Response Surface Modeling of Cu(II) Removal from Electroplating Waste by Adsorption: Application of Box–Behnken Experimental Design

The use of kaolinite‐based clay minerals as a low‐cost natural adsorbent for the removal of Cu(II) from electroplating waste leachate was studied. Batch experiments were conducted to determine the effects of varying adsorbent loading, initial pH, adsorbent dosage, and contact time. Box–Behnken design with three variables like initial pH, adsorbent dosage, and contact time at three different levels was studied to identify a significant correlation between the effects of these variables to the amount of Cu(II) adsorbed. The methodology identifies the principal experimental variables, which have the greatest effect on the adsorption process. After optimizing the input variables by using Simplex algorithm, the adsorption of Cu(II) was maximal (99.9% with a maximum (positive) standard deviation of 9.4) at pH 6.24, adsorbent dosage of 0.83 g L^?1, and contact time of 97 min, respectively. Furthermore, the experimental values are in good agreement with predicted values, the correlation coefficient and adjusted correlation coefficients were found to be 0.96 and 0.87, respectively.     

Influence of synoptic processes on the vietnamese current (the South China Sea) Dynamics during the Winter–Summer 1999 transition period

Demonstrated is an influence of synoptic processes on the seasonal dynamics of the Vietnamese Current in the South China Sea varying its direction under the influence of the monsoon. The spring season of 1999 is used as an example of the transition from the winter to summer. In winter, under the influence of the northeastern monsoon, the current is directed from north to south and in the summer, at the southwestern monsoon, in the opposite direction. In the spring, two zones of different water modification are formed: an impact is observed of both the leaving winter monsoon and the coming summer monsoon. Considered is an atmospheric process of low-gradient field type, when the pressure field is characterized by the low pressure gradient over the whole South China Sea. It is revealed that the Vietnamese Current moves in the summer regime (from south to north) in the northern and southern parts and keeps the winter regime (from north to south) in the central part.     

东秦岭商丹断裂带南侧武关岩群的锆石LA-ICP-MS U-Pb年龄

用LA-ICPMS定年技术测得武关岩群变玄武岩中继承性成因锆石的平均206Pb/238U年龄为348Ma+18/-12Ma。这一年龄代表了继承性锆石受炽热玄武岩浆改造而重结晶的年龄。综合分析认为,武关岩群的时代可能为晚泥盆世。     

Interval‐Based Diagnosis of Biological Systems – a Powerful Tool for Highly Uncertain Anaerobic Digestion Processes

Anaerobic digestion (AD) is a highly nonlinear time‐varying process commonly used for biological wastewater treatment, which is subject to large disturbances of both influent concentrations, and flow rates that may lead the process to a breakdown. In order to compensate the effect of these disturbances, the dynamics of the main state variables – including biomass – must be closely monitored and used to improve the process performance. However, AD processes still suffer from a lack of reliable and cheap sensors of key process variables to insure the right process operation. This has led to the development of estimation schemes, which infer the information of such key variables from the available measurements. Nevertheless, reliable measurements are not always possible to get because these readings may be corrupted by noise or erroneous due to sensor failures and as a consequence, they may lead to deteriorated control efforts and the eventual crash of the AD process. In this article, we propose an integrated system for the detection, isolation, and analysis of faults in AD processes by using interval observers (IO). The proposed approach was experimentally implemented on a 1‐m³ pilot scale anaerobic digester. Based on the comparison between the measured outputs and their corresponding estimates, results show that this approach was able to detect sensor failures as well as faults in the basic hypotheses made during the design step.     

