Ammonium loss and nitrogen isotopic fractionation in biotite as a function of metamorphic grade in metapelites from western Maine, USA

Ammonium fixed in micas of metamorphic rocks is a sensitive indicator both of organic-inorganic interactions during diagenesis as well as of the devolatilization history and fluid/rock interaction during metamorphism. In this study, a collection of geochemically well-characterized biotite separates from a series of graphite-bearing Paleozoic greenschist- to upper amphibolite-facies metapelites, western Maine, USA, were analyzed for ammonium nitrogen () contents and isotopic composition (δ¹⁵N_NH4) using the HF-digestion distillation technique followed by the EA-IRMS technique. Biotite separates, sampled from 9 individual metamorphic zones, contain 3000 to 100 ppm with a wide range in δ¹⁵N from +1.6‰ to +9.1‰. Average contents in biotite show a distinct decrease from about 2750 ppm for the lowest metamorphic grade (∼500 °C) down to 218 ppm for the highest metamorphic grade (∼685 °C). Decreasing abundances in are inversely correlated in a linear fashion with increasing K⁺ in biotite as a function of metamorphic grade and are interpreted as a devolatilization effect. Despite expected increasing δ¹⁵N_NH4 values in biotite with nitrogen loss, a significant decrease from the Garnet Zones to the Staurolite Zones was found, followed by an increase to the Sillimanite Zones. This pattern for δ¹⁵N_NH4 values in biotite inversely correlates with Mg/(Mg + Fe) ratios in biotite and is discussed in the framework of isotopic fractionation due to different exchange processes between or , reflecting devolatilization history and redox conditions during metamorphism.     

Ground ice recharge via brine transport in frozen soils of Victoria Valley, Antarctica: Insights from modeling δO and δD profiles

Soils in the McMurdo Dry Valleys, Antarctica contain ice and considerable amounts of salt. Ice often occurs at shallow depth throughout the Dry Valleys and other areas of hyperarid permafrost, notably on Mars. This common occurrence of shallow ice is enigmatic; however, since according to published sublimation models it should disappear relatively quickly (at rates of order 0.1 mm a⁻¹) due to vapor loss to the atmosphere. This loss may be offset by recharge from snowmelt infiltrating and freezing in the soil. Herein, we present a first quantitative estimate of this recharge based on measured vertical profiles of δD and δ¹⁸O that reveal considerable detail about the sources and sinks of ice. We model these profiles, taking into account the salt content and a soil temperature record along a 1.6 m depth profile of ∼10 ka old ice-cemented soils in Victoria Valley, Antarctica. The stable isotopes of ice are enriched in heavy isotopes at the top of the ice cement (20 cm depth); both δD and δ¹⁸O values plotted against depth exhibit a concave upward curve. At depth, the isotope composition is similar to that of Lake Victoria and modern meteoric water. The concave shape of the isotope profile is suggestive of downward advection-dispersion of snowmelt water enriched in heavy isotopes into the ice cement. Our advection-dispersion model, coupled with field data, enables us to quantify the advective flux and dispersion of melt water into the ice. The advective velocity and dispersion coefficient depend on the time since advection began and the ice-to-brine ratio; they are, respectively, of the order of 10⁻¹¹-10⁻¹⁰ m s⁻¹ and 10⁻¹²-10⁻¹¹ m² s⁻¹. These values suggest that over the ∼10 ka time period, a total of 190 mm water infiltrated into the ice-cemented ground. The isotope composition and deuterium excess values of the uppermost ice cement can be modeled from snowmelt water enriched in salts using open system-Rayleigh fractionation. To develop the isotopic signature of the upper ice cement requires evaporation of ∼95% of the snowmelt water. Based on 190 mm brine infiltrating into the soil requires an initial total of ∼4 m of snowmelt water. This corresponds to ∼0.4 mm a⁻¹ suggesting that, under the current climate condition, water from snowmelt is sufficient to compensate modeled sublimation rates, and therefore conserve ground ice in Victoria Valley.     

