mössbauer data show that iron occurs almost exclusively as ^IVFe²⁺. Only minor Fe³⁺ (<0.005 apfu) was observed in samples with very low total Fe. Optical absorption spectra show that chromium with few exceptions is present as a trivalent cation at the octahedral site. Additional absorption bands attributable to Cr²⁺ and Cr³⁺ at the tetrahedral site are evident in spectra of end-member magnesiochromite and solid-solution crystals with low ferrous contents. Structural parameters a₀, u and T–O increase with chromite content, while the M–O bond distance remains nearly constant, with an average value equal to 1.995(1) Å corresponding to the Cr³⁺ octahedral bond distance. The ideal trend between cell parameter, T–O bond length and Fe²⁺ content (apfu) is described by the following linear relations: a₀=8.3325(5) + 0.0443(8)Fe²⁺ (Å) and T–O=1.9645(6) + 0.033(1)Fe²⁺ (Å) Consequently, Fe²⁺ and Mg tetrahedral bond lengths are equal to 1.998(1) Å and 1.965(1) Å, respectively.     

Granulometric and chemical composition of the Sava River sediments upstream and downstream of the Krsko nuclear power plant

Total concentrations of 13 elements (K, Ca, Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Y, Zr, Pb) in the size-fractionated Sava River sediments upstream and downstream of the Krsko nuclear power plant together with metal speciation within bulk sediment have been investigated. Trace metals generally increase with decreasing particle size, however, because of entrapment of organic matter in the 0.63–1 mm fraction, concentrations in the coarser sediment fraction are higher than expected. Exchangeable Pb, Zn, Cu, Mn, Cr and Fe are generally found to represent a negligible fraction of the total metal concentration of the bulk sediment. Seasonal variations of the Pb, Zn and Cu concentrations in the <0.5 mm fraction reflect decreased values during the spring period. Heavy metal concentrations in the 2003 waste water discharges from the Krsko nuclear power plant released into the Sava River were much lower than their maximum allowed values. Combined rubidium and organic matter normalization of the Zn, Pb and Cu concentrations, which was applied on the minus 0.063 mm fraction, indicated three potential sources of contaminants.     

Characteristics of rapid giant landslides in China

Factual data for 70 rapid, giant landslides since 1900 show that the occurrence of these landslides was largely predisposed by tectonics, geological structures, lithology and topography, and often triggered by rainfall and earthquakes. In terms of mobile behavior, the giant landslides can be classified into three types: slides, slide-flows and flows. It is found that each type of landslide was constrained to certain geologic and topographic regimes. There are good correlations between kinematic parameters of landslides and slope geometries, which confirm the important role played by topographical condition in the mobile behavior of landslides. Moreover, it is also found that each type of landslide presents distinct geotechnical characteristics in terms of nature of the slip zone and properties of sliding mass. Brief analyses of five typical cases illustrate that landslide mechanisms can be conceptually depicted by failure mechanisms of their slip zones prior to onset of movement and following energy conversion during movement. Problems and questions related to experience in China suggest that comprehensive and systematic investigation and study on rapid giant landslides are urgently needed.     

Evolution of geochemistry and depositional settings of Early Palaeozoic siliciclastics of the Barrandian (Teplá-Barrandian Unit,Bohemian Massif,Czech Republic)

Cambrian and Ordovician-Middle Devonian sequences of two successive Early Palaeozoic basins of the Barrandian unconformably overlie Cadomian basement in the Bohemian Massif NW interior (Teplá-Barrandian unit) which is the easternmost peri-Gondwanan remnant within the Variscides. Correlation of stratigraphy and geochemistry of the Early Palaeozoic siliciclastic rocks elucidated sediment provenances. Sandstones of the Middle Cambrian Píbram-Jince Basin were derived from a Cadomian Neoproterozoic island arc. The source area of the Ordovician shallow-marine siliciclastics of the successor Prague Basin is a dissected Cadomian orogen. Late Cambrian acid volcanics of the Barrandian and Cambrian (meta)granitoids emplaced in the W part of the Teplá-Barrandian Cadomian basement are also discernible in these sediments. Old sedimentary component increased during the Ordovician. Early Llandovery siliciclastic rocks show characteristics of an abruptly weakened supply of terrigenous material and an elevated proportion of synsedimentary basic volcanics as a result of Silurian transgression. Emsian siliciclastics (intercalated in the Late Silurian to Early Devonian limestone suite) presumably comprise an addition of coeval basic/ultrabasic volcaniclastics. Middle Devonian flysch-like siliciclastics indicate reappearance of Cadomian source near the Barrandian during early Variscan convergences of Armorican microplates that preceeded accretion of the Teplá-Barrandian unit within the Bohemian Massif terrane mosaic.Dr. Patoka deceased in July 2004.     