Seismic failure probability of concrete slab on CFR dams with welded and friction contacts by response surface method

In this study, failure probability of the concrete slab on concrete-faced rockfill (CFR) dams with welded and friction contact is investigated under earthquake effects by reliability analysis. For this purpose, Torul CFR dam is selected as an example and numerical solutions are performed by considering combination of reliability analysis–finite element method. 1992 Erzincan earthquake acceleration record is used in the finite element analysis considering deconvolved-base rock input model. In this model, the ground motion to be applied to the foundation base rock is obtained by deconvolution of the free-field surface record. In the materially nonlinear analysis, Drucker–Prager model is used for concrete slab and multi-linear kinematic hardening model is utilized for rockfill. Geometrically nonlinearity is also taken into account. Viscous boundary conditions are defined in the finite element model for both foundation soil and reservoir water. The hydrodynamic pressure of the reservoir water is considered using 2D fluid finite elements based on the Lagrangian approach. Both welded contact and friction contact based on the Coulomb’s friction law are defined in the structural connections. Improved Rackwitz–Fiessler method is used with response surface method in the reliability analysis. The tensile and compression strengths of the concrete slab are utilized in the implicit limit state functions considering various thicknesses. The probability of failure of the most critical points in the concrete slab is obtained. According to this study, the probabilities of failure obtained from the CFR dam including friction contact are lower. When the welded contact is considered in joints, the probability of failure of the concrete slab is 1 due to tensile stress limit state and compression stress limit state only if concrete slab is linear. The most critical probability of failure of the concrete slab appears in the case that the concrete slab is linear and rockfill is materially nonlinear. The probability of failure of the concrete slab decreases if the nonlinearity of the concrete is considered. Also, hydrodynamic pressure decreases the reliability of the concrete slab.     

Reconstruction and post-event analysis of a flash flood in a small ungauged basin: a case study in Slovak territory

Flash floods are one of the major natural hazards occurring in small streams with a negative effect on the country as well as on human lives. Heavy rainfall occurred on July 20, 2014 and July 21, 2014 and caused severe surface water flooding and a flash flood in the Malá Fatra National Park (Slovakia). The most affected was Vrátna Valley with the Varínka stream. This study presents a reconstruction and post-event analysis of a flash flood on small ungauged basin located in this protected area of Slovakia. The reconstruction included hydraulic terrain measurements on estimating the flood’s culmination and documenting the flood’s development. The measurements were taken at three cross sections of the Varínka stream. This paper is focused mainly on post-event analysis of the Varínka stream in two profiles: Strá?a (gauged profile) and Tiesňavy (ungauged cross section). Subsequently, the extremeness of the flash flood was preliminary evaluated. Results of the post-event analysis showed that the July 2014 flood was not the highest flood in this area despite its catastrophic consequences. By studying historical materials, we came to the conclusion that in the past (e.g. in 1848 or 1939) some devastating floods in this area had occurred, which had disastrous consequences for the population. The second part of the study is focused on comparing this flash flood with three major floods which have occurred in Slovak territory since 1998. The first flood occurred on the 20th of July, 1998 on the Malá Svinka stream, and the two others are floods which occurred on the 7th of June, 2011 in the Small Carpathian Mountains: on the Gidra stream in Píla village and on the Parná stream in Horné Ore?any village. Such comparison of flash floods from different geographical regions and different rainfall events can provide comprehensive information about their regimes, threats and disastrous effects.     

Development of local authorities in EU-member states between 1950–2011

The aim of the submitted study was to illustrate the development of the number of local authorities in all current EU states in the long period between 1950 and 2011 comprehensively, and also by particular decades, thus demonstrating the originality and uniqueness of the topic analysed in this context. Thus, we obtain a more detailed picture of the development of the number of local authorities in EU countries, and we can monitor how local authorities within a specific country gradually developed. (The stabilisation of the number of local units and an increase or gradual or sudden drop in local units are shown, for example). A sudden drop in local units can be associated with significant administrative reforms and with the development of large units of the so-called municipalities. When it becomes necessary to merge local authorities, many countries look to other countries where extensive reforms took place in the past for inspiration. However, it must be borne in mind that in a general European context, we cannot apply a universal system of public administration reforms, and solutions in the form of these reforms inspired by other countries may not always be appropriate.     

Landslide detection using visualization techniques for deep convolutional neural network models

Natural Hazards - Landslides occur when masses of rock, earth, and other debris move down a slope. The slope of an area is directly responsible for the magnitude of the landslide. Being...