Late Pleistocene genesis of the middle Yarlung Zhangbo Valley,southern Tibet (China), as deduced by sedimentological and luminescence data

Knowledge on valley formation and palaeohydrology of the Yarlung Zhangbo (named Brahmaputra south of the Himalayas) is still in an early stage. Research was conducted in the middle valley reach around Gonggar in order to investigate the sediment properties, age and palaeoenvironmental implication of a widespread aggradational valley terrace. This heavily dissected terrace, lying c. 25 m above the present floodplain, consists of topping aeolian and colluvial deposits, intermediate lacustrine fines and basal fluvial sands. Sedimentological properties of the lacustrine layers suggest a cold-climate depositional environment. Geochemical data refer to a common provenance of all sediments investigated from a regional catchment area, implying a local provenance of topping loesses and sands by aeolian sorting of nearby fluvial deposits. OSL dates, representing the first luminescence dating effort partly applied to non-aeolian sediments in this valley, cluster closely in the interval 11.7 ± 0.8–17.4 ± 1.4 ka. During the Late Pleistocene (until c. 16 ka) the investigated middle valley reach around Gonggar was occupied by a lake attaining an extension of at least 100 km.     

Morphometric and hypsometric analysis in the Tierra Nueva Basin,San Luis Potosí, México

In areas with long periods of drought, it is essential to implement strategies to manage the available water resource. Tierra Nueva Basin is affected by this situation, consequently the farm production and livestock holdings are affected and the people don’t have access to enough water. In this paper, we propose an integrative methodology based on mathematical tools such as hypsometric and morphometric analysis applying geographic information systems. The proposal is strengthened with the aggregation of geological-structural, morphometrical, hypsometrical parameters and climatological information through a precipitation analysis provided by the National Water Commission from 1962 to 2010. According to the available data and the results obtained through the implemented proposal, an acceptable level of reliability is inferred allowing to determine areas structurally suitable for the use of surface water and its uptake. The methodology that we propose facilitates and simplifies the processes of searching and exploring locations suitable for surface water capture in arid and semi-arid zones, identifying in a qualitative and quantitative manner the optimal zone. For the case study, test-and-validation of the methodology the Tierra Nueva Basin in San Luis Potosí, México was selected. Tierra Nueva is a semi-arid site where “La Muñeca” dam is located. The results obtained in this work confirm the location of the “La Muñeca” dam as one of the most suitable areas for water collection. The methodology that we propose is a useful tool for the studies of water capturing purposes in arid and semi-arid zones.     

Depletion-induced seismicity in NW-Germany: lessons from comprehensive investigations

Acta Geotechnica - Evaluating various investigations for north-German gas fields, we discuss past and actual evolutions of the rock fabric in the light of dilatant driven and spontaneous...     

Particulate matter fluxes in the southern and central Kara Sea compared to sediments: Bulk fluxes, amino acids, stable carbon and nitrogen isotopes, sterols and fatty acids

The Kara Sea is one of the arctic marginal seas strongly influenced by fresh water and river suspension. The highly seasonal discharge by the two major rivers Yenisei and Ob induces seasonal changes in hydrography, sea surface temperature, ice cover, primary production and sedimentation. In order to obtain a seasonal pattern of sedimentation in the Kara Sea, sediment traps were deployed near the river mouth of the Yenisei (Yen) as well as in the central Kara Sea (Kara) within the framework of the German–Russian project “Siberian River run-off; SIRRO”. Two and a half years of time-series flux data were obtained between September 2000 and April 2003 and were analyzed for bulk components, amino acids, stable carbon and nitrogen isotopes as well as sterols and fatty acids.Sediment trap data show that much of the annual deposition occurred under ice cover, possibly enhanced by zooplanktonic activity and sediment resuspension. An early bloom of ice-associated algae in April/May occurred in the polynya area and may have been very important to sustain the life cycles of higher organisms after the light limitation of the winter months due to no/low insolation and ice cover. The strong river input dominated the months June–August in the southern part of the Kara Sea. The central Kara Sea had a much shorter productive period starting in August and was less affected by the river plumes. Despite different time-scales of sampling and trapping biases, total annual fluxes from traps were in the same order of magnitude as accumulation rates in surface sediments. Terrestrial organic carbon accumulation decreased from 10.7 to 0.3 g C m⁻² a⁻¹ from the riverine source to the central Kara Sea. Parallel to this, preservation of marine organic matter decreased from 10% to 2% of primary productivity which was probably related to decreasing rates of sedimentation.     