Carbon isotope stratigraphy of Lochkovian to Eifelian limestones from the Devonian of central and southern Europe

Lower to Middle Devonian carbonates of the Prague Syncline, the Carnic Alps, the Montagne Noire, and the Cantabrian Mountains were investigated for δ¹³C_carb and δ¹³C_org. These values were measured on bulk rocks, selected components and cements. Many carbonates exhibit primary marine values, but some are altered by diagenesis. A δ¹³C curve can be presented for the latest Pridolian to Emsian time interval. Several sharp or broad positive excursions are obvious in the woschmidti-postwoschmidti, sulcatus, kitabicus, Late serotinus, and kockelianus conodont zones. The excursion at the Silurian–Devonian boundary is known worldwide and therefore considered global in nature. Some of the others are described for the first time from central and southern Europe, and their global nature has to be verified by further investigations in other regions. Most excursions relate to and/or started during major regressions whereas sea-level highstands correspond to minimal δ¹³C values. Similar relationships between sea-level changes and δ¹³C have been observed from other early Palaeozoic intervals. The transgressive Chote? (?) and Ka?ák events are marked by positive isotope excursions, this type of combination is usually observed in late Palaeozoic to Cenozoic black shale events.     

A field evaluation of enhanced reductive dechlorination of chlorinated solvents in groundwater,New York Metropolitan Area

An initial assessment of an old manufacturing site with groundwater impacted by trichloroethene (TCE) contamination in the metropolitan New York area showed that the TCE was being removed naturally by reductive dechlorination. However, complete dechlorination was not expected at the site because the process was progressing too slowly under transitional to aerobic conditions at a degradation constant of –0.0013 and a TCE half life of 533 days. A pilot test was conducted at the site in which a carbohydrate substrate (molasses) was injected into the groundwater to create an In-Situ Reactive Zone (IRZ). Post-pilot test groundwater sampling and analysis indicated that an IRZ was created successfully as the total organic carbon (TOC) content and conductivity increased significantly while oxidation-reduction (REDOX) potential and dissolved oxygen (DO) decreased. The created IRZ caused enhanced reductive dechlorination of TCE at the site, found to proceed with a degradation constant of –0.0158 and a TCE half life of 44 days.     

Organic tracers in sediments from the coastal zone of Ras Abu el-Darag,Gulf of Suez

Sediment samples from the coastal zone of the Gulf of Suez contain a variety of organic compounds from anthropogenic and natural sources. A total of 12 surface samples of bottom sediments were collected with an Ekman grab sampler along an off-shore transect south of Ras Abu el-Darag. The samples were extracted with a mixture of dichloromethane and methanol (3:1 v/v) after drying and sieving through 250 μm mesh. The extracts were derivatized and analyzed by gas chromatography–mass spectrometry in order to characterize the chemical composition and sources of the organic components. Marine with minor terrestrial biota were the major natural sources of organic tracers and included n-alkanoic acids, sterols and saccharides (5.7–76.7%). Anthropogenic sources, from petroleum related activities, detergent usage for spill cleaning and littering, are indicated by the presence of n-alkanes with carbon preference index ≤1.0, hopanes, steranes, unresolved complex mixture of branched and cyclic hydrocarbons, alkyl nitriles, alkamides and plasticizers. Their total relative concentrations ranged from 23.3 to 97.3% of the total extracts. Petroleum residues from natural seepage may also be part of these hydrocarbons. The levels of anthropogenic inputs decrease from about 94% in coastal zone sediments to about 20% in sediments from the reef front.     

Geophysical and geochemical evidence of Proterozoic collision in the western marginal zone of the Baltic Shield

New continental crust was formed in the Svecofennian domain of the Baltic Shield c. 1.9 Ga ago. Approximately 0.1–0.15 Ga later, new crust accreted to the SW part of the Shield. In this paper an attempt is made, on the basis of gravity measurements and lithogeochemistry, to describe the tectonic processes responsible for the continental growth c. 1.75–1.8 Ga ago. The Transscandinavian Granite Porphyry Belt (TGPB) separates the Svecofennian domain from the polymetamorphic terrain of the SW Swedish gneiss region. Red orthogneisses occurring immediately west of the TGPB are the deformed equivalents of the TGPB type granitoids, while grey orthogneisses, displaying a tonalitic-granodioritic trend and situated further west, were generated in a »volcanic arc« environment. The TGPB granitoids and the red SW Swedish gneisses represent a transition from this volcanic arc type rock to contemporaneous »within-plate« type granites intruded in the Svecofennian crust. The volcanic arc was forced against the Svecofennian crust in which large tensional fracture zones ensued with strike directions normal to the collision front. In such tensional environments the »withinplate« type granites were generated. In the collision zone the crust was down-warped, and huge amounts of granitic melts were generated at the base of the crust. This TGPB Magma rose upwards utilizing the fracture zone between the arc rocks, generated slightly earlier, and the Svecofennian crust. A relatively thin upper part of the TGPB that spread laterally westwards became strongly deformed during the collision (i.e. the red SW Swedish gneisses), while the major deep-reaching TGPB root zone that was not completely solidified yet, acted as a buffer against the foliation front.