Climatic and limnological changes at Lake Karakul (Tajikistan) during the last ~29 cal ka

We present results of analyses on a sediment core from Lake Karakul, located in the eastern Pamir Mountains, Tajikistan. The core spans the last ~29 cal ka. We investigated and assessed processes internal and external to the lake to infer changes in past moisture availability. Among the variables used to infer lake-external processes, high values of grain-size end-member (EM) 3 (wide grain-size distribution that reflects fluvial input) and high Sr/Rb and Zr/Rb ratios (coinciding with coarse grain sizes), are indicative of moister conditions. High values in EM1, EM2 (peaks of small grain sizes that reflect long-distance dust transport or fine, glacially derived clastic input) and TiO₂ (terrigenous input) are thought to reflect greater influence of dry air masses, most likely of Westerly origin. High input of dust from distant sources, beginning before the Last Glacial Maximum (LGM) and continuing to the late glacial, reflects the influence of dry Westerlies, whereas peaks in fluvial input suggest increased moisture availability. The early to early-middle Holocene is characterised by coarse mean grain sizes, indicating constant, high fluvial input and moister conditions in the region. A steady increase in terrigenous dust and a decrease in fluvial input from 6.6 cal ka BP onwards points to the Westerlies as the predominant atmospheric circulation through to present, and marks a return to drier and even arid conditions in the area. Proxies for productivity (TOC, TOC/TN, TOC _Br ), redox potential (Fe/Mn) and changes in the endogenic carbonate precipitation (TIC, δ¹⁸O _Carb ) indicate changes within the lake. Low productivity characterised the lake from the late Pleistocene until 6.6 cal ka BP, and increased rapidly afterwards. Lake level remained low until the LGM, but water depth increased to a maximum during the late glacial and remained high into the early Holocene. Subsequently, the water level decreased to its present stage. Today the lake system is mainly climatically controlled, but the depositional regime is also driven by internal limnogeological processes.     

Insight into the Last Glacial Maximum climate and environments of the Baikal region

This study presents a multi‐proxy record from Lake Kotokel in the Baikal region at decadal‐to‐multidecadal resolution and provides a reconstruction of terrestrial and aquatic environments in the area during a 2000‐year interval of globally harsh climate often referred to as the Last Glacial Maximum (LGM). The studied lake is situated near the eastern shoreline of Lake Baikal, in a climatically sensitive zone that hosts boreal taiga and cold deciduous forests, cold steppe associations typical for northern Mongolia, and mountain tundra vegetation. The results provide a detailed picture of the period in focus, indicating (i) a driest phase (c. 24.0–23.4 cal. ka BP) with low precipitation, high summer evaporation, and low lake levels, (ii) a transitional interval of unstable conditions (c. 23.4–22.6 cal. ka BP), and (iii) a phase (c. 22.6–22.0 cal. ka BP) of relatively high precipitation (and moisture availability) and relatively high lake levels. One hotly debated issue in late Quaternary research is regional summer thermal conditions during the LGM. Our chironomid‐based reconstruction suggests at least 3.5 °C higher than present summer temperatures between c. 22.6 and 22.0 cal. ka BP, which are well in line with warmer and wetter conditions in the North Atlantic region inferred from Greenland ice‐cores. Overall, it appears that environments in central Eurasia during the LGM were affected by much colder than present winter temperatures and higher than present summer temperatures, although the effects of temperature oscillations were strongly influenced by changes in humidity.