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Zusammenfassung Vor 1,9 Milliarden Jahren kam es zur Neubildung von kontinentaler Kruste im svecofennischen Bereich des Baltischen Schildes. Ungefähr 100–150 Millionen Jahre später wurde im Südwesten des Schildes neue Kruste hinzugefügt. In diesem Artikel wird auf der Basis von Gravimetriemessungen und Lithogeochemie der Versuch unternommen die tektomschen Vorgänge, die zu diesem 1,75–1,8 Milliarden Jahre alten Krustenzuwachs führten, zu beschreiben.Der Transskandinavische-Granit-Porphyr-Gürtel (Transscandinavian-Granite-Porphyry-Belt/TGPB) trennt das Svecofennium von der polymetamorphen, im Südwesten Schwedens gelegenen Gneis-Region. Ein direkt westlich des TGPB gelegenes Vorkommen roter Orthogneise entspricht den deformierten TGPB Granitoiden. Graue Orthogneise, die weiter im Westen aufgeschlossen sind, zeigen eine mehr tonalitische bis granodioritische Zusammensetzung und werden auf einen vulkanischen Inselbogen zurückgeführt. Die TGPB Granitoide und die roten südwest-schwedischen Gneise stellen einen Übergang von den Inselbogen-Vulkaniten zu den zeitgleichen »Intra-Platten-Graniten« der svecofennischen Kruste dar. Der Inselbogen kollidierte mit der svecofennischen Kruste, es entstanden großräumige Bruchzonen mit Streichrichtungen senkrecht zur Kollisionsebene. Während des Zustands der hohen Druckspannung des Gebietes intrudierten die »Intra-Platten-Granite«. Innerhalb des Kollisionsbereiches wurde die Kruste nach unten gebogen, und so entstanden an der Basis der Kruste große Mengen granitischen Magmas. Dieses TGPB Magma stieg entlang der Störungszone innerhalb der Inselbogengesteine, die nur wenig älter sind, und der svecofennischen Kruste, auf. Nur ein, von relativ geringer Mächtigkeit, weiter westlich gelegener Teil des TGPB, die roten südwest-schwedischen Gneise, wurde während der Kollision intensiv deformiert. Dagegen war der Hauptanteil der tiefreichenden TGPB Wurzelzone noch nicht vollständig erstarrt und wirkte deshalb wie eine Pufferzone gegen die Schieferungsfront.

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Résumé De la croûte continentale nouvelle s'est formée il y a 1,9 Ga dans le domaine des Svecofennides (Bouclier baltique). Environ 100 à 150 Ma plus tard, de la croûte nouvelle s'est accrétionnée à la bordure sud-ouest du bouclier. Cette note basée sur des mesures de gravité et la lithogéochimie, présente un essai d'analyse des processus tectoniques responsables de cette croissance continentale d'âge 1,75 à 1,8 Ga. Le «Transcandinavian Granite Porphygry Belt» (TGPB) sépare le domaine svécofennien des gneiss polymétamorphiques du sud-ouest de la Suède. Immédiatement à l'ouest de TGPB affleurent des orthogneiss rouges qui représentent l'équivalent déformé de granitoïdes du TGPB, tandis que des orthogneiss gris de tendance tonalitique-granodioritique, situés plus à l'ouest, ont été engendrées dans un environnement d'arc volcanique. Les granitoïdes du TGPB et les gneiss rouges du sud-ouest de la Suède représentent une transition entre ces produits d'arc volcanique et les granites intra-plaque de même âge intrudés dans la croûte svécofennienne. L'arc volcanique a été accrétionné à la croûte svécofennienne avec production dans celleci de grandes fractures d'extension perpendiculaires au front de collision. C'est dans ce domaine en extension que les granites intra-plaque se sont mis en place. Dans la zone de collision, la croûte s'est incurvée vers le bas et de grandes quantités de liquides granitiques ont été engendrées à la base de la croûte. Ces magmas TGPB sont montés à la faveur de la zone fracturée entre les roches de l'arc engendrée un peu plus tôt, et la croûte svécofennienne. Seule une fraction supérieure relativement mince du TGPB, développée vers l'ouest, a subi une déformation importante au cours de la collision, pour former les gneiss rouges du sud-ouest de la Suède; par contre, la partie principale de la racine profonde du TGPB, qui n'était pas encore entièrement solidifiée, a joné le role tampon en avant du front de foliation.

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